2D materials and heterostructures have attracted significant attention for a variety of nanoelectronic and optoelectronic applications. At the atomically thin limit, the material characteristics and ...functionalities are dominated by surface chemistry and interface coupling. Therefore, methods for comprehensively characterizing and precisely controlling surfaces and interfaces are required to realize the full technological potential of 2D materials. Here, the surface and interface properties that govern the performance of 2D materials are introduced. Then the experimental approaches that resolve surface and interface phenomena down to the atomic scale, as well as strategies that allow tuning and optimization of interfacial interactions in van der Waals heterostructures, are systematically reviewed. Finally, a future outlook that delineates the remaining challenges and opportunities for 2D material interface characterization and control is presented.
Realistic applications of 2D materials require nanoscale characterization and control over surfaces and interfaces. After introducing related surface and interface phenomena, characterization techniques and control strategies that have been applied to the surfaces and interfaces of 2D materials and heterostructures are comprehensively reviewed. In addition, the remaining challenges and opportunities in this emerging field are delineated.
The transformation of digital computers from bulky machines to portable systems has been enabled by new materials and advanced processing technologies that allow ultrahigh integration of solid-state ...electronic switching devices. As this conventional scaling pathway has approached atomic-scale dimensions, the constituent nanomaterials (such as SiO2 gate dielectrics, poly-Si floating gates and Co–Cr–Pt ferromagnetic alloys) increasingly possess properties that are dominated by quantum physics. In parallel, quantum information science has emerged as an alternative to conventional transistor technology, promising new paradigms in computation, communication and sensing. The convergence between quantum materials properties and prototype quantum devices is especially apparent in the field of 2D materials, which offer a broad range of materials properties, high flexibility in fabrication pathways and the ability to form artificial states of quantum matter. In this Review, we discuss the quantum properties and potential of 2D materials as solid-state platforms for quantum-dot qubits, single-photon emitters, superconducting qubits and topological quantum computing elements. By focusing on the interplay between quantum physics and materials science, we identify key opportunities and challenges for the use of 2D materials in the field of quantum information science.
The invention and development of the laser have revolutionized science, technology, and industry. Metal halide perovskites are an emerging class of semiconductors holding promising potential in ...further advancing the laser technology. In this Review, we provide a comprehensive overview of metal halide perovskite lasers from the viewpoint of materials chemistry and engineering. After an introduction to the materials chemistry and physics of metal halide perovskites, we present diverse optical cavities for perovskite lasers. We then comprehensively discuss various perovskite lasers with particular functionalities, including tunable lasers, multicolor lasers, continuous-wave lasers, single-mode lasers, subwavelength lasers, random lasers, polariton lasers, and laser arrays. Following this a description of the strategies for improving the stability and reducing the toxicity of metal halide perovskite lasers is provided. Finally, future research directions and challenges toward practical technology applications of perovskite lasers are provided to give an outlook on this emerging field.
This review article provides a comprehensive overview of metal halide perovskite lasers from the viewpoint of materials chemistry and engineering.
Digital twin is a significant way to achieve smart manufacturing, and provides a new paradigm for fault diagnosis. Traditional data-based fault diagnosis methods mostly assume that the training data ...and test data are following the same distribution and can acquire sufficient data to train a reliable diagnosis model, which is unrealistic in the dynamic changing production process. In this paper, we present a two-phase digital-twin-assisted fault diagnosis method using deep transfer learning (DFDD), which realizes fault diagnosis both in the development and maintenance phases. At first, the potential problems that are not considered at design time can be discovered through front running the ultra-high-fidelity model in the virtual space, while a deep neural network (DNN)-based diagnosis model will be fully trained. In the second phase, the previously trained diagnosis model can be migrated from the virtual space to physical space using deep transfer learning for real-time monitoring and predictive maintenance. This ensures the accuracy of the diagnosis as well as avoids wasting time and knowledge. A case study about fault diagnosis using DFDD in a car body-side production line is presented. The results show the superiority and feasibility of our proposed method.
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•FGA is a nanograin layer of 500–800nm thick with grain size of 50nm.•Nanograin layer exists in both sides of fracture surface of FGA region.•Nanograins form at crack wake via ...contacting between originated crack surfaces.•Nanograins present for negative stress ratio cases, but vanish for R>0 cases.•Proposed Numerous Cyclic Pressing model explains FGA formation.
For high-strength steels, the crack initiation of very-high-cycle fatigue (VHCF) is commonly at the interior of material with fish-eye (FiE) morphology containing a fine-granular-area (FGA) surrounding an inclusion as crack origin, and FGA is regarded as the characteristic region of crack initiation. Here, we carefully examined the micro-morphology of FGA and FiE for two high-strength steels. The results revealed that the microscopic nature of FGA is a thin layer of nanograins. Then we proposed the formation mechanism of FGA: Numerous Cyclic Pressing (NCP) between originated crack surfaces, which causes grain refinement at originated crack wake and therefore the formation of FGA. The results of second set experiment showed that the cases with negative stress ratios exhibit the prevalence of nanograin layer in FGA region and the nanograin layer vanishes for the cases with positive stress ratios, which is a verification of the proposed NCP model.
Three‐dimensional (3D) metal‐halide perovskite solar cells (PSCs) have demonstrated exceptional high efficiency. However, instability of the 3D perovskite is the main challenge for industrialization. ...Incorporation of some long organic cations into perovskite crystal to terminate the lattice, and function as moisture and oxygen passivation layer and ion migration blocking layer, is proven to be an effective method to enhance the perovskite stability. Unfortunately, this method typically sacrifices charge‐carrier extraction efficiency of the perovskites. Even in 2D–3D vertically aligned heterostructures, a spread of bandgaps in the 2D due to varying degrees of quantum confinement also results in charge‐carrier localization and carrier mobility reduction. A trade‐off between the power conversion efficiency and stability is made. Here, by introducing 2D C6H18N2O2PbI4 (EDBEPbI4) microcrystals into the precursor solution, the grain boundaries of the deposited 3D perovskite film are vertically passivated with phase pure 2D perovskite. The phases pure (inorganic layer number n = 1) 2D perovskite can minimize photogenerated charge‐carrier localization in the low‐dimensional perovskite. The dominant vertical alignment does not affect charge‐carrier extraction. Therefore, high‐efficiency (21.06%) and ultrastable (retain 90% of the initial efficiency after 3000 h in air) planar PSCs are demonstrated with these 2D–3D mixtures.
High‐efficiency (21.06%) and durable 2D–3D vertical aligned perovskite solar cells (PSCs) with phase pure 2D perovskite are demonstrated. The phase pure 2D perovskite minimizes photo‐generated charge‐carrier localization in the low‐dimensional perovskite; the dominant vertical alignment does not affect charge‐carrier extraction. The traditional constraint of trade‐off between efficiency and stability in PSC is overcome.
Bauschinger effect is a well-known phenomenon, in which the tensile stress is higher than the reverse compressive stress. Here we report that the gradient structured copper exhibits an ...extraordinarily large Bauschinger effect. We propose to use the reverse yield softening, Δσb, as a quantitative parameter to represent the Bauschinger effect. Δσb evolves in the same trend as the back stress with pre-strain, and can be used to evaluate the effectiveness of a heterostructure in producing back stress for superior mechanical properties.
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The tumor hypoxic environment as well as photodynamic therapy (PDT)-induced hypoxia could severely limit the therapeutic efficacy of traditional PDT. Fortunately, the smart integration of ...hypoxia-responsive drug delivery system with PDT might be a promising strategy to enhance the PDT efficiency that is hindered by the hypoxic environment. Herein, a novel azobenzene (AZO) containing conjugated polymers (CPs)-based nanocarriers (CPs-CPT-Ce6 NPs) was constructed for the combination of PDT with chemotherapy, as well as to enhance the hypoxia-responsive drug release by light. The conjugated polymer chains, used as a matrix to prepare the CPs-CPT-Ce6 NPs, were beneficial for loading hydrophobic photosensitizers and chemotherapy drugs, to improve their cellular uptake. Moreover, the AZO group (−NN−) in CPs, which can be reduced and cleaved by azoreductase (a typical biomarker of hypoxia) under the hypoxic environment of tumor cells, acts as the hypoxia-responsive linker component. Upon laser irradiation, the CPs-CPT-Ce6 NPs could produce ROS for PDT and then facilitate the enhancement of tumor hypoxic condition, which could further promote the dissociation of CPs via reductive cleavage of AZO bridges to subsequently release cargos (chemotherapeutic drug, CPT) and then significantly enhance the killing effects to tumor cells that were resistant to PDT. Both in vitro and in vivo studies confirmed the improvement of synergistic therapeutic effects of our CPs-CPT-Ce6 NPs. This cascade responsive approach provides an excellent complementary mode for PDT and could open new insights for constructing programmable and controllable responsive systems in biomedical applications.
This study reports a photoelectrochemical biosensor for dopamine-loaded liposome-encoded magnetic beads cleaved by clustered regularly interspaced short palindromic repeats (CRISPR)/Cas 12a system ...for the quantification of human papilloma virus (HPV)-related DNA using neodymium-doped BiOBr nanosheets (Nd-BiOBr) as a photoactive matrix. Magnetic beads and dopamine-loaded liposomes are covalently attached to the both ends of ssDNA to construct dumbbell-shaped dopamine-loaded liposome-encoded magnetic bead (DLL-MB) probes. When the guide RNA binds to the target HPV-16, the ssDNA will be cleaved by Cas12a, thereby degrading the double dumbbell probes. After magnetic separation, the dissolved DLLs are treated with Triton X-100 to release the dopamine (as an electron donor), which was then detected by an amplified photocurrent using the Nd-BiOBr-based photoelectrode.
This study reports a photoelectrochemical biosensor for dopamine-loaded liposome-encoded magnetic beads cleaved by CRISPR/Cas 12a system for the quantification of human papilloma virus-related DNA using neodymium-doped BiOBr nanosheets.
The effects of stress ratio on high-cycle fatigue (HCF) and very-high-cycle fatigue (VHCF) behavior of a Ti–6Al–4V alloy were systematically investigated in this paper. Fatigue tests with ultrasonic ...frequency (20kHz) were performed on specimens of a bimodal Ti–6Al–4V alloy with stress ratios of −1, −0.5, −0.1, 0.1 and 0.5. Three types of crack initiation mode were observed on the fracture surfaces of the specimens that failed in the HCF and the VHCF regimes, which were explicitly classified as surface-without-facets, surface-with-facets and interior-with-facets. With the increase of stress ratio from −1 to 0.5, the number of specimens for surface-without-facets decreased, that for surface-with-facets increased, and that for interior-with-facets increased first and then decreased. For the failure types of surface-with-facets and interior-with-facets, the fatigue strength decreased sharply in the VHCF regime, and the S–N curve switched from an asymptote shape to a duplex shape. Then, a new model based on Poisson defect distribution was proposed to describe the effects of stress ratio on the occurrence of different failure types, i.e., the competition of alternative failure types. The observations also showed that there is a rough area at the crack initiation region for interior initiation cases, and the values of the stress intensity factor range for the rough area are within a small range, with the mean value being close to the threshold for the crack starting to grow in vacuum environment of the alloy. The estimated value of plastic zone size at the periphery of rough area is close to the average diameter of the primary α grains of the alloy.
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