Despite their importance for regional water resource planning and as indicators of climate change, records of in situ glacier mass balance remain short and spatially sparse in the Himalaya. Here, we ...present an updated series of in situ mass-balance measurements from Rikha Samba Glacier, Nepal, between 2011 and 2021. The updated in situ mass balance is −0.39 ± 0.32 m w.e. for this period. We use an energy-mass balance model to extend the annual mass-balance series back to 1974. The model is forced using daily meteorological variables from ERA5-Land reanalysis data that is linearly bias-corrected using observations from an automatic weather station situated near the glacier terminus. The modeled mass balance is consistent with the in situ mass-balance series measured 2011–2021 and with previous glaciological and geodetic estimates. The model results indicate a mass balance of −0.56 ± 0.27 m w.e. a−1 over the reconstruction period of 1974–2021, which is comparable to the mass losses experienced by other Himalayan glaciers during this time. An assessment of the sensitivity of the glacier mass balance to meteorological forcing suggests that a change in temperature of ±1 K has a stronger effect on the calculated mass balance compared to a ±20% change in either precipitation, or relative humidity, or solar radiation.
Today, relatively warm Circumpolar Deep Water is melting Thwaites Glacier at the base of its ice shelf and at the grounding zone, contributing to significant ice retreat. Accelerating ice loss has ...been observed since the 1970s; however, it is unclear when this phase of significant melting initiated. We analyzed the marine sedimentary record to reconstruct Thwaites Glacier's history from the early Holocene to present. Marine geophysical surveys were carried out along the floating ice-shelf margin to identify core locations from various geomorphic settings. We use sedimentological data and physical properties to define sedimentary facies at seven core sites. Glaciomarine sediment deposits reveal that the grounded ice in the Amundsen Sea Embayment had already retreated to within ~45 km of the modern grounding zone prior to ca. 9,400 y ago. Sediments deposited within the past 100+ y record abrupt changes in environmental conditions. On seafloor highs, these shifts document ice-shelf thinning initiating at least as early as the 1940s. Sediments recovered from deep basins reflect a transition from ice proximal to slightly more distal conditions, suggesting ongoing grounding-zone retreat since the 1950s. The timing of ice-shelf unpinning from the seafloor for Thwaites Glacier coincides with similar records from neighboring Pine Island Glacier. Our work provides robust new evidence that glacier retreat in the Amundsen Sea was initiated in the mid-twentieth century, likely associated with climate variability.
Simple as ABC: Alkynyl borane cycloadditions can be substrate‐directed to assemble aromatic difluoroboranes within an extremely mild and efficient reaction manifold compared to that of traditional ...methods (see scheme). The aromatic boranes are readily transformed into a range of useful products.
The synthesis of a range of novel ynone trifluoroborates has been achieved, in a two-pot process from propargylic alcohols. These alkynes have been subsequently used in the formation of a range of ...pyrazole trifluoroborate salts via cyclization with hydrazines. The products are generated with high levels of regiocontrol and in excellent yields and represent versatile synthetic intermediates.
The geometry of the sea floor immediately beyond Antarctica's marine-terminating glaciers is a fundamental control on warm-water routing, but it also describes former topographic pinning points that ...have been important for ice-shelf buttressing. Unfortunately, this information is often lacking due to the inaccessibility of these areas for survey, leading to modelled or interpolated bathymetries being used as boundary conditions in numerical modelling simulations. At Thwaites Glacier (TG) this critical data gap was addressed in 2019 during the first cruise of the International Thwaites Glacier Collaboration (ITGC) project. We present more than 2000 km.sup.2 of new multibeam echo-sounder (MBES) data acquired in exceptional sea-ice conditions immediately offshore TG, and we update existing bathymetric compilations. The cross-sectional areas of sea-floor troughs are under-predicted by up to 40 % or are not resolved at all where MBES data are missing, suggesting that calculations of trough capacity, and thus oceanic heat flux, may be significantly underestimated. Spatial variations in the morphology of topographic highs, known to be former pinning points for the floating ice shelf of TG, indicate differences in bed composition that are supported by landform evidence. We discuss links to ice dynamics for an overriding ice mass including a potential positive feedback mechanism where erosion of soft erodible highs may lead to ice-shelf ungrounding even with little or no ice thinning. Analyses of bed roughnesses and basal drag contributions show that the sea-floor bathymetry in front of TG is an analogue for extant bed areas. Ice flow over the sea-floor troughs and ridges would have been affected by similarly high basal drag to that acting at the grounding zone today. We conclude that more can certainly be gleaned from these 3D bathymetric datasets regarding the likely spatial variability of bed roughness and bed composition types underneath TG. This work also addresses the requirements of recent numerical ice-sheet and ocean modelling studies that have recognised the need for accurate and high-resolution bathymetry to determine warm-water routing to the grounding zone and, ultimately, for predicting glacier retreat behaviour.
Basal hydrological systems play an important role in controlling the dynamic behaviour of ice streams. Data showing their morphology and relationship to geological substrates beneath modern ice ...streams are, however, sparse and difficult to collect. We present new multibeam bathymetry data that make the Anvers-Hugo Trough west of the Antarctic Peninsula the most completely surveyed palaeo-ice stream pathway in Antarctica. The data reveal a diverse range of landforms, including streamlined features where there was fast flow in the palaeo-ice stream, channels eroded by flow of subglacial water, and compelling evidence of palaeo-ice stream shear margin locations. We interpret landforms as indicating that subglacial water availability played an important role in facilitating ice stream flow and controlling shear margin positions. Water was likely supplied to the ice stream bed episodically as a result of outbursts from a subglacial lake located in the Palmer Deep basin on the inner continental shelf. These interpretations have implications for controls on the onset of fast ice flow, the dynamic behaviour of palaeo-ice streams on the Antarctic continental shelf, and potentially also for behaviour of modern ice streams.
Outburst floods from subglacial lakes beneath the Antarctic Ice Sheet
modulate ice-flow velocities over periods of months to years. Although
subglacial lake drainage events have been observed from
...satellite-altimetric data, little is known about their role in the
long-term evolution of ice-sheet basal hydrology. Here, we
systematically map and model past water flow through an extensive area
containing over 1000 subglacial channels and 19 former lake basins exposed
on over 19 000 km2 of seafloor by the retreat of Pine Island and
Thwaites glaciers, West Antarctica. At 507 m wide and 43 m deep on average,
the channels offshore of present-day Pine Island and Thwaites glaciers
are approximately twice as deep, 3 times as wide, and cover an area over
400 times larger than the terrestrial meltwater channels comprising the
Labyrinth in the Antarctic Dry Valleys. The channels incised into bedrock
offshore of contemporary Pine Island and Thwaites glaciers would have been
capable of accommodating discharges of up to 8.8×106 m3 s−1. We suggest that the channels were formed by episodic discharges
from subglacial lakes trapped during ice-sheet advance and retreat over
multiple glacial periods. Our results document the widespread influence of
episodic subglacial drainage events during past glacial periods, in
particular beneath large ice streams similar to those that continue to
dominate contemporary ice-sheet discharge.
Although the size-frequency distributions of icebergs can provide insight into how they disintegrate, our understanding of this process is incomplete. Fundamentally, there is a discrepancy between ...iceberg power-law size-frequency distributions observed at glacial calving fronts and lognormal size-frequency distributions observed globally within open waters that remains unexplained. Here we use passive seismic monitoring to examine mechanisms of iceberg disintegration as a function of drift. Our results indicate that the shift in the size-frequency distribution of iceberg sizes observed is a product of fracture-driven iceberg disintegration and dimensional reductions through melting. We suggest that changes in the characteristic size-frequency scaling of icebergs can be explained by the emergence of a dominant set of driving processes of iceberg degradation towards the open ocean. Consequently, the size-frequency distribution required to model iceberg distributions accurately must vary according to distance from the calving front.
In vivo patient biomechanical study.
To investigate the dimensions of lumbar intervertebral foramen (LIVF) of patients with degenerative disc disease (DDD) during a flexion-extension motion of the ...body.
LIVF narrowing may result in nerve root compression. The area changes of degenerated and adjacent nondegenerated LIVFs in DDD patients under physiologic loading conditions are unknown.
Nine symptomatic low back pain patients with radiological evidence of L4-S1 DDD were recruited. Each subject was magnetic resonance imaging scanned for construction of three-dimensional lumbar vertebral models, and fluoroscopically imaged when the body extended from 45 flexion to full extension for reconstruction of LIVF dimensions. The data of the adjacent segment L3/4 and diseased segments L4/5 and L5/S1 were compared with a normal control group at 45 flexion, upright, and full extension of the body.
The mean LIVF areas of DDD segments were significantly smaller than those of the normal subjects in all positions (P <0.05). In upright position, the LIVF areas of the DDD patients were 32.8% and 33.6% smaller than the normal subjects for L4/5 and L5/S1, respectively. For the adjacent L3/4, the LIVF area of the DDD patients was 32.3% smaller than that of the normal controls (P <0.05). The total change of L3/4 LIVF area in DDD patients from flexion to extension was significantly smaller than that of the normal subjects, but the changes in L4/5 and L5/S1 LIVF areas were similar between the two groups (P >0.05).
Similar reductions of the LIVF dimensions were observed at the adjacent and the involved levels of the DDD patients, implying that biomechanical changes might have already occurred at the adjacent segment despite the lack of radiographic evidence of degeneration. Subsequent research should focus on the effects of surgical fusion on the biomechanical features of the adjacent segment.
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