Galah is an ongoing high-resolution spectroscopic survey with the goal of disentangling the formation history of the Milky Way using the fossil remnants of disrupted star formation sites that are now ...dispersed around the Galaxy. It is targeting a randomly selected magnitude-limited (V ≤ 14) sample of stars, with the goal of observing one million objects. To date, 300,000 spectra have been obtained. Not all of them are correctly processed by parameter estimation pipelines, and we need to know about them. We present a semi-automated classification scheme that identifies different types of peculiar spectral morphologies in an effort to discover and flag potentially problematic spectra and thus help to preserve the integrity of the survey results. To this end, we employ the recently developed dimensionality reduction technique t-SNE (t-distributed stochastic neighbor embedding), which enables us to represent the complex spectral morphology in a two-dimensional projection map while still preserving the properties of the local neighborhoods of spectra. We find that the majority (178,483) of the 209,533 Galah spectra considered in this study represents normal single stars, whereas 31,050 peculiar and problematic spectra with very diverse spectral features pertaining to 28,579 stars are distributed into 10 classification categories: hot stars, cool metal-poor giants, molecular absorption bands, binary stars, H /Hβ emission, H /Hβ emission superimposed on absorption, H /Hβ P-Cygni, H /Hβ inverted P-Cygni, lithium absorption, and problematic. Classified spectra with supplementary information are presented in the catalog, indicating candidates for follow-up observations and population studies of the short-lived phases of stellar evolution.
ABSTRACT A large sample of over 38,000 chromospherically active candidate solar-like stars and cooler dwarfs from the RAVE survey is addressed in this paper. An improved activity identification with ...respect to the previous study was introduced to build a catalog of field stars in the solar neighborhood with an excess emission flux in the calcium infrared triplet wavelength region. The central result of this work is the calibration of the age-activity relation for main-sequence dwarfs in a range from a few up to a few Gyr. It enabled an order of magnitude age estimation of the entire active sample. Almost 15,000 stars are shown to be younger than and ∼2000 younger than . The young age of the most active stars is confirmed by their position off the main sequence in the J − K versus diagram showing strong ultraviolet excess, mid-infrared excess in the J − K versus diagram, and very cool temperatures ( ). They overlap with the reference pre-main-sequence RAVE stars often displaying X-ray emission. The activity level increasing with the color reveals their different nature from the solar-like stars and probably represents an underlying dynamo-generating magnetic fields in cool stars. Of the RAVE objects from DR5, 50% are found in the TGAS catalog and supplemented with accurate parallaxes and proper motions by Gaia. This makes the database of a large number of young stars in a combination with RAVE's radial velocities directly useful as a tracer of the very recent large-scale star formation history in the solar neighborhood. The data are available online in the Vizier database.
ABSTRACT Data Release 5 (DR5) of the Radial Velocity Experiment (RAVE) is the fifth data release from a magnitude-limited ( ) survey of stars randomly selected in the Southern Hemisphere. The RAVE ...medium-resolution spectra ( ) covering the Ca-triplet region (8410-8795 ) span the complete time frame from the start of RAVE observations in 2003 to their completion in 2013. Radial velocities from 520,781 spectra of 457,588 unique stars are presented, of which 255,922 stellar observations have parallaxes and proper motions from the Tycho-Gaia astrometric solution in Gaia DR1. For our main DR5 catalog, stellar parameters (effective temperature, surface gravity, and overall metallicity) are computed using the RAVE DR4 stellar pipeline, but calibrated using recent K2 Campaign 1 seismic gravities and Gaia benchmark stars, as well as results obtained from high-resolution studies. Also included are temperatures from the Infrared Flux Method, and we provide a catalog of red giant stars in the dereddened color interval (0.50, 0.85) for which the gravities were calibrated based only on seismology. Further data products for subsamples of the RAVE stars include individual abundances for Mg, Al, Si, Ca, Ti, Fe, and Ni, and distances found using isochrones. Each RAVE spectrum is complemented by an error spectrum, which has been used to determine uncertainties on the parameters. The data can be accessed via the RAVE Web site or the VizieR database.
We present part 2 of the sixth and final Data Release (DR6) of the Radial Velocity Experiment (Rave), a magnitude-limited ( ) spectroscopic survey of Galactic stars randomly selected in Earth's ...southern hemisphere. The Rave medium-resolution spectra (R ∼ 7500) cover the Ca triplet region (8410-8795 ) and span the complete time frame from the start of Rave observations on 2003 April 12 to their completion on 2013 April 4. In the second of two publications, we present the data products derived from 518,387 observations of 451,783 unique stars using a suite of advanced reduction pipelines focusing on stellar atmospheric parameters, in particular purely spectroscopically derived stellar atmospheric parameters ( , , and the overall metallicity), enhanced stellar atmospheric parameters inferred via a Bayesian pipeline using Gaia DR2 astrometric priors, and asteroseismically calibrated stellar atmospheric parameters for giant stars based on asteroseismic observations for 699 K2 stars. In addition, we provide abundances of the elements Fe, Al, and Ni, as well as an overall /Fe ratio obtained using a new pipeline based on the GAUGUIN optimization method that is able to deal with variable signal-to-noise ratios. The Rave DR6 catalogs are cross-matched with relevant astrometric and photometric catalogs, and are complemented by orbital parameters and effective temperatures based on the infrared flux method. The data can be accessed via the Rave website (http://rave-survey.org) or the Vizier database.
The Radial Velocity Experiment (Rave) is a magnitude-limited (9 < I < 12) spectroscopic survey of Galactic stars randomly selected in Earth's southern hemisphere. The Rave medium-resolution spectra ...(R ∼ 7500) cover the Ca-triplet region (8410-8795 ). The sixth and final data release (DR6) is based on 518,387 observations of 451,783 unique stars. Rave observations were taken between 2003 April 12 and 2013 April 4. Here we present the genesis, setup, and data reduction of Rave as well as wavelength-calibrated and flux-normalized spectra and error spectra for all observations in Rave DR6. Furthermore, we present derived spectral classification and radial velocities for the Rave targets, complemented by cross-matches with Gaia DR2 and other relevant catalogs. A comparison between internal error estimates, variances derived from stars with more than one observing epoch, and a comparison with radial velocities of Gaia DR2 reveals consistently that 68% of the objects have a velocity accuracy better than 1.4 km s-1, while 95% of the objects have radial velocities better than 4.0 km s-1. Stellar atmospheric parameters, abundances and distances are presented in a subsequent publication. The data can be accessed via the Rave website (http://rave-survey.org) or the Vizier database.
This paper presents the detailed abundances and r-process classifications of 126 newly identified metal-poor stars as part of an ongoing collaboration, the R-Process Alliance. The stars were ...identified as metal-poor candidates from the RAdial Velocity Experiment (RAVE) and were followed up at high spectral resolution (R ∼ 31,500) with the 3.5 m telescope at Apache Point Observatory. The atmospheric parameters were determined spectroscopically from Fe i lines, taking into account non-LTE corrections and using differential abundances with respect to a set of standards. Of the 126 new stars, 124 have Fe/H < −1.5, 105 have Fe/H < −2.0, and 4 have Fe/H < −3.0. Nine new carbon-enhanced metal-poor stars have been discovered, three of which are enhanced in r-process elements. Abundances of neutron-capture elements reveal 60 new r-I stars (with +0.3 ≤ Eu/Fe ≤ +1.0 and Ba/Eu < 0) and 4 new r-II stars (with Eu/Fe > +1.0). Nineteen stars are found to exhibit a "limited-r" signature (Sr/Ba > +0.5, Ba/Eu < 0). For the r-II stars, the second- and third-peak main r-process patterns are consistent with the r-process signature in other metal-poor stars and the Sun. The abundances of the light, , and Fe-peak elements match those of typical Milky Way (MW) halo stars, except for one r-I star that has high Na and low Mg, characteristic of globular cluster stars. Parallaxes and proper motions from the second Gaia data release yield UVW space velocities for these stars that are consistent with membership in the MW halo. Intriguingly, all r-II and the majority of r-I stars have retrograde orbits, which may indicate an accretion origin.
A new moderately r-process-enhanced metal-poor star, RAVE J093730.5−062655, has been identified in the Milky Way halo as part of an ongoing survey by the R-Process Alliance. The temperature and ...surface gravity indicate that J0937−0626 is likely a horizontal branch star. At Fe/H = −1.86, J0937−0626 is found to have subsolar X/Fe ratios for nearly every light, , and Fe-peak element. The low /Fe ratios can be explained by an ∼0.6 dex excess of Fe; J0937−0626 is therefore similar to the subclass of "iron-enhanced" metal-poor stars. A comparison with Milky Way field stars at Fe/H = −2.5 suggests that J0937−0626 was enriched in material from an event, possibly a Type Ia supernova, that created a significant amount of Cr, Mn, Fe, and Ni and smaller amounts of Ca, Sc, Ti, and Zn. The r-process enhancement of J0937−0626 is likely due to a separate event, which suggests that its birth environment was highly enriched in r-process elements. The kinematics of J0937−0626, based on Gaia DR2 data, indicate a retrograde orbit in the Milky Way halo; J0937−0626 was therefore likely accreted from a dwarf galaxy that had significant r-process enrichment.
Lipophilicity, a very important parameter in the potential biological activities of molecules, was investigated for newly synthesized N-substituted-2-phenylacetamide derivatives. The determination ...was carried out in two ways: first experimentally, by applying thin-layer chromatography (TLC) on reversed-phase TLC (RPTLC) RP18F254s in the presence of one protic (methanol) and one aprotic solvent (acetonitrile) and then mathematically, by using different software packages. The intercept of the linear dependence between volume fractions of the organic solvent and the retention parameters obtained by TLC is known as the retention chromatographic constant, R
M
0, while the slope represents the m value. In order to establish the dependences between the partition coefficient, log P as the standard measure of lipophilicity and the alternative lipophilic parameters obtained experimentally by TLC, R
M
0 and m values, linear regression analysis and multivariate methods, cluster analysis (CA) and principal component analysis (PCA), were used. All applied methods gave approximately similar results. Although there is a linear dependence between the two chromatographic parameters, the retention constant, R
M
0, and the m values, only R
M
0 shows suitable similarity with the standard measure of lipophilicity of the investigated N-substituted-2-phenylacetamide derivatives at the given conditions. The existence of this resemblance proves that the chromatographic retention constant, R
M
0, obtained by RPTLC could be successfully used for the description of lipophilicity of investigated compounds. On the other hand, the results confirmed that the applied linear regression analysis and the multivariate analysis (CA and PCA) have the ability to compare lipophilic parameters of the investigated phenylacetamide derivatives obtained in different ways.
The adsorption of several anionic dyes on nanosize alumina-modified silica particles of different compositions and modal sizes has been studied. These silica cores have the same surface properties as ...alumina dispersed in aqueous solutions. The negatively charged dyes are electrostatically attracted to positively charged cores and chemisorbed by forming a surface Al lake. The application of so obtained pigments in the preparation of color films and their optical characteristics are described.