Over the past decade, graphene has advanced rapidly as one of the most promising materials changing human life. Development of production‐worthy synthetic methodologies for the preparation of various ...types of graphene forms the basis for its investigation and applications. Graphene can be used in the forms of either microflake powders or large‐area thin films. Graphene powders are prepared by the exfoliation of graphite or the reduction of graphene oxide, while graphene films are prepared predominantly by chemical vapor deposition (CVD) on a variety of substrates. Both metal and dielectric substrates have been explored; while dielectric substrates are preferred over any other substrate, much higher quality graphene large‐area films have been grown on metal substrates such as Cu. The focus here is on the progress of graphene synthesis on Cu foils by CVD, including various CVD techniques, graphene growth mechanisms and kinetics, strategies for synthesizing large‐area graphene single crystals, graphene transfer techniques, and, finally, challenges and prospects are discussed.
Synthesis of graphene films on copper foils by chemical vapor deposition (CVD) is widely used for the production of large‐area graphene due to the advantages of low cost, ease for graphene transfer, and high graphene quality, for example. The progress of this technique is summarized, including various CVD techniques, graphene growth mechanisms and kinetics, strategies for synthesizing large‐area graphene single crystals, and graphene transfer techniques.
Zinc‐based batteries have a high capacity and are safe, cost‐effective, environmentally‐friendly, and capable of scalable production. However, dendrite formation and poor reversibility hinder their ...performance. Metal‐organic framework (MOF)‐based Zn anodes are made by wet chemistry to address these issues. These MOF‐based anodes exhibit high efficiency during Zn plating‐stripping and prevent dendrite formation, as shown by ex situ SEM analysis. The practicality of the MOF‐based anodes is demonstrated in aqueous Zn ion batteries, which show improved performance including specific capacity, cycle life, and safety relative to the pristine Zn anode due to their hydrophilic and porous surface. These results, along with the easy scalability of the process, demonstrate the high potential of MOF‐modified Zn anodes for use in dendrite‐free, higher‐performance, Zn‐based energy storage systems.
Metal–organic framework (MOF) integrated Zn metal anodes are designed for next‐generation dendrite‐free Zn‐based batteries. These anodes have hydrophilic and porous surfaces that facilitate Zn2+ ion diffusion and the production of a uniform charge distribution. These novel MOF‐integrated Zn anodes outperform existing Zn anodes and have great potential for use in large‐scale energy storage systems.
Interest in graphene centres on its excellent mechanical, electrical, thermal and optical properties, its very high specific surface area, and our ability to influence these properties through ...chemical functionalization. There are a number of methods for generating graphene and chemically modified graphene from graphite and derivatives of graphite, each with different advantages and disadvantages. Here we review the use of colloidal suspensions to produce new materials composed of graphene and chemically modified graphene. This approach is both versatile and scalable, and is adaptable to a wide variety of applications.
Lithium‐ion batteries (LIBs) have dominated the portable electronics industry and solid‐state electrochemical research and development for the past two decades. In light of possible concerns over the ...cost and future availability of lithium, sodium‐ion batteries (SIBs) and other new technologies have emerged as candidates for large‐scale stationary energy storage. Research in these technologies has increased dramatically with a focus on the development of new materials for both the positive and negative electrodes that can enhance the cycling stability, rate capability, and energy density. Two‐dimensional (2D) materials are showing promise for many energy‐related applications and particularly for energy storage, because of the efficient ion transport between the layers and the large surface areas available for improved ion adsorption and faster surface redox reactions. Recent research highlights on the use of 2D materials in these future ‘beyond‐lithium‐ion’ battery systems are reviewed, and strategies to address challenges are discussed as well as their prospects.
Two‐dimensional nanomaterials have gained growing interest as promising candidates for electrode materials for lithium ion batteries and beyond. Various kinds of two‐dimensional nanomaterials for sodium ion batteries and other emerging battery technologies are summarized, along with the current difficulties and potential strategies. Perspectives on the future development of two‐dimensional nanomaterials as beyond‐Li‐ion energy storage electrodes are presented.
Ultracapacitors are rapidly being adopted for a wide range of electrical energy storage applications. While ultracapacitors are able to deliver high rates of charge and discharge, they are limited in ...the amount of energy stored. The capacity of ultracapacitors is largely determined by the electrode material and as a result research to improve the performance of electrode materials has dramatically increased. While test methods for packaged ultracapacitors are well developed, it is often impractical for the materials scientist to assemble full sized, packaged cells to test electrode materials. Methodology to reliably measure a material's performance for use as an ultracapacitor electrode is not well standardized with various techniques yielding widely varying results. In this manuscript, we review and validate best practice test methods that accurately predict a material's performance, yet are flexible and quick enough to accommodate a wide range of material sample types and amounts.
Best practice test methods that accurately predict a material's performance for ultracapacitor electrodes are described and validated.
Conspectus Graphene, a one-atom-thick layer of carbon with a honeycomb lattice, has drawn great attention due to its outstanding properties and its various applications in electronic and photonic ...devices. Mechanical exfoliation has been used for preparing graphene flakes (from monolayer to multilayer with thick pieces also typically present), but with sizes limited typically to less than millimeters, its usefulness is limited. Chemical vapor deposition (CVD) has been shown to be the most effective technique for the scalable preparation of graphene films with high quality and uniformity. To date, CVD growth of graphene on the most commonly used substrates (Cu and Ni foils) has been demonstrated and intensively studied. However, a survey of the existing literature and earlier work using Cu or Ni substrates for CVD growth indicates that the bilayer and multilayer graphene over a large area, particularly single crystals, have not been obtained. In this Account, we review current progress and development in the CVD growth of graphene and highlight the important challenges that need to be addressed, for example, how to achieve large single crystal graphene films with a controlled number of layers. A single-layer graphene film grown on polycrystalline Cu foil was first reported by our group, and since then various techniques have been devoted to achieving the fast growth of large-area graphene films with high quality. Commercially available Cu/Ni foils, sputtered Cu/Ni thin films, and polycrystalline Cu/Ni foils have been used for the CVD synthesis of bilayer, trilayer, and multilayer graphene. Cu/Ni alloy substrates are particularly interesting due to their greater carbon solubility than pure Cu substrates and this solubility can be finely controlled by changing the alloy composition. These substrates with controlled compositions have shown the potential for the growth of layer-tunable graphene films in addition to providing a much higher growth rate due to their stronger catalytic activity. However, the well-controlled preparation of single crystal graphene with a defined number of layers on Cu/Ni substrates is still challenging. Due to its small lattice mismatch with graphene, a single crystal Cu(111) foil has been shown to be an ideal substrate for the epitaxial growth of graphene. Our group has reported the synthesis of large-size single crystal Cu(111) foils by the contact-free annealing of commercial Cu foils, and single crystal Cu/Ni(111) alloy foils have also been obtained after the heat-treatment of Ni-coated Cu(111) foils. The use of these single crystal foils (especially the Cu/Ni alloy foils) as growth substrates has enabled the fast growth of single crystal single-layer graphene films. By increase of the Ni content, single crystal bilayer, trilayer, and even multilayer graphene films have been synthesized. In addition, we also discuss the wafer-scale growth of single-layer graphene on the single crystalline Cu/Ni(111) thin films. Recent research results on the large-scale preparation of single crystal graphene films with different numbers of layers on various types of Cu/Ni alloy substrates with different compositions are reviewed and discussed in detail. Despite the remarkable progress in this field, further challenges, such as the wafer-scale synthesis of single crystal graphene with a controlled number of layers and a deeper understanding of the growth mechanism of bilayer and multilayer graphene growth on Cu/Ni substrates, still need to be addressed.
Continuous ultrathin graphite foams (UGFs) have been actively researched recently to obtain composite materials with increased thermal conductivities. However, the large pore size of these graphitic ...foams has resulted in large thermal resistance values for heat conduction from inside the pore to the high thermal conductivity graphitic struts. Here, we demonstrate that the effective thermal conductivity of these UGF composites can be increased further by growing long CNT networks directly from the graphite struts of UGFs into the pore space. When erythritol, a phase change material for thermal energy storage, is used to fill the pores of UGF–CNT hybrids, the thermal conductivity of the UGF–CNT/erythritol composite was found to increase by as much as a factor of 1.8 compared to that of a UGF/erythritol composite, whereas breaking the UGF–CNT bonding in the hybrid composite resulted in a drop in the effective room-temperature thermal conductivity from about 4.1 ± 0.3 W m–1 K–1 to about 2.9 ± 0.2 W m–1 K–1 for the same UGF and CNT loadings of about 1.8 and 0.8 wt %, respectively. Moreover, we discovered that the hybrid structure strongly suppresses subcooling of erythritol due to the heterogeneous nucleation of erythritol at interfaces with the graphitic structures.
Pressure-driven, superfast organic solvent filtration membranes have significant practical applications. An excellent filtration membrane should exhibit high selectivity and permeation in aqueous and ...organic solvents to meet increasing industrial demand. Here, we report an amino functionalized boron nitride (FBN) based filtration membrane with a nanochannel network for molecular separation and permeation. This membrane is highly stable in water and in several organic solvents and shows high transport performance for solvents depending on the membranes' thickness. In addition, the FBN membrane is applicable for solute screening in water as well as in organic solvents. More importantly, the FBN membranes are very stable in acidic, alkaline and oxidative media for up to one month. The fast-flow rate and good separation performance of the FBN membranes can be attributed to their stable networks of nanochannels and thin laminar structure, which provide the membranes with beneficial properties for practical separation and purification processes.
Tiny computers located in end-user premises are becoming popular as local servers for Internet of Things (IoT) and Fog computing services. These highly distributed servers that can host and ...distribute content and applications in a peer-to-peer (P2P) fashion are known as nano data centers (nDCs). Despite the growing popularity of nano servers, their energy consumption is not well-investigated. To study energy consumption of nDCs, we propose and use flow-based and time-based energy consumption models for shared and unshared network equipment, respectively. To apply and validate these models, a set of measurements and experiments are performed to compare energy consumption of a service provided by nDCs and centralized data centers (DCs). A number of findings emerge from our study, including the factors in the system design that allow nDCs to consume less energy than its centralized counterpart. These include the type of access network attached to nano servers and nano server's time utilization (the ratio of the idle time to active time). Additionally, the type of applications running on nDCs and factors such as number of downloads, number of updates, and amount of preloaded copies of data influence the energy cost. Our results reveal that number of hops between a user and content has little impact on the total energy consumption compared to the above-mentioned factors. We show that nano servers in Fog computing can complement centralized DCs to serve certain applications, mostly IoT applications for which the source of data is in end-user premises, and lead to energy saving if the applications (or a part of them) are off-loadable from centralized DCs and run on nDCs.
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