The accumulation of marine organisms on ship hulls, such as microorganisms, barnacles, and seaweeds, represents a global problem for maritime industries, with both economic and environmental costs. ...The use of biocide-containing paints poses a serious threat to marine ecosystems, affecting both target and non-target organisms driving science and technology towards non-biocidal solutions based on physico-chemical and materials properties of coatings. The review reports recent development of hydrophobic protective coatings in terms of mechanical properties, correlated with the wet ability features. The attention is focused mainly on coatings based on siloxane and epoxy resin due to the wide application fields of such systems in the marine industry. Polyurethane and other systems have been considered as well. These coatings for anti-fouling applications needs to be both long-term mechanically stable, perfectly adherent with the metallic/composite substrate, and capable to detach/destroy the fouling organism. Prospects should focus on developing even "greener" antifouling coatings solutions. These coatings should also be readily addressable to industrial scale-up for large-scale product distribution, possibly at a reasonable cost.
Agri-food wastes (such as brewer’s spent grain, olive pomace, residual pulp from fruit juice production, etc.) are produced annually in very high quantities posing a serious problem, both ...environmentally and economically. These wastes can be used as secondary starting materials to produce value-added goods within the principles of the circular economy. In this context, this review focuses on the use of agri-food wastes either to produce building blocks for bioplastics manufacturing or biofillers to be mixed with other bioplastics. The pros and cons of the literature analysis have been highlighted, together with the main aspects related to the production of bioplastics, their use and recycling. The high number of European Union (EU)-funded projects for the valorisation of agri-food waste with the best European practices for this industrial sector confirm a growing interest in safeguarding our planet from environmental pollution. However, problems such as the correct labelling and separation of bioplastics from fossil ones remain open and to be optimised, with the possibility of reuse before final composting and selective recovery of biomass.
In this paper, we report the synthesis and characterization of novel coatings based on (3-aminopropyl)-triethoxysilane (AP) mixed with different amounts of glutaraldehyde (GA). The synthesized ...coatings have been layered on a glass substrate and characterized by optical microscopy and roughness measurements, thermogravimetric analyses and differential scanning calorimetry, contact angle analysis, rheological measurement, and an adhesion test. It was observed that the higher the GA content (up to AP:GA ratio of 0.3), the sooner the crosslinking reaction starts, leading to a coating with increased hydrophobic and adhesion features without compromising the final AP cross-linked network. Hence, the obtained results show the effectiveness of AP modification with GA from the perspective of an application as protective coatings.
Bio-polybutylene succinate (PBS) is a biodegradable polymer obtained from renewable feedstock having physical-mechanical properties like traditional low-density polyethylene (LDPE). PBS is employed ...by many manufacturing sectors, from biomedical to agri-food and cosmetics. Although some studies have already evaluated the resistance of PBS to photodegradation caused by natural outdoor solar exposure (UVA-UVB), a systematic study on the resistance to degradation caused by exposure to UVC rays, which is the subject of this study, has not yet been carried out. PBS was exposed to UVC either neat or filled with 2% carbon black (CB). Mechanical and physical characterization (tensile, hardness, calorimetry, contact angle, morphology, and surface roughness analyses) indicates that the bulk and surface properties of the polymer matrix changes after exposure to UVC radiations, due to a severe degradation. However, the presence of carbon black compensates for the degradation phenomenon. Because UVC rays are used for the sterilization process, necessary in applications such as biomedical, cosmetic, pharmaceutical, food, and other products, a comparison of the protocol used in this paper with the literature's data has been reported and discussed.
Dissimilar welds between ferritic and austenitic steels represent a good solution for exploiting the best performance of stainless steels at high and low temperatures and in aggressive environments, ...while minimizing costs. Therefore, they are widely used in nuclear and petrochemical plants; however, due to the different properties of the steels involved, the welding process can be challenging. Fusion welding can be specifically applied to connect low-carbon or low-alloy steels with high-alloy steels, which have similar melting points. The welding of thick plates can be performed with an electric arc in multiple passes or in a single pass by means of laser beam equipment. Since the microstructure and, consequently, the mechanical properties of the weld are closely related to the composition, the choice of the filler metal and processing parameters, which in turn affect the dilution rate, plays a fundamental role. Numerous technical solutions have been proposed for welding dissimilar steels and much research has developed on welding metallurgy; therefore, this article is aimed at a review of the most recent scientific literature on issues relating to the fusion welding of ferritic/austenitic steels. Two specific sections are dedicated, respectively, to electric arc and laser beam welding; finally, metallurgical issues, related to dilution and thermal field are debated in the discussion section.
Polymeric joints, made of biomedical polyethylene (UHMWPE) nanocomposite sheets, were welded with a diode laser. Since polyethylene does not absorb laser light, nanocomposites were prepared ...containing different percentages by weight of titanium dioxide as it is a laser absorbent. The joints were first analyzed with static mechanical tests to establish the best percentage weight content of filler that had the best mechanical response. Then, the nanocomposites containing 1 wt% titanium dioxide were selected (white color) to be subjected to fatigue tests. The experimental results were also compared with those obtained on UMMWPE with a different laser light absorbent nano filler (carbon, with greater laser absorbing power, gray in color), already studied by our research team. The results showed that the two types of joints had an appreciable resistance to fatigue, depending on the various loads imposed. Therefore, they can be chosen in different applications of UHMWPE, depending on the stresses imposed during their use.
In this work, formulations of "environmentally compatible" silicone-based antifouling, synthesized in the laboratory and based on copper and silver on silica/titania oxides, have been characterized. ...These formulations are capable of replacing the non-ecological antifouling paints currently available on the market. The texture properties and the morphological analysis of these powders with an antifouling action indicate that their activity is linked to the nanometric size of the particles and to the homogeneous dispersion of the metal on the substrate. The presence of two metal species on the same support limits the formation of nanometric species and, therefore, the formation of homogeneous compounds. The presence of the antifouling filler, specifically the one based on titania (TiO
) and silver (Ag), facilitates the achievement of a higher degree of cross-linking of the resin, and therefore, a better compactness and completeness of the coating than that attained with the pure resin. Thus, a high degree of adhesion to the tie-coat and, consequently, to the steel support used for the construction of the boats was achieved in the presence of the silver-titania antifouling.
Ultra High molecular weight polyethylene (UHMWPE) suffers wear degradation in total joint replacements and it needs to be improved. Thus, we enhanced wear resistance of UHMWPE with carbon nanofiller ...and paraffin oil and studied its tribological behavior in Simulated Synovial Fluid (SSF) for 60 days at 37 °C to reproduce the conditions of a real joint. Ageing in biological fluid accelerates the wear action but nanocomposite exhibited a higher wear resistance compared to UHMWPE because of its higher structural homogeneity. Carbon nanofiller closes the porosity of UHMWPE hindering SSF to penetrate inside. Wear resistance of the nanocomposite with 1.0 wt.% of CNF improved of 65% (before ageing) and of 70% (after 60 days in SSF) with respect to pure UHMWPE.
In the present paper, we investigate the effectiveness of nanocomposites (composed of ultra-high molecular weight polyethylene (UHMWPE) mixed with carbon nano-filler (CNF) and medical grade paraffin ...oil (PO), from the biological point of view. Wear measurements were carried out without (air) and with lubricant (distilled water, natural, and artificial lubricant), and antibacterial activity and cytotoxicity were evaluated. The results highlighted that the presence of CNF is important in the nanocomposite formulation because it reduces the wear rate and prevents oxidative degradation during its processing. An amount of 1.0 wt % of CNF is best because it reaches the optimal distribution within the polymeric matrix, resulting in the best wear resistant, bio-active, and anti-bacterial nanocomposite among all investigated samples.
Debris formation is a crucial aspect that determines the lifespan of prosthetic joints. The wearing contact between ultra-high molecular weight polyethylene (UHMWPE) and a Ti alloy surface has been ...studied in the literature. However, when measuring mass loss, potential errors can arise due to the very small values involved (on the order of some units of 0.1 mg in experiments lasting several hours) and be caused by the absorption of humidity in the specimen, in addition to the lack of accuracy typical of weight scales. These errors can hardly be avoided, but accurate cleaning and drying processes can minimize them. With these premises, the present work aims to determine, by pin-on-disc test, the wear effect in the UHMWPE rotating sheet and Ti6Al4V pin produced by Electron Beam Melting (EBM) under dry and lubricated conditions. The morphology of the worn surface was documented by optical microscopy, and the volume loss of both the rotating specimens and the pin was accurately calculated through the detection of the wear track observed by optical microscopy. In particular, the present work proposes a method for directly determining the volume loss of the polymer to compare it with that obtained with the weight measurement. For both procedures, the uncertainty in evaluating the specific wear rate was analyzed, demonstrating that volume measurement allows for avoiding any possible error associated with weighing the polymeric specimens.
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