In this study, we prepared strontium-doped lanthanum ferrites with the perovskite-type structure for application as solid oxide fuel cell (SOFC) cathodes. We used the Pechini method to prepare ...strontium-doped lanthanum ferrites with the strontium:lanthanum molar ratios of 20:80 and 40:60. The resulting doped materials were characterized using various analytical tools. The calcination process was conducted at 450 °C because above this temperature, the stabilization of mass loss occurred and no phase transformation was observed. The X-ray diffraction results confirmed the mixing of the powder phases after the calcination process and the presence of a single powder phase in the air-sintered samples. The high-resolution transmission electron microscopy results revealed the presence of agglomerated nanoparticles smaller than 20 nm in size in the samples. The electrochemical impedance spectroscopy results revealed that the sample with 20% strontium exhibited a conductivity of 3.9 × 10−3 S cm−1 at 95 °C and activation energy of 0.37 eV. In contrast, the sample with 40% strontium exhibited a conductivity of 3.5 × 10−2 S cm−1 and activation energy of 0.29 eV. These results suggest that with an increase in the strontium content, the conductivity of the samples increased, where as the activation energy of the conduction process decreased. Therefore, the ferrites synthesized in this work are potential catalysts for SOFC cathodes.
•Provides Stress Intensity Factor solutions for Fretting Fatigue.•Presents the Stress Gradient Factor applied to Fretting Fatigue.•Presents a set of results for the Stress Gradient Factor considering ...different geometries, materials and loadings.•2D SIF fretting solution could be applied to different methods of fracture analysis.
This paper presents stress intensity factor (SIF) solutions for fretting fatigue conditions by including a stress gradient factor (SGF) to correct the classic geometry factor for tension semi-infinite strip (TSIS) specimen. This gradient factor considers the stress gradient due to the pressure of the pad on the surface of the specimen, which creates a high concentration of stresses around the contact of the bodies. To obtain these solutions, 2D finite element model simulations were performed varying important fretting parameters, namely: coefficient of friction, bulk stress intensity, pad radius and material. All configurations respected a partial slip contact condition and the results obtained show agreement with the ones obtained analytically. Weight functions were used to obtain stress intensity factors under mode I, then to compute the SGF, which were fit into equations with a unique structure, varying only coefficients. To consider real problems, a 3D correction factor was introduced. The final SGF presented a general form to compute SIF under fretting conditions when applied in suggested methods, such as: Strain-based Fracture Mechanics, Theory of Critical Distances (TCD) and Stress Gradient.
Doped CeGdO and codoped CeGdOSmO compositions were synthesized, giving rise to nanoparticulate powders. Ionic conductivities at bulk and grain boundaries of the sintered samples were determined, ...exhibiting increased conductivity in the samaria-codoped samples. Scanning electron microscopy (SEM) showed a significant reduction in the grain size of samaria-codoped electrolytes. This reduced grain size of the codoped samples caused a reduction in Schottky barrier height, increasing oxygen vacancy concentration in the space-charge layer of the grain boundary and culminating in greater ionic conductivity in the boundary region. For the gadolinium doped samples, high resolution transmission electron microscopy images at grains showed the presence of large cluster of defects (nanodomains), hindering the movement of charge carriers and reducing ionic conductivity. However, the samaria-codoped system displayed better homogeneity at atomic level, resulting in reduced oxygen vacancy ordering and, consequently, smaller nanodomains and higher bulk (grain) conductivity. The reduced grain sizes and smaller nanodomains caused by codoping favor the ionic conductivity of ceria-based ceramics, doped with gadolinia and codoped with samaria.
Fatigue and microhardness of 6201 wire of overhead conductor Diniz, Layse Mendes; Reinke, Gustavo; Badibanga, Remy Kalombo ...
Journal of the Brazilian Society of Mechanical Sciences and Engineering,
05/2022, Letnik:
44, Številka:
5
Journal Article
Wind-induced fatigue failure frequently occurs in the electric conductor, causing the electrical distribution system to lose reliability. In this work, two electric conductors ("1" and "2") were ...tested under fatigue. Both were manufactured with the same aluminum alloy (6201) and submitted to the same T81 heat treatment. However, the fatigue life of one conductor was around three times shorter. Intending to identify the likely causes of this difference, this study investigated the influence of heat treatment on static and dynamic mechanical properties of aluminum wires of an electric conductor. Wires removed from the conductors were subjected to heat treatments of solution at 470°, 510°, and 550 °C and aging at 170 °C at different times. Then, in selected samples, mechanical properties were determined to evaluate the influence of solution and aging on these properties. Among the solubilized and aged wires, the sample solubilized at 550 °C and aged for 20 h (S5E5) showed lower elongation (2.49%) and higher values of microhardness (~ 83HV1), tensile strength (231.0 MPa), yield strength (209.0 MPa), and fatigue strength depicted in
S
–
N
curve, when compared to the sample only solubilized at 550 °C. There was an increase in the fatigue strength of the wires for longer aging times. The reduced hardening and tensile strength values of conductor "1" wires compared to conductor "2" are associated with different heat treatment parameters applied to each conductor during the manufacturing process. Microstructural analyses showed that conductor "2" wires and those subjected to longer aging times generated precipitates in higher numbers, with smaller size and better distribution in the aluminum matrix. The deformation fields adjacent to these precipitates caused by aging acted as obstacles and promoted obstruction/delay in the movement of the dislocations during the fatigue test, resulting in higher fatigue strength values for the conductor “2” and the S5E5 wire sample.
•Lifetime of overhead conductors can be improved using CrN coated suspension clamps.•Deep cryogenic treatments improved the fretting fatigue resistance of aluminum.•Stick-slip regimes generate ...material transfer from the conductor to the clamps.•CrN reduced clamp damage and material transfer from the conductor to the clamps.•Aluminum oxide wear debris are mainly generated when full relative slip occurs.
As commonly known, the endurance of overhead conductors is limited by fretting fatigue. The most severe fretting fatigue damage occurrence is the suspension clamp, as a superposition of many different loads occurs in the conductor/clamp assembly. Therefore, this paper focuses on two modification methods, which aim to reduce the fretting fatigue loading in such assemblies. The investigated modification methods are a deep cryogenic treatment and a surface coating. To study the effect of both methods on the duration of overhead conductors, comparative fretting fatigue tests with real conductor/clamp contacts were carried out. A reduced amount of wire breaks was found for both modification methods. Especially the first wire break occurred significantly delayed using deep cryogenic treated and coated suspension clamps (20% for the deep cryogenic treated and 60% for the tests with coated clamps). The post mortem analysis showed severe damage marks in the suspension clamps. The use of the surface coating led to a reduced amount of damage in the suspension clamps.
Solid electrolyte powders based on gadolium-doped and samaria-codoped ceria of compositions Ce0.8Gd0.2−xSmxO1.9 (x = 0.00; 0.01; 0.03; 0.05) were sintered using the polymeric precursor method ...(Pechini). The X-ray diffractometry results confirmed the formation of a single crystalline phase, that is, a solid solution. Test specimens were compacted using uniaxial cold pressing followed by two-stage sintering. Relative densities were higher than 96% of theoretical density in all the samples. Ionic conductivity was determined using impedance spectroscopy, obtaining values of 10−2Scm−1 at 700°C, with the best results for codoped electrolytes, primarily the Ce0.8Gd0.15Sm0.05O1.9. system. This study aimed at correlating ionic conductivity variations of codoped electrolytes with microstructural alterations (on a nanometric scale) resulting from the addition of codopants. Energy dispersive spectroscopy (EDS) was used to analyze the grain boundary compositions of the electrolytes produced and assess possible dopant segregation in these regions. Interplanar spacings corresponding to the crystallographic planes of the cubic (fluorite-type) phase were identified using high-resolution transmission electron microscopy (HRTEM) images. Extra diffraction spots and diffuse stains were observed in the doped and codoped electrolytes, using selected area electron diffraction (SAED), confirming the presence of amorphous nanodomains at the atomic level. However, the codoped system exhibited diffraction patterns with no diffuse stains, indicating that codoping favored obtaining nanodomain-free regions. These regions displayed better structural homogeneity, which may explain the enhanced ionic conductivity in codoped systems.
This work evaluates the effects of grain growth and tetragonality of the t-ZrO2 phase on the mechanical properties of 3Y-TZP ceramics. Samples were sintered at 1475 °C for 2 h, and at 1600 °C for 2, ...12, or 24 h. After sintering, the tetragonal ZrO2 polytypes t and t′ were observed under all sintering conditions, while a residual content of monoclinic ZrO2 was detected in samples sintered at 1600 °C for 24 h. The average grain size was found to vary from 0.65 ± 0.10 to 2.20 ± 0.35 μm. Moreover, zirconia ceramics sintered at 1475 °C for 2 h exhibit higher flexural strength (1210 ± 85 MPa), while samples sintered at 1600 °C for 24 h exhibit the lowest flexural strength (910 ± 90 MPa). These results were related to the progressive formation of Y3+-rich grains (t′-ZrO2) due to the grain boundary segregation-induced phase (GBSIPT) mechanism. Due to the high stabilizer concentration in the solid solution, these grains present lower tetragonality, being highly stable at room temperature. Consequently, the observed strength reduction of samples sintered at 1600 °C for 24 h is related to the presence of the t′-ZrO2 phase, which is less prompt to the phase transformation toughening process, limiting shielding zones’ effectiveness at the crack tip.
Superalloys are used primarily for the aerospace, automotive, and petrochemical industries. These applications require materials with high creep resistance. In this work, evaluation of creep ...resistance and microstructural characterization were carried out at two new nickel intermediate content alloys for application in aerospace industry and in high performance valves for automotive applications (alloys VAT 32 and VAT 36). The alloys are based on a high nickel chromium austenitic matrix with dispersion of intermetallic L12 and phases containing different (Nb,Ti)C carbides. Creep tests were performed at constant load, in the temperature range of 675–750 °C and stress range of 500–600 MPa. Microstructural characterization and failure analysis of fractured surfaces of crept samples were carried out with optical and scanning electron microscopy with EDS. Phases were identified by Rietveld refinement. The results showed that the superalloy VAT 32 has higher creep resistance than the VAT 36. The superior creep resistance of the alloy VAT 32 is related to its higher fraction of carbides (Nb,Ti)C and intermetallic L12 provided by the amount of carbon, titanium, and niobium in its chemical composition and subsequent heat treatment. During creep deformation these precipitates produce anchoring effect of grain boundaries, hindering relative slide between grains and therefore inhibiting crack formation. These volume defects act also as obstacles to dislocation slip and climb, decreasing the creep rate. Failure analysis of surface fractures of crept samples showed intergranular failure mechanism at crack origin for both alloys VAT 36 and VAT 32. Intergranular fracture involves nucleation, growth, and subsequent binding of voids. The final fractured portion showed transgranular ductile failure, with dimples of different shapes, generated by the formation and coalescence of microcavities with dissimilar shape and sizes. The occurrence of a given creep mechanism depends on the test conditions. At creep tests of VAT 32 and VAT 36, for lower stresses and higher temperature, possible dislocation climb over carbides and precipitates would prevail. For higher stresses and intermediate temperatures shear mechanisms involving stacking faults presumably occur over a wide range of experimental conditions.
RESUMO Com a necessidade de aperfeiçoamento do processo de transmissão e distribuição de energia elétrica, as indústrias e concessionárias desse setor estão em busca de componentes mais otimizados ...para suas linhas de transmissão. Em consequência, há a necessidade de aprimorar a formação do cabo condutor, que é o elemento mais oneroso das linhas elétricas. Nestas circunstâncias, condutores formados apenas por fios de alumínio aparentam ser mais vantajosos em relação aos cabos com alma de aço, obtendo melhores índices de ampacidade/peso, diminuindo assim, o custo de transmissão. Neste cenário, o objetivo deste artigo, foi verificar a influência do fenômeno de fadiga por fretting sob condições controladas, nos fios de liga de alumínio AA 6201 T81 e AA 1120 H19, que formam os condutores CAL 900 MCM e CAL 823 MCM, respectivamente. Para alcançar tal fim, criou-se um programa experimental capaz de adquirir os dados sobre a resistência à fadiga dos cabos condutores e dos fios de forma separada, a fim de analisar a influência do fretting sob o parâmetro de carga normal de contato de 750 N. Ao examinar os resultados, o condutor CAL 900 MCM obteve a menor resistência à fadiga, apesar de ser constituído por uma liga com melhores propriedades mecânicas. O mesmo resultado foi obtido nos ensaios de fadiga por fretting nos fios, deste modo, pôde-se inferir que a liga AA 6201 T81, embora possua melhor resistência à fadiga, ela é mais suscetível a falha na presença de fretting quando comparada a liga AA 1120 H19.
ABSTRACT The electric transmission and distribution industries and utilities are looking for the most optimized components for their transmission lines. Thus, there is a need to improve the formation of the overhead conductor, which is the costliest element of electric transmission lines. Under these circumstances, conductors formed solely of aluminum wires appear to be more advantageous over aluminum conductor steel reinforced, obtaining better ampacity/weight ratios, thus lowering the transmission cost. The objective of this article was to verify the influence of the fretting fatigue phenomenon under controlled conditions, on the AA 6201 T81 and AA 1120 H19 aluminum alloy wires, which form the overhead conductors CAL 900 MCM and CAL 823 MCM, respectively. To achieve these goals, an experimental program was created capable of acquiring the data on the fatigue life of the overhead conductors and the wires separately, in order to verify the influence of fretting under a 750 N normal contact load parameter. In the results, the CAL 900 MCM achieved the lowest fatigue life, despite it made of an alloy with better mechanical properties. The same result was obtained in the fretting fatigue tests on wires, so it can be inferred that the AA 6201 T81 alloy, although it has better fatigue resistance, is more susceptible to failure in the presence of fretting when compared to AA 1120 H19 alloy.
In this work was obtained solid electrolytes of fully stabilized zircônia with doped of 10 and 12 mol% of Re2O3 (mixed oxides rare earth), for use in oxygen sensors and or fuel cells. The specimens ...were prepared by uniaxial pressing and sintered using two heating schedules, S1 and S2. Impedance diagrams show that the crystalline phases and the grain size change the electrical behavior of the ceramics. The sample with the best electrical performance was obtained with 10 mol% doped and was sintered with the curve S1. The value of the total conductivity of this sample was 2,85x10-3 W -1.cm-1 (taken at 600 ° C). When making a comparison between this values of conductivity with the reported in the literature is identified similarity with or traditional system zirconia-yttria the most widely used commercially as electrolyte oxygen sensors and fuel cells, confirming the potential use of the oxides mixed rare earth for these specific applications.
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