Li‐rich Mn‐based cathode materials (LRMs) are potential cathode materials for high energy density lithium‐ion batteries. However, low initial Coulombic efficiency (ICE) severely hinders the ...commercialization of LRM. Herein, a facile oleic acid‐assisted interface engineering is put forward to precisely control the ICE, enhance reversible capacity and rate performance of LRM effectively. As a result, the ICE of LRM can be precisely adjusted from 84.1% to 100.7%, and a very high specific capacity of 330 mAh g−1 at 0.1 C, as well as outstanding rate capability with a fascinating specific capacity of 250 mAh g−1 at 5 C, are harvested. Theoretical calculations reveal that the introduced cation/anion double defects can reduce the diffusion barrier of Li+ ions, and in situ surface reconstruction layer can induce a self‐built‐in electric field to stabilize the surface lattice oxygen. Moreover, this facile interface engineering is universal and can enhance the ICEs of other kinds of LRM effectively. This work provides a valuable new idea for improving the comprehensive electrochemical performance of LRM through multistrategy collaborative interface engineering technology.
Introduced cation/anion double defects can reduce the interface charge transfer resistance and enhance the Li+ ion diffusion coefficient. The induced in situ surface reconstruction layer can increase the electronic conductivity and stabilize the surface lattice oxygen. As a result, the initial Coulombic efficiency of Li‐rich Mn‐based cathode material is controlled precisely.
Li‐rich cathode materials have attracted increasing attention because of their high reversible discharge capacity (>250 mA h g−1), which originates from transition metal (TM) ion redox reactions and ...unconventional oxygen anion redox reactions. However, many issues need to be addressed before their practical applications, such as their low kinetic properties and inefficient voltage fading. The development of cutting‐edge technologies has led to cognitive advances in theory and offer potential solutions to these problems. Herein, a recent in‐depth understanding of the mechanisms and the frontier electrochemical research progress of Li‐rich cathodes are reviewed. In addition, recent advances associated with various strategies to promote the performance and the development of modification methods are discussed. In particular, excluding Li‐rich Mn‐based (LRM) cathodes, other branches of the Li‐rich cathode materials are also summarized. The consistent pursuit is to obtain energy storage devices with high capacity, reliable practicability, and absolute safety. The recent literature and ongoing efforts in this area are also described, which will create more opportunities and new ideas for the future development of Li‐rich cathode materials.
The practical applications of Li‐rich cathode materials, especially Li‐rich Mn‐based (LRM) cathodes, are hindered by their inherent shortcomings. In this case, the recent understanding of complex reaction mechanisms, the novel modification methods, and the corresponding development trends are comprehensively reviewed. Additionally, other branches and the future opportunities of the Li‐rich cathode materials are also summarized.
The synergetic mechanism of chemisorption and catalysis play an important role in developing high‐performance lithium–sulfur (Li–S) batteries. Herein, a 3D lather‐like porous carbon framework ...containing Fe‐based compounds (including Fe3C, Fe3O4, and Fe2O3), named FeCFeOC, is designed as the sulfur host and the interlayer on separator. Due to the strong chemisorption and catalytic ability of FeCFeOC composite, the soluble lithium polysulfides (LiPSs) are first adsorbed and anchored on the surface of the FeCFeOC composite and then are catalyzed to accelerate their conversion reaction. In addition, the FexOy in Fe‐based compounds can spontaneously react with LiPSs to form magnetic FeSx species with a larger size, further blocking the penetration of LiPSs cross the separator. As a result, the assembled Li–S cells show excellent long‐term stability (748 mAh g−1 over 500 cycles at 1.0 C, and ≈0.036% decay per cycle for 1000 cycles at 3.0 C), a superb rate capability with 659 mAh g−1 at 5.0 C, and lower electrochemical polarization. This work introduces a feasible strategy to anchor and accelerate the conversion of LiPSs by designing the multifunctional Fe‐based compounds with high chemisorption and catalytic activity, which advances the large‐scale application of high‐performance Li–S batteries.
The carbon framework containing Fe‐based compounds (FeCFeOC) composite can first anchor the soluble LiPSs on the surface of FeCFeOC by strong chemisorption, and then its catalytic effect can accelerate LiPSs redox kinetics. Moreover, the FexOy in FeCFeOC composite can spontaneously react with LiPSs to form magnetic FeSx species with a larger size, further blocking the penetration of sulfur active materials cross the separator.
Single‐ion conducting polymer electrolytes are considered particularly attractive for realizing high‐performance solid‐state lithium‐metal batteries. Herein, a polysiloxane‐based single‐ion conductor ...(PSiO) is investigated. The synthesis is performed via a simple thiol‐ene reaction, yielding flexible and self‐standing polymer electrolyte membranes (PSiOM) when blended with poly(vinylidene fluoride‐co‐hexafluoropropylene) (PVdF‐HFP). When incorporating 57 wt% of organic carbonates, these polymer membranes provide a Li+ conductivity of >0.4 mS cm−1 at 20 °C and a wide electrochemical stability window of more than 4.8 V. This excellent electrochemical stability allows for the highly reversible cycling of symmetric Li||Li cells as well as high‐energy Li||LiNi0.6Mn0.2Co0.2O2 (NMC622) and Li||LiNi0.8Mn0.1Co0.1O2 (NMC811) cells for several hundred cycles at relatively high discharge and charge rates. Remarkably, Li||NMC811 cells with high mass loading cathodes provide more than 76% capacity retention at a high current density of 1.44 mA cm−2, thus rendering this polymer electrolyte suitable for high‐performance battery applications.
A polysiloxane‐based single‐ion conducting polymer electrolyte comprised of organic carbonates enables a high Li+ conductivity of >0.4 mS cm−1 (20 °C) and provides stable cycling in high‐energy Li||NMC622 and Li||NMC811 cells for several hundred cycles. Remarkably, the polymer‐based electrolyte can withstand current densities exceeding 5 mA cm–2 at reasonable specific capacities.
Manipulating the local electronic structure is employed to address the capacity/voltage decay and poor rate capability of Li‐rich layered cathodes (LLOs) via the dual‐doping of Na+ and F− ions, as ...well as the regulation of Li+/Ni2+ intermixing and the content of “LiOLi” configuration. The designed cathode exhibits a high initial Coulombic efficiency of about 90%, large specific capacity of 296 mAh g−1 and energy density of 1047 Wh kg−1 at 0.2 C, and a superior rate capability of 222 mAh g−1 at 5 C with a good capacity retention of 85.7% even after 500 cycles. And the operating voltage is increased without compromising the high‐capacity advantage. Such improved electrochemical performances primarily result from the band shift of the TM 3d‐O 2p and non‐bonding O‐2p to lower energy, which would decrease Li+ diffusion activation energy and increase oxygen vacancy forming energy, finally improving the Li+ diffusion kinetics and stabilizing lattice oxygen. Moreover, the increased “LiOLi” configuration in the Li2MnO3 phase via increasing the Mn concentration can increase the reversible capacity to offset the negative effect of inactive doping and Li+/Ni2+ intermixing. This strategy of modulating the local electronic structure of LLOs provides great potential to design high‐energy‐density Li‐ion batteries.
The local electronic structure is modulated effectively via adjusting the local atomic coordination, triggering the TM 3d‐O 2p bands and non‐bonding O‐2p bands to lower energy. The low‐energy shift quickens the Li+ diffusion kinetics and stabilizes the lattice oxygen. As a result, outstanding electrochemical performance is achieved.
Metal–sulfur batteries exhibit great potential as next‐generation rechargeable batteries due to the low sulfur cost and high theoretical energy density. Sodium–sulfur (Na–S) batteries present higher ...feasibility of long‐term development than lithium–sulfur (Li–S) batteries in technoeconomic and geopolitical terms. Both lithium and sodium are alkali metal elements with body‐centered cubic structures, leading to similar physical and chemical properties and exposing similar issues when employed as the anode in metal–sulfur batteries. Indeed, some inspiration for mechanism researches and strategies in Na–S systems comes from the more mature Li–S systems. However, the dissimilarities in microscopic characteristics determine that Na–S is not a direct Li–S analogue. Herein, the daunting challenges derived by the differences of fundamental characteristics in Na–S and Li–S systems are discussed. And the corresponding strategies in Na–S batteries are reviewed. Finally, general conclusions and perspectives toward the research direction are presented based on the dissimilarities between both systems. This review attempts to provide important insights to facilitate the assimilation of the available knowledge on Li–S systems for accelerating the development of Na–S batteries on the basis of their dissimilarities.
Sodium–sulfur (Na–S) batteries present higher feasibility of long‐term development than lithium–sulfur (Li–S) batteries in technoeconomic and geopolitical terms. This review summarizes the daunting challenges derived by the differences of the fundamental characteristics in Na–S and Li–S batteries and corresponding strategies based on Na metal anode, electrolyte systems, and S cathode.
Incarcerated Obturator Hernia Yang, Weisheng; Peng, Liang
The New England journal of medicine,
02/2024, Letnik:
390, Številka:
5
Journal Article
Recenzirano
An 84-year-old woman presented with a 12-hour history of left lower abdominal pain, nausea, and vomiting. CT of the abdomen revealed a loop of small bowel protruding through the left obturator canal.
Potassium‐ion batteries (PIBs) are promising alternatives to lithium‐ion batteries because of the advantage of abundant, low‐cost potassium resources. However, PIBs are facing a pivotal challenge to ...develop suitable electrode materials for efficient insertion/extraction of large‐radius potassium ions (K+). Here, a viable anode material composed of uniform, hollow porous bowl‐like hard carbon dual doped with nitrogen (N) and phosphorus (P) (denoted as N/P‐HPCB) is developed for high‐performance PIBs. With prominent merits in structure, the as‐fabricated N/P‐HPCB electrode manifests extraordinary potassium storage performance in terms of high reversible capacity (458.3 mAh g−1 after 100 cycles at 0.1 A g−1), superior rate performance (213.6 mAh g−1 at 4 A g−1), and long‐term cyclability (205.2 mAh g−1 after 1000 cycles at 2 A g−1). Density‐functional theory calculations reveal the merits of N/P dual doping in favor of facilitating the adsorption/diffusion of K+ and enhancing the electronic conductivity, guaranteeing improved capacity, and rate capability. Moreover, in situ transmission electron microscopy in conjunction with ex situ microscopy and Raman spectroscopy confirms the exceptional cycling stability originating from the excellent phase reversibility and robust structure integrity of N/P‐HPCB electrode during cycling. Overall, the findings shed light on the development of high‐performance, durable carbon anodes for advanced PIBs.
A viable anode material composed of nitrogen/phosphorus co‐doped hollow porous bowl‐like hard carbon is developed for potassium ion batteries. The resulting anode manifests prominent merits in structure, endowing it with extraordinary K+ storage capability. The K+ storage mechanisms are revealed through in‐depth studies by combining in situ TEM studies, ex situ microscopic, and Raman spectroscopy in conjunction with DFT calculations.
•A bibliometric analysis on Big Data and Business Intelligence from 1990 to 2016.•Big Data papers grow much faster than Business Intelligence papers•Computer Science and information systems are two ...core disciplines.•Most influential papers are identified and a research framework is proposed.
Business Intelligence that applies data analytics to generate key information to support business decision making, has been an important area for more than two decades. In the last five years, the trend of “Big Data” has emerged and become a core element of Business Intelligence research. In this article, we review academic literature associated with “Big Data” and “Business Intelligence” to explore the development and research trends. We use bibliometric methods to analyze publications from 1990 to 2017 in journals indexed in Science Citation Index Expanded (SCIE), Social Science Citation Index (SSCI) and Arts & Humanities Citation Index (AHCI). We map the time trend, disciplinary distribution, high-frequency keywords to show emerging topics. The findings indicate that Computer Science and management information systems are two core disciplines that drive research associated with Big Data and Business Intelligence. “Data mining”, “social media” and “information system” are high frequency keywords, but “cloud computing”, “data warehouse” and “knowledge management” are more emphasized after 2016.
Lithium–sulfur (Li–S) batteries are regarded as the most promising next‐generation energy storage systems due to their high energy density and cost‐effectiveness. However, their practical ...applications are seriously hindered by several inevitable drawbacks, especially the shuttle effects of soluble lithium polysulfides (LiPSs) which lead to rapid capacity decay and short cycling lifespan. This review specifically concentrates on the shuttle path of LiPSs and their interaction with the corresponding cell components along the moving way, systematically retrospect the recent advances and strategies toward polysulfides diffusion suppression. Overall, the strategies for the shuttle effect inhibition can be classified into four parts, including capturing the LiPSs in the sulfur cathode, reducing the dissolution in electrolytes, blocking the shuttle channels by functional separators, and preventing the chemical reaction between LiPSs and Li metal anode. Herein, the fundamental aspect of Li–S batteries is introduced first to give an in‐deep understanding of the generation and shuttle effect of LiPSs. Then, the corresponding strategies toward LiPSs shuttle inhibition along the diffusion path are discussed step by step. Finally, general conclusions and perspectives for future research on shuttle issues and practical application of Li–S batteries are proposed.
This review summarizes the recent advances and strategies to suppress the shuttle effect of lithium polysulfides (LiPSs) in lithium–sulfur batteries. These strategies are composed of using the modified sulfur hosts to immobilize LiPSs, electrolyte systems to alleviate shuttle behavior, functional separator to intercept LiPSs, and anode surface engineering to avoid the chemical reaction between LiPSs and Li.
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