The properties of quantum materials are commonly tuned using experimental variables such as pressure, magnetic field and doping. Here we explore a different approach using irreversible, plastic ...deformation of single crystals. We show that compressive plastic deformation induces low-dimensional superconductivity well above the superconducting transition temperature (T
) of undeformed SrTiO
, with evidence of possible superconducting correlations at temperatures two orders of magnitude above the bulk T
. The enhanced superconductivity is correlated with the appearance of self-organized dislocation structures, as revealed by diffuse neutron and X-ray scattering. We also observe deformation-induced signatures of quantum-critical ferroelectric fluctuations and inhomogeneous ferroelectric order using Raman scattering. Our results suggest that strain surrounding the self-organized dislocation structures induces local ferroelectricity and quantum-critical dynamics that strongly influence T
, consistent with a theory of superconductivity enhanced by soft polar fluctuations. Our results demonstrate the potential of plastic deformation and dislocation engineering for the manipulation of electronic properties of quantum materials.
Abstract
The interplay between structural and electronic degrees of freedom in complex materials is the subject of extensive debate in physics and materials science. Particularly interesting ...questions pertain to the nature and extent of pre-transitional short-range order in diverse systems ranging from shape-memory alloys to unconventional superconductors, and how this microstructure affects macroscopic properties. Here we use neutron and X-ray diffuse scattering to uncover universal structural fluctuations in La
2-x
Sr
x
CuO
4
and Tl
2
Ba
2
CuO
6+δ
, two cuprate superconductors with distinct point disorder effects and with optimal superconducting transition temperatures that differ by more than a factor of two. The fluctuations are present in wide doping and temperature ranges, including compositions that maintain high average structural symmetry, and they exhibit unusual, yet simple scaling behaviour. The scaling regime is robust and universal, similar to the well-known critical fluctuations close to second-order phase transitions, but with a distinctly different physical origin. We relate this behaviour to pre-transitional phenomena in a broad class of systems with structural and magnetic transitions, and propose an explanation based on rare structural fluctuations caused by intrinsic nanoscale inhomogeneity. We also uncover parallels with superconducting fluctuations, which indicates that the underlying inhomogeneity plays an important role in cuprate physics.
We present a further simplification of the essentially parameter-free revised physical adsorption model (K. Agashe, J.R. Regalbuto, J. Colloid Interface Sci. 185 (1997) 174) in this paper. It has ...been discovered that a physical adsorption model describing the uptake of various metal complexes from aqueous solutions onto oxide surfaces can most accurately simulate experimental data when the model contains only a coulombic energy term, and not a solvation energy term. The results of the simulation for cobalt/silica, chloroplatinic acid (CPA)/alumina, and tetraamonium platinate (TAP)/alumina and silica are presented here. A reasonable justification for the omission of this term is that solvation effects are negligible when adsorbing metal complexes retain one or more hydration sheaths.
A search for the decay of the Standard Model Higgs boson into a bb¯ pair when produced in association with a W or Z boson is performed with the ATLAS detector. The data, corresponding to an ...integrated luminosity of 79.8fb−1 were collected in proton–proton collisions during Run 2 of the Large Hadron Collider at a centre-of-mass energy of 13TeV. For a Higgs boson mass of 125GeV, an excess of events over the expected background from other Standard Model processes is found with an observed (expected) significance of 4.9 (4.3) standard deviations. A combination with the results from other searches in Run 1 and in Run 2 for the Higgs boson in the bb¯ decay mode is performed, which yields an observed (expected) significance of 5.4 (5.5) standard deviations, thus providing direct observation of the Higgs boson decay into b-quarks. The ratio of the measured event yield for a Higgs boson decaying into bb¯ to the Standard Model expectation is 1.01±0.12(stat.)−0.15+0.16(syst.). Additionally, a combination of Run 2 results searching for the Higgs boson produced in association with a vector boson yields an observed (expected) significance of 5.3 (4.8) standard deviations.
This letter presents a combination of searches for Higgs boson pair production using up to 36.1fb−1 of proton–proton collision data at a centre-of-mass energy s=13 TeV recorded with the ATLAS ...detector at the LHC. The combination is performed using six analyses searching for Higgs boson pairs decaying into the bb¯bb¯, bb¯W+W−, bb¯τ+τ−, W+W−W+W−, bb¯γγ and W+W−γγ final states. Results are presented for non-resonant and resonant Higgs boson pair production modes. No statistically significant excess in data above the Standard Model predictions is found. The combined observed (expected) limit at 95% confidence level on the non-resonant Higgs boson pair production cross-section is 6.9 (10) times the predicted Standard Model cross-section. Limits are also set on the ratio (κλ) of the Higgs boson self-coupling to its Standard Model value. This ratio is constrained at 95% confidence level in observation (expectation) to −5.0<κλ<12.0 (−5.8<κλ<12.0). In addition, limits are set on the production of narrow scalar resonances and spin-2 Kaluza–Klein Randall–Sundrum gravitons. Exclusion regions are also provided in the parameter space of the habemus Minimal Supersymmetric Standard Model and the Electroweak Singlet Model.
The observation of Higgs boson production in association with a top quark pair (tt¯H), based on the analysis of proton–proton collision data at a centre-of-mass energy of 13 TeV recorded with the ...ATLAS detector at the Large Hadron Collider, is presented. Using data corresponding to integrated luminosities of up to 79.8 fb−1, and considering Higgs boson decays into bb¯, WW⁎, τ+τ−, γγ, and ZZ⁎, the observed significance is 5.8 standard deviations, compared to an expectation of 4.9 standard deviations. Combined with the tt¯H searches using a dataset corresponding to integrated luminosities of 4.5 fb−1 at 7 TeV and 20.3 fb−1 at 8 TeV, the observed (expected) significance is 6.3 (5.1) standard deviations. Assuming Standard Model branching fractions, the total tt¯H production cross section at 13 TeV is measured to be 670 ± 90 (stat.) −100+110 (syst.) fb, in agreement with the Standard Model prediction.
Measurements of the yield and nuclear modification factor, RAA, for inclusive jet production are performed using 0.49 nb−1 of Pb+Pb data at sNN=5.02TeV and 25 pb−1 of pp data at s=5.02TeV with the ...ATLAS detector at the LHC. Jets are reconstructed with the anti-kt algorithm with radius parameter R=0.4 and are measured over the transverse momentum range of 40–1000 GeV in six rapidity intervals covering |y|<2.8. The magnitude of RAA increases with increasing jet transverse momentum, reaching a value of approximately 0.6 at 1 TeV in the most central collisions. The magnitude of RAA also increases towards peripheral collisions. The value of RAA is independent of rapidity at low jet transverse momenta, but it is observed to decrease with increasing rapidity at high transverse momenta.
Measurements of the Standard Model Higgs boson decaying into a
b
b
¯
pair and produced in association with a
W
or
Z
boson decaying into leptons, using proton–proton collision data collected between ...2015 and 2018 by the ATLAS detector, are presented. The measurements use collisions produced by the Large Hadron Collider at a centre-of-mass energy of
s
=
13
Te
, corresponding to an integrated luminosity of
139
fb
-
1
. The production of a Higgs boson in association with a
W
or
Z
boson is established with observed (expected) significances of 4.0 (4.1) and 5.3 (5.1) standard deviations, respectively. Cross-sections of associated production of a Higgs boson decaying into bottom quark pairs with an electroweak gauge boson,
W
or
Z
, decaying into leptons are measured as a function of the gauge boson transverse momentum in kinematic fiducial volumes. The cross-section measurements are all consistent with the Standard Model expectations, and the total uncertainties vary from 30% in the high gauge boson transverse momentum regions to 85% in the low regions. Limits are subsequently set on the parameters of an effective Lagrangian sensitive to modifications of the
WH
and
ZH
processes as well as the Higgs boson decay into
b
b
¯
.
Celotno besedilo
Dostopno za:
DOBA, IZUM, KILJ, NUK, PILJ, PNG, SAZU, SIK, UILJ, UKNU, UL, UM, UPUK
A search for high-mass dielectron and dimuon resonances in the mass range of 250GeV to 6TeV is presented. The data were recorded by the ATLAS experiment in proton–proton collisions at a ...centre-of-mass energy of s=13TeV during Run 2 of the Large Hadron Collider and correspond to an integrated luminosity of 139 fb−1. A functional form is fitted to the dilepton invariant-mass distribution to model the contribution from background processes, and a generic signal shape is used to determine the significance of observed deviations from this background estimate. No significant deviation is observed and upper limits are placed at the 95% confidence level on the fiducial cross-section times branching ratio for various resonance width hypotheses. The derived limits are shown to be applicable to spin-0, spin-1 and spin-2 signal hypotheses. For a set of benchmark models, the limits are converted into lower limits on the resonance mass and reach 4.5TeV for the E6-motivated Zψ′ boson. Also presented are limits on Heavy Vector Triplet model couplings.
Hydrogen hexachloroplatinate(IV), also called chloroplatinic acid (CPA), is a strong acid that undergoes rapid and extensive hydrolysis. Extended X-ray absorption fine structure (EXAFS) ...characterization was performed at the Advanced photon source (APS) at Argonne National Laboratory to determine the PtCl and PtO co-ordination chemistry of 200–2000
ppm CPA at pHs of 1.5–12 with different chloride concentrations, light conditions, and time frames. The EXFAS analysis was combined with potentiometric data to postulate the following speciation behavior of the dilute CPA. The initial hydrolysis reaction, aquo ligand exchange of chloride ions, is rapid and reversible, while the latter two reactions, hydroxide ion ligand exchange of chloride and aquo ligands, are relatively slow in acidic solutions but accelerated in the presence of light. Many of the stable Pt complexes in solution are zero valent. High chloride co-ordination is favored at low pH and high chloride concentration. As a result, the PtCl
6
2− species is present only in acidic solutions with a moderate excess of chloride ion or in the neutral solutions in a large excess of chloride ion. Hydroxide ligand formation is favored at low pH and suppressed by chloride ion concentration. As a result, full hydrolysis of CPA by hydroxide ions with precipitation of H
2Pt(OH)
6 (or Na
2Pt(OH)
6) is favored only at very low CPA concentrations (ca. 30
ppm).
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