One of the long standing debates in actinide chemistry is the level of localization and participation of the actinide 5f valence orbitals in covalent bonds across the actinide series. Here we ...illuminate the role of the 5f valence orbitals of uranium, neptunium and plutonium in chemical bonding using advanced spectroscopies: actinide M
HR-XANES and 3d4f RIXS. Results reveal that the 5f orbitals are active in the chemical bonding for uranium and neptunium, shown by significant variations in the level of their localization evidenced in the spectra. In contrast, the 5f orbitals of plutonium appear localized and surprisingly insensitive to different bonding environments. We envisage that this report of using relative energy differences between the 5fδ/φ and 5fπ*/5fσ* orbitals as a qualitative measure of overlap-driven actinyl bond covalency will spark activity, and extend to numerous applications of RIXS and HR-XANES to gain new insights into the electronic structures of the actinide elements.
Control and bribery are settings in which an external agent seeks to influence the outcome of an election. Constructive control of elections refers to attempts by an agent to, via such actions as ...addition/deletion/partition of candidates or voters, ensure that a given candidate wins. Destructive control refers to attempts by an agent to, via the same actions, preclude a given candidate's victory. An election system in which an agent can sometimes affect the result and it can be determined in polynomial time on which inputs the agent can succeed is said to be vulnerable to the given type of control. An election system in which an agent can sometimes affect the result, yet in which it is NP-hard to recognize the inputs on which the agent can succeed, is said to be resistant to the given type of control.
Aside from election systems with an NP-hard winner problem, the only systems previously known to be resistant to all the standard control types were highly artificial election systems created by hybridization. This paper studies a parameterized version of Copeland voting, denoted by Copeland^\alpha, where the parameter \alpha is a rational number between 0 and 1 that specifies how ties are valued in the pairwise comparisons of candidates. In every previously studied constructive or destructive control scenario, we determine which of resistance or vulnerability holds for Copeland^\alpha for each rational \alpha, 0 \leq \alpha \leq 1. In particular, we prove that Copeland^{0.5}, the system commonly referred to as ``Copeland voting,'' provides full resistance to constructive control, and we prove the same for Copeland^\alpha, for all rational \alpha, 0 < \alpha < 1. Among systems with a polynomial-time winner problem, Copeland voting is the first natural election system proven to have full resistance to constructive control. In addition, we prove that both Copeland^0 and Copeland^1 (interestingly, Copeland^1 is an election system developed by the thirteenth-century mystic Llull) are resistant to all standard types of constructive control other than one variant of addition of candidates. Moreover, we show that for each rational \alpha, 0 \leq \alpha \leq 1, Copeland^\alpha voting is fully resistant to bribery attacks, and we establish fixed-parameter tractability of bounded-case control for Copeland^\alpha.
We also study Copeland^\alpha elections under more flexible models such as microbribery and extended control, we integrate the potential irrationality of voter preferences into many of our results, and we prove our results in both the unique-winner model and the nonunique-winner model. Our vulnerability results for microbribery are proven via a novel technique involving min-cost network flow.
This book is an introduction to the field of constrained Hamiltonian systems and their quantization, a topic which is of central interest to theoretical physicists who wish to obtain a deeper ...understanding of the quantization of gauge theories, such as describing the fundamental interactions in nature. Beginning with the early work of Dirac, the book covers the main developments in the field up to more recent topics, such as the field–antifield formalism of Batalin and Vilkovisky, including a short discussion of how gauge anomalies may be incorporated into this formalism. All topics are well illustrated with examples emphasizing points of central interest. The book should enable graduate students to follow the literature on this subject without much problems, and to perform research in this field.
The CRESST experiment is a direct dark matter search which aims to measure interactions of potential dark matter particles in an Earth-bound detector. With the current stage, CRESST-III, we focus on ...a low energy threshold for increased sensitivity towards light dark matter particles. In this paper we describe the analysis of one detector operated in the first run of CRESST-III (05/2016–02/2018) achieving a nuclear recoil threshold of 30.1 eV. This result was obtained with a 23.6 g CaWO4 crystal operated as a cryogenic scintillating calorimeter in the CRESST setup at the Laboratori Nazionali del Gran Sasso (LNGS). Both the primary phonon (heat) signal and the simultaneously emitted scintillation light, which is absorbed in a separate silicon-on-sapphire light absorber, are measured with highly sensitive transition edge sensors operated at ∼15 mK. The unique combination of these sensors with the light element oxygen present in our target yields sensitivity to dark matter particle masses as low as 160 MeV/c2.
Models for light dark matter particles with masses below 1 GeV/c Formula omitted are a natural and well-motivated alternative to so-far unobserved weakly interacting massive particles. Gram-scale ...cryogenic calorimeters provide the required detector performance to detect these particles and extend the direct dark matter search program of CRESST. A prototype 0.5 g sapphire detector developed for the Formula omitted-cleus experiment has achieved an energy threshold of Formula omitted eV. This is one order of magnitude lower than for previous devices and independent of the type of particle interaction. The result presented here is obtained in a setup above ground without significant shielding against ambient and cosmogenic radiation. Although operated in a high-background environment, the detector probes a new range of light-mass dark matter particles previously not accessible by direct searches. We report the first limit on the spin-independent dark matter particle-nucleon cross section for masses between 140 and 500 MeV/c Formula omitted.
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Dostopno za:
DOBA, IZUM, KILJ, NUK, PILJ, PNG, SAZU, SIK, UILJ, UKNU, UL, UM, UPUK
We discuss a small-scale experiment, called
ν
-cleus, for the first detection of coherent neutrino–nucleus scattering by probing nuclear-recoil energies down to the 10 eV regime. The detector ...consists of low-threshold CaWO
4
and Al
2
O
3
calorimeter arrays with a total mass of about 10 g and several cryogenic veto detectors operated at millikelvin temperatures. Realizing a fiducial volume and a multi-element target, the detector enables active discrimination of
γ
, neutron and surface backgrounds. A first prototype Al
2
O
3
device, operated above ground in a setup without shielding, has achieved an energy threshold of
∼
20
eV and further improvements are in reach. A sensitivity study for the detection of coherent neutrino scattering at nuclear power plants shows a unique discovery potential (5
σ
) within a measuring time of
≲
2
weeks. Furthermore, a site at a thermal research reactor and the use of a radioactive neutrino source are investigated. With this technology, real-time monitoring of nuclear power plants is feasible.
Celotno besedilo
Dostopno za:
DOBA, IZUM, KILJ, NUK, PILJ, PNG, SAZU, SIK, UILJ, UKNU, UL, UM, UPUK
The energy threshold of a cryogenic calorimeter can be lowered by reducing its size. This is of importance since the resulting increase in signal rate enables new approaches in rare-event searches, ...including the detection of MeV mass dark matter and coherent scattering of reactor or solar neutrinos. A scaling law for energy threshold vs detector size is given. We analyze the possibility of lowering the threshold of a gram-scale cryogenic calorimeter to the few eV regime. A prototype 0.5 g Al2O3 device achieved an energy threshold of Eth=(19.7±0.9) eV, the lowest value reported for a macroscopic calorimeter.
The CRESST experiment (Cryogenic Rare Even Search with Superconducting Thermometers), located at Laboratori Nazionali del Gran Sasso in Italy, searches for dark matter particles via their elastic ...scattering off nuclei in a target material. The CRESST target consists of scintillating CaWO4 crystals, which are operated as cryogenic calorimeters at millikelvin temperatures. Each interaction in the CaWO4 target crystal produces a phonon signal and a light signal that is measured by a second cryogenic calorimeter. Since the CRESST-II result in 2015, the experiment is leading the field of direct dark matter search for dark matter masses below 1.7 GeV/c2, extending the reach of direct searches to the sub-GeV/c2 mass region. For CRESST-III, whose Phase 1 started in July 2016, detectors have been optimized to reach the performance required to further probe the low-mass region with unprecedented sensitivity. In this contribution the achievements of the CRESST-III detectors will be discussed together with preliminary results and perspectives of Phase 1.
In this work we report the realization of the first low-threshold cryogenic detector that uses diamond as absorber for astroparticle physics applications. We tested two 0.175 g CVD diamond samples, ...each instrumented with a W-TES. The sensors showed transitions at about 25 mK. We present the performance of the diamond detectors and we highlight the best performing one, where we obtained an energy threshold as low as 16.8 eV. This promising result lays the foundation for the use of diamond for different fields of applications where low threshold and excellent energy resolution are required, as i.e. light dark matter searches and BSM physics with coherent elastic neutrino nucleus scattering.
Celotno besedilo
Dostopno za:
DOBA, IZUM, KILJ, NUK, PILJ, PNG, SAZU, SIK, UILJ, UKNU, UL, UM, UPUK
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