Radiolarians have been used to determine geological ages and have contributed markedly to our understanding of Earth’s history. Hydrofluoric acid (HF) has traditionally been used to extract ...radiolarian fossils from siliceous deposits (i.e., radiolarian cherts), but this acid is strictly regulated because of environmental and human health concerns. Here we report on the successful extraction of radiolarians from cherts using a low-concentration NaOH solution (1 mol/L NaOH) as an alternative to HF. The degree of chert dissolution in NaOH is strongly temperature-dependent and is limited at < 80 °C. However, even a 1 mol/L NaOH solution is sufficient to dissolve chert at 100 °C. Our new NaOH method yields better-preserved radiolarian fossils compared with the conventional HF method. The 1 mol/L NaOH solution is less hazardous, easier to handle, and has fewer effects on the environment and human health than HF. Therefore, this method can be widely used for research and teaching purposes in studies of radiolarian fossils, even in institutions where HF cannot be used owing to chemical restrictions.
For the Upper Triassic, conodonts are the primary tools utilized in biostratigraphic investigations. For an effective biostratigraphic zonation, the species should be constrained by clear ...phylogenetic relationships, in which the stratigraphic ranges and taxonomy are reliable. Unfortunately, a phylogenetic framework for the Late Triassic pectiniform conodonts is almost missing, except for particular intervals, such as the Carnian/Norian boundary. The purpose of this study is to examine the latest Norian and Rhaetian pectiniform conodonts in detail in an attempt to determine their phylogenetic relationships, by applying novel phylogenetic methodologies that incorporate both morphological and stratigraphic data. This work is based on the conodont assemblages from the Upper Triassic strata of the Lagonegro Basin (southern Apennines, southern Italy) and the Csővár area (north-central Hungary), complemented with data from the literature. The calibrated phylogenetic analysis of the latest Norian and Rhaetian conodonts supports a two-step evolutionary history: a first radiation (~211–210 Ma) of the Parvigondolella species and the first representative of the genus Misikella, followed by a second phase (~206.5–205 Ma) leading to the final radiation of the Misikella species. Furthermore, the systematic revision of uppermost Triassic conodonts is provided along with the description of Misikella kolarae n. sp.
•Mockina bidentata: ancestor of clade Parvigondolella and clade Misikella•Two radiation phases in Late Norian-Rhaetian conodont evolution•Affinity of Misikella rhaetica with the Misikella clade is confirmed•Upper Sevatian and Rhaetian conodont zones subdivided into six subzones
The Carnian Pluvial Episode (CPE) was a global environmental change and biotic crisis that occurred during the Carnian (Late Triassic). The climate during the CPE was characterized by a short-lived ...period of extreme rainfall, and an extinction of marine taxa is known to have occurred during the latest Julian (i.e. early Carnian). Although these events are considered to have been caused by the Wrangellia Flood Basalt (FB) volcanism, existing studies have found little direct evidence to support this. We investigated the temporal relationship between the eruption of Wrangellia FB and CPE using high-resolution microfossil biostratigraphy and paleo-seawater Os isotope data of an Upper Triassic bedded chert succession from an accretionary complex in Japan, which accumulated in a pelagic deep-sea environment in an equatorial region of the Panthalassa Ocean. Our biostratigraphic analysis, based on conodonts and radiolarians, and osmium isotope data show: (i) a continuous decline of initial Os isotope ratios (187Os/188Osi) in the early Julian; (ii) low 187Os/188Osi ratios during the late Julian; and (iii) an abrupt increase in 187Os/188Osi ratios at the end of the Julian. The decrease in 187Os/188Osi ratios throughout the Julian suggests an increased input of unradiogenic Os from the eruption of the Wrangellia FB into the ocean. Moreover, redox-sensitive elements, such as V and U, increased abruptly at the end of the Julian, which is the first evidence of reducing conditions during the CPE within the pelagic deep-sea Panthalassa Ocean. Marine anoxic event in the late Julian has been recognized from widespread deposition of black shales and organic-rich marls in intermediate to shallow water Tethyan sections. Thus, oxygen-depleted conditions occurred at the Tethyan shallow continental margin, as well as in the pelagic deep-sea Panthalassa Ocean, at the end of Wrangellia FB volcanism.
•An Os isotopic profile of the Carnian chert succession in Japan was determined.•Os isotope data indicate the Wrangellia LIP formed during the Julian.•Two negative δ13Corg shifts were detected in the Julian 2 in the study section.•Enrichment of redox-sensitive elements suggests oxygen-depleted conditions occurred in the Panthalassa in the Julian 2.
We investigated for magnetostratigraphy the Rio Nigra and Rio Frommer stratigraphic sections from Alpe di Siusi/Seiser Alm (Dolomites, northern Italy) in order to improve the calibration of the ...Triassic time scale. Both sections are characterized by ammonoid and conodont associations typical of Longobardian (late Ladinian, Middle Triassic) age. Moreover, the Rio Nigra section is constrained by a U-Pb zircon date of 237.77 ± 0.05 Ma. Building on the recently verified Newark-Hartford astrochronological polarity timescale for the Late Carnian–Rhaetian (plus the Hettangian) and through magnetostratigraphic correlations of an updated inventory of Tethyan marine stratigraphic sections from the literature, some of which are provided with U-Pb zircon age constraints, we propose a revised Geomagnetic Polarity Time Scale for the entire Triassic.
•New U-Pb constrained Ladinian magnetostratigraphy improves Triassic chronology.•Using recent magnetostratigraphic data to update the Geomagnetic Polarity Timescale•Updated Geomagnetic Polarity Timescale led to a duration of 50.5 Myr for Triassic.
We present a multi-proxy investigation of a lower Carnian basinal succession from Polzberg in the Northern Calcareous Alps (Lower Austria). A section comprising a unique Konservat-Lagerstätte was ...studied based on bio- and chemostratigraphy along with geophysical methods, yielding a detailed and robust stratigraphic calibration of the Polzberg succession. The Polzberg section revealed the paleoceanographic history and helped to identify a global climatic reversal, the Carnian Pluvial Episode. The age of the Upper Triassic Reingraben formation in the Northern Calcareous Alps is refined as the Austrotrachyceras austriacum Zone within the lower Carnian (Julian 2). Ammonoids and conodonts provide a detailed biostratigraphic subdivision that serves as a basis for analyses of the faunal distribution and the paleoenvironmental evolution of the Upper Triassic Reifling Basin. The succession includes lithological and facies changes similar to those of coeval units in the Tethys. The Carnian was characterized by a weak (~ 1‰) positive δ
C trend, punctuated by a negative shift during the lower Carnian corresponding to the initiation of the Carnian Pluvial Episode, a period representing the onset of early/late Carnian transitional global greenhouse conditions. Organic maturity parameters and the conodont alteration index (CAI) show that the thermal overprint of the Polzberg section is low. Biomarker proxies suggest that the organic matter of the uppermost Göstling formation is a mixture of marine and terrestrial material deposited in a dysoxic environment. Within the overlaying Reingraben formation, the amount of marine biomass decreased gradually upwards. Oxygen-depleted conditions, probably due to water-column stratification, continued during deposition of the Reingraben formation. Bacterial sulfate reduction played a major role in organic matter degradation.
The Carnian Pluvial Episode was a phase of global climatic change and biotic turnover that occurred during the early Late Triassic. In marine sedimentary basins, the arrival of huge amounts of ...siliciclastic sediments, the establishment of anoxic conditions, and a sudden change of the carbonate factory on platforms marked the Carnian Pluvial Episode. The sedimentary changes are closely associated with abrupt biological turnover among marine and terrestrial groups as, for example, an extinction among ammonoids and conodonts in the ocean, and a turnover of the vertebrate fauna and the flora on land. Multiple negative carbon-isotope excursions were recorded during the Carnian Pluvial Episode in both organic matter and marine carbonates, suggesting repeated injection of 13C-depleted CO2 into the ocean–atmosphere system, but their temporal and causal links with the sedimentological and palaeontological changes are poorly understood. We here review the existing carbon-isotope records and present new data on the carbon-isotope composition of organic carbon in selected sections of the western Tethys realm that record the entire Carnian Pluvial Episode. New ammonoid, conodont and sporomorph biostratigraphic data were collected and coupled to an extensive review of the existing biostratigraphy to constrain the age of the sampled sections. The results provide biostratigraphically constrained composite organic carbon-isotope curves for the Carnian, which sheds light on the temporal and causal links between the main carbon-isotope perturbations, and the distinct environmental and biotic changes that mark the Carnian Pluvial Episode. The carbon-isotope records suggest that a series of carbon-cycle perturbations, possibly recording multiple phases of volcanic activity during the emplacement of the Wrangellia Large Igneous Province, disrupted Carnian environments and ecosystems repeatedly over a remarkably long time interval of about 1 million years.
The objective of this study is to examine the evolution of all the braced patients diagnosed with early onset scoliosis in a private scoliosis center. All patients diagnosed with EOS and braced ...before the age of ten were retrospectively reviewed. The results have been defined in accordance with the Scoliosis Research Society (SRS) for bracing criteria, and with a minimum follow-up of one year. Improvement and stabilization were considered successful treatments, while failure was considered to be an unsuccessful treatment. Successful results were observed in 80% of patients (63% worst case). In the success group, the Cobb angle was reduced from 36.3° (21-68) to 25° (10-43), with 36% of patients being initially treated only with night-time bracing. Twenty percent of the patients failed, seven had more than 45° at the last control and five had undergone surgery. This study suggests that bracing, using a modern 3D-brace concept, could be an effective treatment option for early onset scoliosis and advocates exploring its effectiveness as an alternative to casting throughout studies of higher levels of evidence.
The Carnian Pluvial Episode (CPE) was a short interval of extreme rainfall in the Late Triassic that caused significant changes in marine ecosystems. Global warming induced by Wrangellia volcanism is ...thought to have resulted in oceanic anoxia during the CPE, but the global extent, duration, and severity of anoxia, and its effects on major marine taxa, remain unclear. To address this, we examined an equatorial record of conditions in the Panthalassa Ocean during the CPE, focusing on marine Os isotope data, redox conditions, and conodont and radiolarian biostratigraphy. The results show that Wrangellia volcanism peaked in the latest Julian (early Carnian), coinciding with development of reducing conditions in the deep-sea Panthalassa. A strong conodont turnover occurred during the period of oceanic anoxia, whereas radiolarians were less affected and their diversity increased after the recovery from anoxia. The increased radiolarian diversity during the early Tuvalian (late Carnian) can be attributed to chemical weathering and enhanced nutrient fluxes associated with global warming and the more humid climate of Pangea.
The latest Triassic was an interval of prolonged biotic extinction culminating in the end-Triassic Extinction (ETE). The ETE is now associated with a perturbation of the global carbon cycle just ...before the end of the Triassic that has been attributed to the extensive volcanism of the Circum-Atlantic Magmatic Province (CAMP). However, we attribute the onset of declining latest Triassic diversity to an older perturbation of the carbon cycle (δ13Corg) of global extent at or very close to the Norian/Rhaetian boundary (NRB). The NRB appears to be the culmination of stepwise biotic turnovers that characterize the latest Triassic and includes global extinctions of significant marine and terrestrial fossil groups. These biotic events across the NRB have been largely under-appreciated, yet together with a coeval disturbance of the carbon cycle were pivotal in the history of the Late Triassic. Here, we present new and published δ13Corg data from widespread sections (Italy, Greece, ODP, Australia, New Zealand, USA, Canada). These sections document a previously unknown perturbation in the carbon cycle of global extent that spanned the NRB. The disturbance extended across the Panthalassa Ocean to both sides of the Pangaean supercontinent and is recorded in both the Northern and Southern Hemispheres. The onset of stepwise Late Triassic extinctions coincides with carbon perturbation (δ13Corg) at the NRB, indicating that a combination of climatic and environmental changes impacted the biota at a global scale. The NRB event may have been triggered either by gas emissions from the eruption of a large igneous province pre-dating the NRB, by a bolide impact of significant size or by some alternative source of greenhouse gas emissions. As yet, it has not been possible to clearly determine which of these trigger scenarios was responsible; the evidence is insufficient to decisively identify the causal mechanism and merits further study.
A series of biotic crises and turnovers have been recorded at the Norian/Rhaetian boundary (NRB), together with a putative perturbation to the global carbon cycle in the form of one or more negative ...carbon-isotope shifts. Despite this evidence, the full validation of Norian/Rhaetian climate changes has not been possible. In particular, no clear record of Norian/Rhaetian environmental change has yet been recovered from a terrestrial setting. The eruption of the Angayucham Large Igneous Province has been considered as a possible cause for the putative NRB negative carbon-isotope shifts. Hg as a volcanism proxy has been well-studied in many ancient marine and terrestrial sediments, but to date no Hg record has been obtained across the NRB. In this study, we focus on a terrestrial Norian-Rhaetian section (Xujiahe section) located north of Guangyuan in the northwestern Sichuan Basin, which has been correlated to the NRB using cyclostratigraphy and magnetostratigraphy. A long-lived negative trend in δ13Corg, superimposed with four negative shifts, is recognized across the NRB interval. This can be correlated to the uppermost part of the third negative δ13Corg shift (named S3) recognized in profiles from marine sites in Europe. Contemporaneous Hg concentration, Hg/Al and Hg/TOC anomalies in the Xujiahe section were possibly caused by large-scale volcanic activity. The large amplitude changes in δ13Corg (ca. −5.2‰) that we observe are suggested to be associated with local wildfire and enhanced coarse sediment input, indicating a significant environmental change during the NRB interval. Similar paleoclimatic perturbations have been noted across other extinction events (e.g., end-Permian mass extinction event) as a result of the emplacement of large igneous provinces, or because of felsic volcanism.
•A long negative trend in δ13Corg, superimposed with four negative shifts, is recognized across a terrestrial NRB interval.•Anomalies in Hg concentrations, Hg/Al and Hg/TOC ratios are possibly caused by large-scale volcanic activity.•Black carbon analysis suggests a low ignited temperature of the NRB wildfire, which could be due to wet fuel or smoldering.
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