Reprocessing of spent nuclear fuel (SNF) is an important task in a frame of ecology and rational use of natural resources. Uranium, as the main component of SNF (>95%), can be recovered for further ...use as fresh nuclear fuel. To minimize an amount of solid radioactive waste generated during SNF reprocessing, new extractants are under investigation. Diamides of 1,10-phenanthroline-2,9-dicarboxylic acid are perspective tetradentate N-donor ligands that form strong complexes with f-elements, which are soluble in polar organic solvents. As an example of three ligands of this class, we conducted a comparative study and showed how the substituent in the amide functional group affects the extraction ability toward uranyl nitrate from nitric acid media. We have performed a careful study (NMR, FT-IR, XRD, RMC-EXAFS) of the structures of synthesized complexes of new ligands with uranyl nitrate and used quantum mechanical calculations to explain the discovered regularities through.
In this work we report on new examples of phenanthrolindiamides containing asymmetric centers in amide substituents. The synthesized ligands are expected to have complex thermodynamic behavior. Their ...structure was unambiguously confirmed by a combination of spectral analysis methods and X-ray analysis. It is shown that the obtained ligands form complexes with nitrates of rare-earth elements, and the stability constants of such complexes in acetonitrile solution were also measured. The performed solvent extraction tests revealed a significant effect of methyl groups in cyclic amide substituents on the distribution ratios and selectivity factors in the lanthanides(
iii
) and Am(
iii
) series in comparison with the previously studied ligands based on unsubstituted pyrrolidine. The observed effects are explained from the standpoint of quantum chemistry calculations taking into account possible stereoisomerism.
In this work we report on new examples of phenanthrolindiamides containing asymmetric centers in amide substituents.
The origin and nature of extreme energy cosmic rays (EECRs), which have energies above the
5
⋅
10
19
eV
—the Greisen-Zatsepin-Kuzmin (GZK) energy limit, is one of the most interesting and complicated ...problems in modern cosmic-ray physics. Existing ground-based detectors have helped to obtain remarkable results in studying cosmic rays before and after the GZK limit, but have also produced some contradictions in our understanding of cosmic ray mass composition. Moreover, each of these detectors covers only a part of the celestial sphere, which poses problems for studying the arrival directions of EECRs and identifying their sources. As a new generation of EECR space detectors, TUS (Tracking Ultraviolet Set-up), KLYPVE and JEM-EUSO, are intended to study the most energetic cosmic-ray particles, providing larger, uniform exposures of the entire celestial sphere. The TUS detector, launched on board the Lomonosov satellite on April 28, 2016 from Vostochny Cosmodrome in Russia, is the first of these. It employs a single-mirror optical system and a photomultiplier tube matrix as a photo-detector and will test the fluorescent method of measuring EECRs from space. Utilizing the Earth’s atmosphere as a huge calorimeter, it is expected to detect EECRs with energies above
10
20
eV
.
It will also be able to register slower atmospheric transient events: atmospheric fluorescence in electrical discharges of various types including precipitating electrons escaping the magnetosphere and from the radiation of meteors passing through the atmosphere. We describe the design of the TUS detector and present results of different ground-based tests and simulations.
This article presents a brief history of the appearance of electron spin in relativistic wave equations. Dirac derived his wave equation in 1928 with the intention to obtain an equation for the ...'simplest' particle with spin zero. But, as Dirac later announced at the European Conference on Particle Physics (Budapest, 4-9 July 1977), it was a big surprise for him that the equation described the states of a particle with spin 1/2.
Abstract
Hot ion mode was recently achieved at the Globus-M2 spherical tokamak when the toroidal magnetic field was as high as 0.9 T and plasma current 0.35 MA. The injection of two neutral beams ...with a total power of 0.7 MW and an energy of 30 keV into a plasma with major radius 0.36 m and minor radius 0.22 m (aspect ratio 1.6) made it possible to heat the plasma ions up to 4 keV, while electron density in the plasma center was as high as 8 × 10
19
m
−3
. The achievement of high temperatures became possible due to the good thermal insulation of the plasma.
Based on experimental observations using the TUMAN-3M and FT-2 tokamaks, and the results of gyrokinetic modeling of the interplay between turbulence and the geodesic acoustic mode (GAM) in these ...installations, a simple model is proposed for the analysis of the conditions required for L-H transition triggering by a burst of radial electric field oscillations in a tokamak. In the framework of this model, one-dimensional density evolution is considered to be governed by an anomalous diffusion coefficient dependent on radial electric field shear. The radial electric field is taken as the sum of the oscillating term and the quasi-stationary one determined by density and ion temperature gradients through a neoclassical formula. If the oscillating field parameters (amplitude, frequency, etc) are properly adjusted, a transport barrier forms at the plasma periphery and sustains after the oscillations are switched off, manifesting a transition into the high confinement mode with a strong inhomogeneous radial electric field and suppressed transport at the plasma edge. The electric field oscillation parameters required for L-H transition triggering are compared with the GAM parameters observed at the TUMAN-3M (in the discharges with ohmic L-H transition) and FT-2 tokamaks (where no clear L-H transition was observed). It is concluded based on this comparison that the GAM may act as a trigger for the L-H transition, provided that certain conditions for GAM oscillation and tokamak discharge are met.
The layered oxides being considered as intercalation compounds for lithium batteries display significant differences between the long-range crystal structure and local arrangements around individual ...atoms. These differences are important, because the local atomic environments affect Li-ion transport and, hence, the oxide’s rate capability, by determining activation barrier energies, by blocking or opening Li-diffusion pathways, etc. Traditional diffraction methods provide key information on the average crystal structure. However, no single experimental technique can unequivocally determine the average long-range crystal structure and the distribution of local environments over crystallographic distances while retaining atomic-scale resolution. Therefore, in this study, we have employed a combination of diffraction, microscopy, and spectroscopy techniques to investigate the long-range (∼1 μm) and local structure (≤1 nm) of Li1.2Co0.4Mn0.4O2, which is a model compound for layered oxides being considered for transportation applications. We find that Li1.2Co0.4Mn0.4O2 contains mostly Mn4+ in Li2MnO3-like atomic environments and Co3+ in LiCoO2-like atomic environments, which are intimately mixed over length scales of ≥2−3 nm, resulting in a Li1.2Co0.4Mn0.4O2 crystallite composition that appears homogeneous over the long-range. In addition, we observed a quasi-random distribution of locally monoclinic structures, topotaxially integrated within a rhombohedral-NaFeO2 framework. Based on these observations, we propose a dendritic microstructure model for Li1.2Co0.4Mn0.4O2 consisting of well integrated LiCoO2- and Li2MnO3-like structures.
Cases of colonization of the narrow-leaved oleaster
Elaeagnus angustifolia
L., lacking external signs of being weakened, by bark beetles of the genus
Scolytus
and development of the beetles’ ...offspring are described. The biological specificities of an aggressive xylophage,
Scolytus jaroschewskii
, and its association with the microorganisms in the foci of forest dieback are also characterized.
Winds from fast rotating stars Bogovalov, S V; Petrov, M A; Timofeev, V A
Monthly notices of the Royal Astronomical Society,
04/2021, Letnik:
502, Številka:
2
Journal Article
Recenzirano
ABSTRACT
Numerical modelling of an isothermal wind from a fast rotating star is performed. Excitation of hydrodynamical turbulence and deviation of the shape of the stellar surface from a sphere are ...taken into account. Rotation and turbulence result in a dramatic increase of the mass flow rate from the star in comparison with a non-rotating one. The outflow occurs predominantly from a region on the stellar surface located at the equator. This flow expands rapidly due to thermal pressure. However, a disc-like flow at the equator is formed. The flow is more complicated near the pole. At large distances from the star a radially expanding wind is formed while close to the star some fraction of the outflow from the equatorial region falls down on to the stellar surface, producing a huge vortex. The dependence of the mass loss rate on the parameters of the star is presented.
The results of measuring the electron temperature and density spatial distributions in plasma of the Globus-M2 tokamak using the Thomson scattering diagnostics are presented. The diagnostics provides ...measurements throughout the entire tokamak discharge, starting from time of gas breakdown. The Thomson scattering data were analyzed in order to determine the positions of the last closed flux surface, the plasma magnetic axis, and the radius of inversion during the saw-tooth oscillations. The results of measurements performed during the internal reconnection of magnetic field lines are presents, as well as the dynamics of spatial distributions of electron temperature, density and pressure during the plasma transition to the H-mode. The results of measuring the electron temperature distribution in the scrape-off layer using the Thomson scattering diagnostics are also presented for distances up to 4 cm outside the last closed flux surface.
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