Gaia Data Release 2 Riello, M.; De Angeli, F.; Evans, D. W. ...
Astronomy and astrophysics (Berlin),
08/2018, Letnik:
616
Journal Article
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Context.
The second
Gaia
data release is based on 22 months of mission data with an average of 0.9 billion individual CCD observations per day. A data volume of this size and granularity requires a ...robust and reliable but still flexible system to achieve the demanding accuracy and precision constraints that
Gaia
is capable of delivering.
Aims.
We aim to describe the input data, the treatment of blue photometer/red photometer (BP/RP) low-resolution spectra required to produce the integrated
G
BP
and
G
RP
fluxes, the process used to establish the internal
Gaia
photometric system, and finally, the generation of the mean source photometry from the calibrated epoch data for
Gaia
DR2.
Methods.
The internal
Gaia
photometric system was initialised using an iterative process that is solely based on
Gaia
data. A set of calibrations was derived for the entire
Gaia
DR2 baseline and then used to produce the final mean source photometry. The photometric catalogue contains 2.5 billion sources comprised of three different grades depending on the availability of colour information and the procedure used to calibrate them: 1.5 billion gold, 144 million silver, and 0.9 billion bronze. These figures reflect the results of the photometric processing; the content of the data release will be different due to the validation and data quality filters applied during the catalogue preparation. The photometric processing pipeline, PhotPipe, implements all the processing and calibration workflows in terms of Map/Reduce jobs based on the Hadoop platform. This is the first example of a processing system for a large astrophysical survey project to make use of these technologies.
Results.
The improvements in the generation of the integrated
G
–band fluxes, in the attitude modelling, in the cross-matching, and and in the identification of spurious detections led to a much cleaner input stream for the photometric processing. This, combined with the improvements in the definition of the internal photometric system and calibration flow, produced high-quality photometry. Hadoop proved to be an excellent platform choice for the implementation of PhotPipe in terms of overall performance, scalability, downtime, and manpower required for operations and maintenance.
The separation of molecules with similar size and shape is an important technological challenge. For example, rare gases can pose either an economic opportunity or an environmental hazard and there ...is a need to separate these spherical molecules selectively at low concentrations in air. Likewise, chiral molecules are important building blocks for pharmaceuticals, but chiral enantiomers, by definition, have identical size and shape, and their separation can be challenging. Here we show that a porous organic cage molecule has unprecedented performance in the solid state for the separation of rare gases, such as krypton and xenon. The selectivity arises from a precise size match between the rare gas and the organic cage cavity, as predicted by molecular simulations. Breakthrough experiments demonstrate real practical potential for the separation of krypton, xenon and radon from air at concentrations of only a few parts per million. We also demonstrate selective binding of chiral organic molecules such as 1-phenylethanol, suggesting applications in enantioselective separation.
Five new metal-organic frameworks prepared from the ligand 5-bis(3-(1-imidazolyl)propylcarbamoyl)terephthalate (bipta(2-)) and transition metal salts, Zn(2+) (1), Co(2+) (2), Mn(2+) (3, 4) and Cu(2+) ...(5), are reported. Single crystal X-ray studies reveal that the bipta(2-) ligand acts as a tetradentate ligand and combines with four-coordinate cationic metal nodes to give four-connected framework structures. Whilst reaction of bipta(2-) with Zn(II) gives rise to a framework of diamondoid topology 1, the analogous frameworks with Co(II), Mn(II) and Cu(II) afford frameworks that incorporate square-planar nodes. Whereas 2 and 5 form frameworks of Cd(SO(4)) (cds) and square 4(4) nets (sql), respectively, reaction of Mn(II) with bipta(2-) forms two supramolecular isomers of topology cds for 3 and sql for 4.
Five new metalorganic frameworks prepared from the ligand 5-bis(3-(1-imidazolyl)propylcarbamoyl)terephthalate (bipta
2
) and transition metal salts, Zn
2+
(
1
), Co
2+
(
2
), Mn
2+
(
3
,
4
) and Cu
...2+
(
5
), are reported. Single crystal X-ray studies reveal that the bipta
2
ligand acts as a tetradentate ligand and combines with four-coordinate cationic metal nodes to give four-connected framework structures. Whilst reaction of bipta
2
with Zn(
ii
) gives rise to a framework of diamondoid topology
1
, the analogous frameworks with Co(
ii
), Mn(
ii
) and Cu(
ii
) afford frameworks that incorporate square-planar nodes. Whereas
2
and
5
form frameworks of Cd(SO
4
) (
cds
) and square 4
4
nets (
sql
), respectively, reaction of Mn(
ii
) with bipta
2
forms two supramolecular isomers of topology
cds
for
3
and
sql
for
4
.
Reaction of the ligand 5-bis(3-(1-imidazolyl)propylcarbamoyl)terephthalate (bipta
2
) with transition metal salts leads to five new MOFs including examples of supramolecular isomerism.
Microporous materials play an important role in a variety of industrial and domestic applications. While a diverse range of microporous materials have been identified, this thesis focuses on porous ...organic cages (POCs) because they have received much attention as synthetically tunable, solution processable, microporous materials. After introducing the latest developments in POC synthesis and the general application of microporous materials as selective sorbents, this thesis presents three developments in organic cage chemistry: a high-throughput workflow for the discovery of POCs, which yielded a novel organic cage compound; the measurement of selective adsorption by POCs, wherein the first instance of chiral selectivity by a POC was recorded; and the first instance of applying POCs as stationary phases for gas chromatography, which produced columns that separate racemic mixtures, alkylaromatic isomers, and alkane isomers. Chapter 2, discovering novel organic cages, presents attempts to use high-throughput and in-silico techniques to accelerate the discovery of novel organic cages. These methods were utilised to isolate a novel organic cage, CCX-S, which is characterised and discussed. Chapter 3, organic cages as selective sorbents, presents the development of approaches for measuring selective adsorption. These methods were used to identify the first reported instance of enantioselective adsorption by an organic cage. Further measurements to explain this separation behavior are also presented. Chapter 4, chromatographic separations with organic cages, presents one method of practically leveraging the presented separation behavior. In Chapter 4, the coating of capillary columns with CC3 is presented. These columns were used to successfully perform gas chromatographic separations, the first recorded instance of using a POC to do so. The columns were further improved by modifying the coating method and using prefabricated CC3 nanoparticles. This modification enabled difficult separations to be performed using the column; for example, the separation of hexane’s five isomers.
Microporous materials play an important role in a variety of industrial and domestic applications. While a diverse range of microporous materials have been identified, this thesis focuses on porous ...organic cages (POCs) because they have received much attention as synthetically tunable, solution processable, microporous materials. After introducing the latest developments in POC synthesis and the general application of microporous materials as selective sorbents, this thesis presents three developments in organic cage chemistry: a high-throughput workflow for the discovery of POCs, which yielded a novel organic cage compound; the measurement of selective adsorption by POCs, wherein the first instance of chiral selectivity by a POC was recorded; and the first instance of applying POCs as stationary phases for gas chromatography, which produced columns that separate racemic mixtures, alkylaromatic isomers, and alkane isomers. Chapter 2, discovering novel organic cages, presents attempts to use high-throughput and in-silico techniques to accelerate the discovery of novel organic cages. These methods were utilised to isolate a novel organic cage, CCX-S, which is characterised and discussed. Chapter 3, organic cages as selective sorbents, presents the development of approaches for measuring selective adsorption. These methods were used to identify the first reported instance of enantioselective adsorption by an organic cage. Further measurements to explain this separation behavior are also presented. Chapter 4, chromatographic separations with organic cages, presents one method of practically leveraging the presented separation behavior. In Chapter 4, the coating of capillary columns with CC3 is presented. These columns were used to successfully perform gas chromatographic separations, the first recorded instance of using a POC to do so. The columns were further improved by modifying the coating method and using prefabricated CC3 nanoparticles. This modification enabled difficult separations to be performed using the column; for example, the separation of hexane’s five isomers.
ABSTRACT
In the optical spectra of galaxies, methods for the separation of line emission arising from star formation and an additional hard component, such as shocks or active galactic nuclei (AGNs), ...is well-understood and possible with current diagnostics. However, such diagnostics fail when attempting to separate and define line emission which arises from shocked gas, and that arising from AGNs. We present a new three-dimensional diagnostic diagram for integral field unit data which can simultaneously separate the line emission amongst star formation, shocks, and AGNs within a galaxy. We show that regions we define as AGN-dominated correlate well with the hard X-ray distribution in our test case NGC 1068, as well as with known regions of AGN activity in NGC 1068. Similarly, spaxels defined as shock-dominated correlate strongly with regions of high-velocity dispersion within the galaxy.
ABSTRACT
In the optical spectra of galaxies, the separation of line emission from gas ionized by star formation and an active galactic nucleus (AGN), or by star formation and shocks, are very ...well-understood problems. However, separating line emission between AGN and shocks has proven difficult. With the aid of a new three-dimensional diagnostic diagram, we show the simultaneous separation of line emission from star formation, shocks, and AGN in NGC 1068, and quantify the ratio of star formation, shocks, and AGN in each spaxel. The AGN, shock, and star formation luminosity distributions across the galaxy accurately align with X-ray, radio, and CO(3–2) observations, respectively. Comparisons with previous separation methods show that the shocked emission heavily mixes with the AGN emission. We also show that if the H α flux is to be used as a star formation rate indicator, separating line emission from as many sources as possible should be attempted to ensure accurate results.
We systematically measure the gas-phase metallicities and the mass-metallicity relation of a large sample of local active galaxies for the first time. Observed emission-line fluxes from the Sloan ...Digital Sky Survey are compared to a four-dimensional grid of photoionization models using the Bayesian parameter estimation code NebulaBayes. For the first time we take into account arbitrary mixing between H ii region and narrow-line region (NLR) emission, and the models are also varied with metallicity, ionization parameter in the NLR, and gas pressure. The active galactic nucleus oxygen abundance is found to increase by Δ O H ∼ 0.1 dex as a function of host galaxy stellar mass over the range 10.1 < log M * M < 11.3 . We also measure the metallicity and ionization parameter of 231,000 star-forming galaxies for comparison with the sample of 7670 Seyfert 2 galaxies. A systematic offset in oxygen abundance of 0.09 dex is observed between the mass-metallicity relations of the star-forming and active galaxies. We investigate potential causes of the offset, including sample selection and the treatment in the models of diffuse ionized gas, pressure, and ionization parameter. We cannot identify the major cause(s), but suspect contributions due to deficiencies in modeling the ionizing spectra and the treatment of dust physics. Optical diagnostic diagrams are presented with the star-forming and Seyfert data colored by the inferred oxygen abundance, ionization parameter, and gas pressure, clearly illustrating the trends in these quantities.
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