We present an overview of the GBT Observations of TMC-1: Hunting Aromatic Molecules Large Program on the Green Bank Telescope. This and a related program were launched to explore the depth and ...breadth of aromatic chemistry in the interstellar medium at the earliest stages of star formation, following our earlier detection of benzonitrile (c-C6H5CN) in TMC-1. In this work, details of the observations, use of archival data, and data reduction strategies are provided. Using these observations, the interstellar detection of propargyl cyanide (HCCCH2CN) is described, as well as the accompanying laboratory spectroscopy. We discuss these results, and the survey project as a whole, in the context of investigating a previously unexplored reservoir of complex, gas-phase molecules in pre-stellar sources. A series of companion papers describe other new astronomical detections and analyses.
Using data from the Green Bank Telescope (GBT) Observations of TMC-1: Hunting for Aromatic Molecules (GOTHAM) survey, we report the first astronomical detection of the C10H− anion. The astronomical ...observations also provided the necessary data to refine the spectroscopic parameters of C10H−. From the velocity stacked data and the matched filter response, C10H− is detected at >9σ confidence level at a column density of 4.04−2.23+10.67×1011 cm−2. A dedicated search for the C10H radical was also conducted toward TMC-1. In this case, the stacked molecular emission of C10H was detected at a ∼3.2σ confidence interval at a column density of 2.02−0.82+2.68×1011 cm−2. However, as the determined confidence level is currently <5σ, we consider the identification of C10H as tentative. The full GOTHAM data set was also used to better characterize the physical parameters including column density, excitation temperature, line width, and source size for the C4H, C6H, and C8H radicals and their respective anions, and the measured column densities were compared to the predictions from a gas/grain chemical formation model and from a machine learning analysis. Given the measured values, the C10H−/C10H column density ratio is ∼2.0−1.6+5.9—the highest value measured between an anion and neutral species to date. Such a high ratio is at odds with current theories for interstellar anion chemistry. For the radical species, both models can reproduce the measured abundances found from the survey; however, the machine learning analysis matches the detected anion abundances much better than the gas/grain chemical model, suggesting that the current understanding of the formation chemistry of molecular anions is still highly uncertain.
Abstract
High-spatial-resolution observations of CO isotopologue line emission in protoplanetary disks at mid-inclinations (≈30°–75°) allow us to characterize the gas structure in detail, including ...radial and vertical substructures, emission surface heights and their dependencies on source characteristics, and disk temperature profiles. By combining observations of a suite of CO isotopologues, we can map the two-dimensional (
r
,
z
) disk structure from the disk upper atmosphere, as traced by CO, to near the midplane, as probed by less abundant isotopologues. Here, we present high-angular-resolution (≲0.″1 to ≈0.″2; ≈15–30 au) observations of CO,
13
CO, and C
18
O in either or both
J
= 2–1 and
J
= 3–2 lines in the transition disks around DM Tau, Sz 91, LkCa 15, and HD 34282. We derived line emission surfaces in CO for all disks and in
13
CO for the DM Tau and LkCa 15 disks. With these observations, we do not resolve the vertical structure of C
18
O in any disk, which is instead consistent with C
18
O emission originating from the midplane. Both the
J
= 2–1 and
J
= 3–2 lines show similar heights. Using the derived emission surfaces, we computed radial and vertical gas temperature distributions for each disk, including empirical temperature models for the DM Tau and LkCa 15 disks. After combining our sample with literature sources, we find that
13
CO line emitting heights are also tentatively linked with source characteristics, e.g., stellar host mass, gas temperature, disk size, and show steeper trends than seen in CO emission surfaces.
Abstract
High spatial resolution CO observations of midinclination (≈30°–75°) protoplanetary disks offer an opportunity to study the vertical distribution of CO emission and temperature. The ...asymmetry of line emission relative to the disk major axis allows for a direct mapping of the emission height above the midplane, and for optically thick, spatially resolved emission in LTE, the intensity is a measure of the local gas temperature. Our analysis of Atacama Large Millimeter/submillimeter Array archival data yields CO emission surfaces, dynamically constrained stellar host masses, and disk atmosphere gas temperatures for the disks around the following: HD 142666, MY Lup, V4046 Sgr, HD 100546, GW Lup, WaOph 6, DoAr 25, Sz 91, CI Tau, and DM Tau. These sources span a wide range in stellar masses (0.50–2.10
M
⊙
), ages (∼0.3–23 Myr), and CO gas radial emission extents (≈200–1000 au). This sample nearly triples the number of disks with mapped emission surfaces and confirms the wide diversity in line emitting heights (
z
/
r
≈ 0.1 to ≳0.5) hinted at in previous studies. We compute the radial and vertical CO gas temperature distributions for each disk. A few disks show local temperature dips or enhancements, some of which correspond to dust substructures or the proposed locations of embedded planets. Several emission surfaces also show vertical substructures, which all align with rings and gaps in the millimeter dust. Combining our sample with literature sources, we find that CO line emitting heights weakly decline with stellar mass and gas temperature, which, despite large scatter, is consistent with simple scaling relations. We also observe a correlation between CO emission height and disk size, which is due to the flared structure of disks. Overall, CO emission surfaces trace ≈2–5× gas pressure scale heights (H
g
) and could potentially be calibrated as empirical tracers of H
g
.
Recent measurements of carbon isotope ratios in both protoplanetary disks and exoplanet atmospheres have suggested a possible transfer of significant carbon isotope fractionation from disks to ...planets. For a clearer understanding of the isotopic link between disks and planets, it is important to measure the carbon isotope ratios in various species. In this paper, we present a detection of the 13CN N = 2 − 1 hyperfine lines in the TW Hya disk with the Atacama Large Millimeter/submillimeter Array. This is the first spatially resolved detection of 13CN in disks, which enables us to measure the spatially resolved 12CN/13CN ratio for the first time. We conducted nonlocal thermal equilibrium modeling of the 13CN lines in conjunction with previously observed 12CN lines to derive the kinetic temperature, H2 volume density, and column densities of 12CN and 13CN. The H2 volume density is found to range between (4 − 10) × 107 cm−3, suggesting that CN molecules mainly reside in the disk's upper layer. The 12CN/13CN ratio is measured to be 70−6+9 at 30 < r < 80 au from the central star, which is similar to the 12C/13C ratio in the interstellar medium. However, this value differs from the previously reported values found for other carbon-bearing molecules (CO and HCN) in the TW Hya disk. This could be self-consistently explained by different emission layer heights for different molecules combined with preferential sequestration of 12C into the solid phase toward the disk midplane. This study reveals the complexity of the carbon isotope fractionation operating in disks.
Abstract Much of the information gleaned from observations of star-forming regions comes from the analysis of their molecular emission spectra, particularly in the radio regime. The time-consuming ...nature of fitting synthetic spectra to observations interactively for such line-rich sources, however, often results in such analysis being limited to data extracted from a single-dish observation or a handful of pixels from an interferometric observation. Yet, star-forming regions display a wide variety of physical conditions that are difficult, if not impossible, to accurately characterize with such a limited number of spectra. We have developed an automated fitting routine that visits every pixel in the field of view of an Atacama Large Millimeter/submillimeter Array (ALMA) data cube and determines the best-fit physical parameters, including excitation temperature and column densities, for a given list of molecules. In this proof-of-concept work, we provide an overview of the fitting routine and apply it to 0.″26, 1.1 km s −1 resolution ALMA observations of two sites of massive star formation in NGC 6334I. Parameters were found for 21 distinct molecules by generating synthetic spectra across 7.48 GHz of spectral bandwidth between 280 and 351 GHz. Spatial images of the derived parameters for each of the >8000 pixels are presented with special attention paid to the C 2 H 4 O 2 isomers and their relative variations. We highlight the greater scientific utility of the column density and velocity images of individual molecules compared to traditional moment maps of single transitions.
Abstract
Polycyclic aromatic hydrocarbons (PAHs) have long been invoked in the study of interstellar and protostellar sources, but the unambiguous identification of any individual PAH has proven ...elusive until very recently. As a result, the formation mechanisms for this important class of molecules remain poorly constrained. Here we report the first interstellar detection of a pure hydrocarbon PAH, indene (C
9
H
8
), as part of the GBT Observations of TMC-1: Hunting for Aromatic Molecules (GOTHAM) survey. This detection provides a new avenue for chemical inquiry, complementing the existing detections of CN-functionalized aromatic molecules. From fitting the GOTHAM observations, indene is found to be the most abundant organic ring detected in TMC-1 to date. And from astrochemical modeling with
nautilus
, the observed abundance is greater than the model’s prediction by several orders of magnitude, suggesting that current formation pathways in astrochemical models are incomplete. The detection of indene in relatively high abundance implies related species such as cyanoindene, cyclopentadiene, toluene, and styrene may be detectable in dark clouds.
Abstract At centimeter wavelengths, single-dish observations have suggested that the Sagittarius (Sgr) B2 molecular cloud at the Galactic Center hosts weak maser emission from several organic ...molecules, including CH 2 NH, HNCNH, and HCOOCH 3 . However, the lack of spatial distribution information on these new maser species has prevented us from assessing the excitation conditions of the maser emission as well as their pumping mechanisms. Here, we present a mapping study toward Sgr B2 north (N) to locate the region where the complex maser emission originates. We report the first detection of the Class I methanol (CH 3 OH) maser at 84 GHz and the first interferometric map of the methanimine (CH 2 NH) maser at 5.29 GHz toward this region. In addition, we present a tool for modeling and fitting the unsaturated molecular maser signals with non-LTE radiative transfer models and Bayesian analysis using the Markov Chain Monte Carlo approach. These enable us to quantitatively assess the observed spectral profiles. The results suggest a two-chain-clump model for explaining the intense CH 3 OH Class I maser emission toward a region with low continuum background radiation. By comparing the spatial origin and extent of maser emission from several molecular species, we find that the 5.29 GHz CH 2 NH maser has a close spatial relationship with the 84 GHz CH 3 OH Class I masers. This relationship serves as observational evidence to suggest a similar collisional pumping mechanism for these maser transitions.
Abstract
Here we present high-resolution (15–24 au) observations of CO isotopologue lines from the Molecules with ALMA on Planet-forming Scales (MAPS) ALMA Large Program. Our analysis employs ...observations of the (
J
= 2–1) and (1–0) lines of
13
CO and C
18
O and the (
J
= 1–0) line of C
17
O for five protoplanetary disks. We retrieve CO gas density distributions, using three independent methods: (1) a thermochemical modeling framework based on the CO data, the broadband spectral energy distribution, and the millimeter continuum emission; (2) an empirical temperature distribution based on optically thick CO lines; and (3) a direct fit to the C
17
O hyperfine lines. Results from these methods generally show excellent agreement. The CO gas column density profiles of the five disks show significant variations in the absolute value and the radial shape. Assuming a gas-to-dust mass ratio of 100, all five disks have a global CO-to-H
2
abundance 10–100 times lower than the interstellar medium ratio. The CO gas distributions between 150 and 400 au match well with models of viscous disks, supporting the long-standing theory. CO gas gaps appear to be correlated with continuum gap locations, but some deep continuum gaps do not have corresponding CO gaps. The relative depths of CO and dust gaps are generally consistent with predictions of planet–disk interactions, but some CO gaps are 5–10 times shallower than predictions based on dust gaps. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.
H2CO is one of the most abundant organic molecules in protoplanetary disks and can serve as a precursor to more complex organic chemistry. We present an Atacama Large Millimeter/submillimeter Array ...survey of H2CO toward 15 disks covering a range of stellar spectral types, stellar ages, and dust continuum morphologies. H2CO is detected toward 13 disks and tentatively detected toward a fourteenth. We find both centrally peaked and centrally depressed emission morphologies, and half of the disks show ring-like structures at or beyond expected CO snowline locations. Together these morphologies suggest that H2CO in disks is commonly produced through both gas-phase and CO-ice-regulated grain-surface chemistry. We extract disk-averaged and azimuthally-averaged H2CO excitation temperatures and column densities for four disks with multiple H2CO line detections. The temperatures are between 20-50 K, with the exception of colder temperatures in the DM Tau disk. These temperatures suggest that H2CO emission in disks generally emerges from the warm molecular layer, with some contributions from the colder midplane. Applying the same H2CO excitation temperatures to all disks in the survey, we find that H2CO column densities span almost three orders of magnitude (∼5 × 1011-5 × 1014 cm−2). The column densities appear uncorrelated with disk size and stellar age, but Herbig Ae disks may have less H2CO compared to T Tauri disks, possibly because of less CO freeze-out. More H2CO observations toward Herbig Ae disks are needed to confirm this tentative trend, and to better constrain under which disk conditions H2CO and other oxygen-bearing organics efficiently form during planet formation.
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