Abstract
Recent surveys have uncovered an exciting new population of ultra-short-period (USP) planets with orbital periods less than a day. These planets typically have radii ≲1.5 R
⊕, indicating ...that they likely have rocky compositions. This stands in contrast to the overall distribution of planets out to ∼100 d, which is dominated by low-density sub-Neptunes above 2 R
⊕, which must have gaseous envelopes to explain their size. However, on the USP orbits, planets are bombarded by intense levels of photoionizing radiation and consequently gaseous sub-Neptunes are extremely vulnerable to losing their envelopes to atmospheric photoevaporation. Using models of planet evolution, I show that the rocky USP planets can easily be produced as the evaporated remnants of sub-Neptunes with H/He envelopes and that we can therefore understand the observed dearth of USP sub-Neptunes as a natural consequence of photoevaporation. Critically however, planets on USP orbits could often retain their envelopes if they are formed with very high-metallicity water-dominated envelopes. Such water-rich planets would commonly be ≳2 R
⊕ today, which is inconsistent with the observed evaporation desert, indicating that most USP planets likely formed from water-poor material within the snow-line. Finally, I examine the special case of 55 Cancri e and its possible composition in the light of recent observations, and discuss the prospects for further characterizing this population with future observations.
The looming antibiotic-resistance crisis has penetrated the consciousness of clinicians, researchers, policymakers, politicians and the public at large. The evolution and widespread distribution of ...antibiotic-resistance elements in bacterial pathogens has made diseases that were once easily treatable deadly again. Unfortunately, accompanying the rise in global resistance is a failure in antibacterial drug discovery. Lessons from the history of antibiotic discovery and fresh understanding of antibiotic action and the cell biology of microorganisms have the potential to deliver twenty-first century medicines that are able to control infection in the resistance era.
The escalating and unpredictable cost of oil, the concentration of major oil resources in the hands of a few politically sensitive nations, and the long-term impact of CO
2
emissions on global ...climate constitute a major challenge for the 21
st
century. They also constitute a major incentive to harness alternative sources of energy and means of vehicle propulsion. Today's lithium-ion batteries, although suitable for small-scale devices, do not yet have sufficient energy or life for use in vehicles that would match the performance of internal combustion vehicles. Energy densities 2 and 5 times greater are required to meet the performance goals of a future generation of plug-in hybrid-electric vehicles (PHEVs) with a 40-80 mile all-electric range, and all-electric vehicles (EVs) with a 300-400 mile range, respectively. Major advances have been made in lithium-battery technology over the past two decades by the discovery of new materials and designs through intuitive approaches, experimental and predictive reasoning, and meticulous control of surface structures and chemical reactions. Further improvements in energy density of factors of two to three may yet be achievable for current day lithium-ion systems; factors of five or more may be possible for lithium-oxygen systems, ultimately leading to our ability to confine extremely high potential energy in a small volume without compromising safety, but only if daunting technological barriers can be overcome.
Confining extremely high potential energy in a small volume without compromising safety or lifetime is the grand challenge of lithium batteries.
Lowering the Temperature of Solid Oxide Fuel Cells Wachsman, Eric D.; Lee, Kang Taek
Science (American Association for the Advancement of Science),
11/2011, Letnik:
334, Številka:
6058
Journal Article
Recenzirano
Fuel cells are uniquely capable of overcoming combustion efficiency limitations (e.g., the Carnot cycle). However, the linking of fuel cells (an energy conversion device) and hydrogen (an energy ...carrier) has emphasized investment in proton-exchange membrane fuel cells as part of a larger hydrogen economy and thus relegated fuel cells to a future technology. In contrast, solid oxide fuel cells are capable of operating on conventional fuels (as well as hydrogen) today. The main issue for solid oxide fuel cells is high operating temperature (about 800°C) and the resulting materials and cost limitations and operating complexities (e.g., thermal cycling). Recent solid oxide fuel cells results have demonstrated extremely high power densities of about 2 watts per square centimeter at 650°C along with flexible fueling, thus enabling higher efficiency within the current fuel infrastructure. Newly developed, high-conductivity electrolytes and nanostructured electrode designs provide a path for further performance improvement at much lower temperatures, down to ~350°C, thus providing opportunity to transform the way we convert and store energy.
•Ecological engineers have largely focused on landscape retention systems for P management.•Ecological engineering can play a broader role that supports a circular P economy.•Several ecological ...engineering approaches to P recovery and recycling have emerged.•Many strategies show promise for producing recovered P fertilizer and co-benefits, but challenges remain.•A systems framework is outlined that can guide research on P recovery and recycling.
Phosphorus is essential to life on Earth and frequently limits the productivity of ecosystems, including agroecosystems. Currently, a substantial portion of the global human population relies on finite phosphate rock resources used for chemical fertilizer production. Concern over poor management of these vital resources and continued efforts to enhance soil fertility and food security have stimulated interest in phosphorus recovery and recycling. Existing heterogeneity in phosphorus waste flows, agricultural phosphorus needs, the availability of resources, and spatial patterns of land use calls for a diverse array of phosphorus recycling strategies. Ecological engineers working on phosphorus management have most commonly aimed to create phosphorus sinks on the landscape to help mitigate eutrophication. There is a growing need for ecological engineering approaches that go beyond phosphorus retention to create pathways for phosphorus recovery and recycling, supporting both eutrophication control and food security. This review includes a brief overview of human impacts on the global phosphorus cycle and a survey of existing ecological engineering techniques for phosphorus recovery and recycling discussed in the literature. A systems approach for design and feasibility assessment of phosphorus recycling with eco-technology is outlined, along with several key challenges. The importance of an interdisciplinary, multiple element, and multiple resource approach to phosphorus recycling is emphasized.
A major challenge in theoretical ecology is understanding how natural microbial communities support species diversity, and in particular how antibiotic-producing, -sensitive and -resistant species ...coexist. While cyclic ‘rock–paper–scissors’ interactions can stabilize communities in spatial environments, coexistence in unstructured environments remains unexplained. Here, using simulations and analytical models, we show that the opposing actions of antibiotic production and degradation enable coexistence even in well-mixed environments. Coexistence depends on three-way interactions in which an antibiotic-degrading species attenuates the inhibitory interactions between two other species. These interactions enable coexistence that is robust to substantial differences in inherent species growth rates and to invasion by ‘cheating’ species that cease to produce or degrade antibiotics. At least two antibiotics are required for stability, with greater numbers of antibiotics enabling more complex communities and diverse dynamic behaviours ranging from stable fixed points to limit cycles and chaos. Together, these results show how multi-species antibiotic interactions can generate ecological stability in both spatially structured and mixed microbial communities, suggesting strategies for engineering synthetic ecosystems and highlighting the importance of toxin production and degradation for microbial biodiversity.
Celotno besedilo
Dostopno za:
DOBA, IJS, IZUM, KILJ, KISLJ, NUK, PILJ, PNG, SAZU, SBMB, SIK, UILJ, UKNU, UL, UM, UPUK
Application-specific requirements for future lighting, displays and photovoltaics will include large-area, low-weight and mechanical resilience for dual-purpose uses such as electronic skin, textiles ...and surface conforming foils. Here we demonstrate polymer-based photovoltaic devices on plastic foil substrates less than 2 μm thick, with equal power conversion efficiency to their glass-based counterparts. They can reversibly withstand extreme mechanical deformation and have unprecedented solar cell-specific weight. Instead of a single bend, we form a random network of folds within the device area. The processing methods are standard, so the same weight and flexibility should be achievable in light emitting diodes, capacitors and transistors to fully realize ultrathin organic electronics. These ultrathin organic solar cells are over ten times thinner, lighter and more flexible than any other solar cell of any technology to date.
We demonstrate ultrathin (2 µm thick) red and orange polymer light-emitting diodes with unprecedented mechanical properties in terms of their flexibility and ability to be stretched. The devices have ...a luminance greater than 100 cd m-2 , sufficient for a variety of optoelectronic applications including indoor displays. They can be operated as free-standing ultrathin films, allowing for crumpling during device operation. Furthermore, they may be applied to almost any surface whether rigid or elastomeric, and can withstand the associated mechanical deformation. They are shown to be extremely flexible, with radii of curvature under 10 µm, and stretch-compatible to 100% tensile strain. Such ultrathin light-emitting foils constitute an important step towards integration with malleable materials like textiles and artificial skin.
We use models of coupled thermal evolution and photo-evaporative mass loss to understand the formation and evolution of the Kepler-36 system. We show that the large contrast in mean planetary density ...observed by Carter et al. can be explained as a natural consequence of photo-evaporation from planets that formed with similar initial compositions. However, rather than being due to differences in XUV irradiation between the planets, we find that this contrast is due to the difference in the masses of the planets' rock/iron cores and the impact that this has on mass-loss evolution. We explore in detail how our coupled models depend on irradiation, mass, age, composition, and the efficiency of mass loss. Based on fits to large numbers of coupled evolution and mass-loss runs, we provide analytic fits to understand threshold XUV fluxes for significant atmospheric loss, as a function of core mass and mass-loss efficiency. Finally we discuss these results in the context of recent studies of the radius distribution of Kepler candidates. Using our parameter study, we make testable predictions for the frequency of sub-Neptune-sized planets. We show that 1.8-4.0 R sub(+ in circle) planets should become significantly less common on orbits within 10 days and discuss the possibility of a narrow "occurrence valley" in the radius-flux distribution. Moreover, we describe how photo-evaporation provides a natural explanation for the recent observations of Ciardi et al. that inner planets are preferentially smaller within the systems.