The SARS-CoV-2 pandemic has highlighted the weaknesses of relying on single-use mask and respirator personal protective equipment (PPE) and the global supply chain that supports this market. There ...have been no major innovations in filter technology for PPE in the past two decades. Non-woven textiles used for filtering PPE are single-use products in the healthcare environment; use and protection is focused on preventing infection from airborne or aerosolized pathogens such as Influenza A virus or SARS-CoV-2. Recently, C-H bond activation under mild and controllable conditions was reported for crosslinking commodity aliphatic polymers such as polyethylene and polypropylene. Significantly, these are the same types of polymers used in PPE filtration systems. In this report, we take advantage of this C-H insertion method to covalently attach a photosensitizing zinc-porphyrin to the surface of a melt-blow non-woven textile filter material. With the photosensitizer covalently attached to the surface of the textile, illumination with visible light was expected to produce oxidizing
O
/ROS at the surface of the material that would result in pathogen inactivation. The filter was tested for its ability to inactivate Influenza A virus, an enveloped RNA virus similar to SARS-CoV-2, over a period of four hours with illumination of high intensity visible light. The photosensitizer-functionalized polypropylene filter inactivated our model virus by 99.99% in comparison to a control.
Absolute cross sections for isotopically identified products formed in multinucleon transfer in the (136)Xe+(198)Pt system at ∼8 MeV/nucleon are reported. The isotopic distributions obtained using a ...large acceptance spectrometer demonstrated the production of the "hard-to-reach" neutron-rich isotopes for Z<78 around the N=126 shell closure far from stability. The main contribution to the formation of these exotic nuclei is shown to arise in collisions with a small kinetic energy dissipation. The present experimental finding corroborates for the first time recent predictions that multinucleon transfer reactions would be the optimum method to populate and characterize neutron-rich isotopes around N=126 which are crucial for understanding both astrophysically relevant processes and the evolution of "magic" numbers far from stability.
To detect and track structural changes in atomic nuclei, the systematic study of nuclear levels with firm spin-parity assignments is important. While linear polarization measurements have been ...applied to determine the electromagnetic character of gamma-ray transitions, the applicable range is strongly limited due to the low efficiency of the detection system. The multi-layer Cadmium-Telluride (CdTe) Compton camera can be a state-of-the-art gamma-ray polarimeter for nuclear spectroscopy with the high position sensitivity and the detection efficiency. We demonstrated the capability to operate this detector as a reliable gamma-ray polarimeter by using polarized 847-keV gamma rays produced by the Formula: see text(Formula: see text) reaction. By combining the experimental data and simulated calculations, the modulation curve for the gamma ray was successfully obtained. A remarkably high polarization sensitivity was achieved, compatible with a reasonable detection efficiency. Based on the obtained results, a possible future gamma-ray polarimetery is discussed.
The proton-rich isotope 68Br was discovered in secondary fragmentation reactions of fast radioactive beams. Proton-rich secondary beams of 70,71,72Kr and 70Br, produced at the RIKEN Nishina Center ...and identified by the BigRIPS fragment separator, impinged on a secondary 9Be target. Unambiguous particle identification behind the secondary target was achieved with the ZeroDegree spectrometer. Based on the expected direct production cross sections from neighboring isotopes, the lifetime of the ground or long-lived isomeric state of 68Br was estimated. The results suggest that secondary fragmentation reactions, where relatively few nucleons are removed from the projectile, offer an alternative way to search for new isotopes, as these reactions populate preferentially low-lying states.
Excited states in 56Zn were populated following one-neutron removal from a 57Zn beam impinging on a Be target at intermediate energies in an experiment conducted at the Radioactive Isotope Beam ...Factory at RIKEN. Three γ rays were observed and tentatively assigned to the 6+→4+→2+→0+ yrast sequence. This turns 56Zn into the heaviest Tz=−2 nucleus in which excited states are known. The excitation-energy differences between these levels and the isobaric analogue states in the Tz=+2 mirror partner, 56Fe, are compared with large-scale shell-model calculations considering the full pf valence space and various isospin-breaking contributions. This comparison, together with an analysis of the mirror energy differences in the A=58, Tz=±1 pair 58Zn and 58Ni, provides valuable information with respect to the size of the monopole radial and the isovector multipole isospin-breaking terms in the region above doubly-magic 56Ni.
Structure of the neutron-rich N=86 isotope 140Xe, located northeast of a doubly-magic nucleus 132Sn, is investigated by β−γ spectroscopy. Two β-decay isomers in 140I are newly found in the study of ...two different β decays of 140I which were produced by two reactions (i) direct in-flight fission at a primary target and (ii) β decay of 140Te at an active stopper. Half-lives of the β decays of the ground state, the low-spin isomer, and the high-spin isomer are determined to be 0.38(2), 0.91(5), and 0.47(4) s, respectively. Decay schemes of the β decay of the high-spin isomer and of the mixed β decays of the ground state and the low-spin isomer in 140I to 140Xe are constructed using the information on γ-ray coincidence relation and γ-ray intensity. Nuclear structures of the low-lying states in 140Xe and 140I are discussed by comparing the experimental results to two theoretical calculations based on a large-scale shell model and the deformed Skyrme Hartree-Fock-Bogoliubov plus deformed quasiparticle-random-phase approximation. Possible candidates for (quasi-)γ-band members of 2+ and 4+ states and the octupole collective 1− state are proposed in 140Xe. Increase of quadrupole, triaxial, and octupole collectivities is discussed with the increase of neutron and proton numbers.
The β-decay scheme of 138Te and the level structure of 138I is reported for the first time. The experiment was performed at the Radioactive Isotope Beam Factory of RIKEN, as one of the EUROBALL-RIKEN ...Cluster Array campaigns. Secondary radioactive ions, including 138Te and 138Sb, were produced by the in-flight fission of a 238U beam with the energy of 345 MeV per nucleon. From the β decay of 138Te, the level scheme of 138I was supplemented with new spin and parity assignments, such as the low-lying negative-parity states and a positive-parity 1+ state. This 1+ state can be interpreted as being associated with the π0h11/2⊗ν0h9/2 partner orbital configuration populated by the Gamow-Teller transition between a neutron in the 0h9/2 orbital and a proton in the 0h11/2 orbital. Details of the structure of 138I are discussed in terms of the proton-neutron interactions and Gamow-Teller transition strength within the theoretical context of shell-model calculations.
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