A delicate control of the stoichiometry, crystallographic phase, and grain structure of the photoactive material is typically required to fabricate high-performance photovoltaic (PV) devices. ...Organo-metal halide perovskite materials, however, exhibit a large degree of tolerance in synthesis and can be fabricated into high efficiency devices by a variety of different vacuum and solution-based processes, with a wide range of precursor ratios. This suggests that the phase field for the desired material is wider than expected or that high device efficiency may be achieved with a range of phases. Here, we investigate the structural and optical properties of the materials formed when a range of compositions of methylammonium iodide (MAI) and lead iodide (PbI2) were reacted at temperatures from 40 to 190 °C. The reactions were performed according to a commonly employed synthetic approach for high efficiency PV devices, and the data was analyzed to construct a pseudobinary, temperature-dependent, phase-composition processing diagram. Escape of MAI vapor at the highest temperatures (150–190 °C) enabled a PbI2 phase to persist to very high MAI concentrations, and the processing diagram was not representative of phase equilibrium in this range. Data from reactions performed with a fixed vapor pressure of MAI allowed the high temperature portion of the diagram to be corrected and a near-equilibrium phase diagram to be proposed. The perovskite phase field is wider than previously thought under both processing conditions and extended by the existence of stacked perovskite sheet phases. Several aspects of the diagrams clarify why the organo-halide perovskite materials are compatible with solution processing.
Emerging insights from adaptive and community-based resource management suggest that building resilience into both human and ecological systems is an effective way to cope with environmental change ...characterized by future surprises or unknowable risks. We argue that these emerging insights have implications for policies and strategies for responding to climate change. We review perspectives on collective action for natural resource management to inform understanding of climate response capacity. We demonstrate the importance of social learning, specifically in relation to the acceptance of strategies that build social and ecological resilience. Societies and communities dependent on natural resources need to enhance their capacity to adapt to the impacts of future climate change, particularly when such impacts could lie outside their experienced coping range. This argument is illustrated by an example of present-day collective action for community-based coastal management in Trinidad and Tobago. The case demonstrates that community-based management enhances adaptive capacity in two ways: by building networks that are important for coping with extreme events and by retaining the resilience of the underpinning resources and ecological systems.
This paper investigates whether and to what extent a wide range of actors in the UK are adapting to climate change, and whether this is evidence of a social transition. We document evidence of over ...300 examples of early adopters of adaptation practice to climate change in the UK. These examples span a range of activities from small adjustments (or coping), to building adaptive capacity, to implementing actions and to creating deeper systemic change in public and private organisations in a range of sectors. We find that adaptation in the UK has been dominated by government initiatives and has principally occurred in the form of research into climate change impacts. These government initiatives have stimulated a further set of actions at other scales in public agencies, regulatory agencies and regional government (and the devolved administrations), though with little real evidence of climate change adaptation initiatives trickling down to local government level. The sectors requiring significant investment in large scale infrastructure have invested more heavily than those that do not in identifying potential impacts and adaptations. Thus we find a higher level of adaptation activity by the water supply and flood defence sectors. Sectors that are not dependent on large scale infrastructure appear to be investing far less effort and resources in preparing for climate change. We conclude that the UK government-driven top-down targeted adaptation approach has generated anticipatory action at low cost in some areas. We also conclude that these actions may have created enough niche activities to allow for diffusion of new adaptation practices in response to real or perceived climate change. These results have significant implications for how climate policy can be developed to support autonomous adaptors in the UK and other countries.
The Paris Agreement requires measurement of the progress made on adaptation. Tracking the progress made by governments through analysis of policies provides insight into the goals and means to ...achieve adaptation targets. Here we show the current state-of-the-art in public adaptation planning affecting 136 of the largest coastal port urban agglomerations, covering 68 countries. We identify 226 adaptation policies: 88 at national level, 57 at regional/state level and 81 at city/metropolitan level. This set of adaptation policies can be considered the latest, most up-to-date database of governmental and public-led adaptations. Our analyses show that (1) in one half of cases, there is no evidence of policy implementation, (2) in almost 85% of cases, planned adaptation actions are not driven by present or future climatic impacts or risks, and (3) formal adaptation planning is relatively recent and is concentrated in more developed areas and countries.
Cystic fibrosis (CF) clinical care guidelines exist for the care of infants up to age 2 years and for individuals ≥6 years of age. An important gap exists for preschool children between the ages of 2 ...and 5 years. This period marks a time of growth and development that is critical to achieve optimal nutritional status and maintain lung health. Given that disease often progresses in a clinically silent manner, objective and sensitive tools that detect and track early disease are important in this age group. Several challenges exist that may impede the delivery of care for these children, including adherence to therapies. A multidisciplinary committee was convened by the CF Foundation to develop comprehensive evidence-based and consensus recommendations for the care of preschool children, ages 2 to 5 years, with CF. This document includes recommendations in the following areas: routine surveillance for pulmonary disease, therapeutics, and nutritional and gastrointestinal care.
To better anticipate potential impacts of climate change, diverse information about the future is required, including climate, society and economy, and adaptation and mitigation. To address this ...need, a global RCP (Representative Concentration Pathways), SSP (Shared Socio-economic Pathways), and SPA (Shared climate Policy Assumptions) (RCP–SSP–SPA) scenario framework has been developed by the Intergovernmental Panel on Climate Change Fifth Assessment Report (IPCC-AR5). Application of this full global framework at sub-national scales introduces two key challenges: added complexity in capturing the multiple dimensions of change, and issues of scale. Perhaps for this reason, there are few such applications of this new framework. Here, we present an integrated multi-scale hybrid scenario approach that combines both expert-based and participatory methods. The framework has been developed and applied within the DECCMA11DECCMA (DEltas, vulnerability and Climate Change: Migration and Adaptation) project is part of the Collaborative Adaptation Research Initiative in Africa and Asia (CARIAA), with financial support from the UK Government's Department for International Development (DFID) and the International Development Research Centre (IDRC), Canada. For more information, visit the project website: http://www.geodata.soton.ac.uk/deccma/. project with the purpose of exploring migration and adaptation in three deltas across West Africa and South Asia: (i) the Volta delta (Ghana), (ii) the Mahanadi delta (India), and (iii) the Ganges-Brahmaputra-Meghna (GBM) delta (Bangladesh/India). Using a climate scenario that encompasses a wide range of impacts (RCP8.5) combined with three SSP-based socio-economic scenarios (SSP2, SSP3, SSP5), we generate highly divergent and challenging scenario contexts across multiple scales against which robustness of the human and natural systems within the deltas are tested. In addition, we consider four distinct adaptation policy trajectories: Minimum intervention, Economic capacity expansion, System efficiency enhancement, and System restructuring, which describe alternative future bundles of adaptation actions/measures under different socio-economic trajectories. The paper highlights the importance of multi-scale (combined top-down and bottom-up) and participatory (joint expert-stakeholder) scenario methods for addressing uncertainty in adaptation decision-making. The framework facilitates improved integrated assessments of the potential impacts and plausible adaptation policy choices (including migration) under uncertain future changing conditions. The concept, methods, and processes presented are transferable to other sub-national socio-ecological settings with multi-scale challenges.
An integrated scenario framework for applying the global RCP–SSP–SPA scenario framework at sub-national scale: A multi-scale and participatory approach. The generic framework (left) is applied and demonstrated within the DECCMA project to explore migration and adaptation in deltas (right, showing the various scales of interest and broad workflow). Display omitted
•We develop a framework for applying the global RCP-SSP-SPA scenario framework at sub-national scales.•The framework is applied and tested for deltas to explore migration and adaptation.•We demonstrated the benefits of a multi-dimensional approach to capture different drivers of change.•Highlighted the need to integrate the best science and stakeholder views.•The concept, methods, processes are transferrable to other sub-national settings with multi-scale challenges.
Climate change poses many challenges for ecosystem and resource management. In particular, coastal planners are struggling to find ways to prepare for the potential impacts of future climate change ...while dealing with immediate pressures. Decisions on how to respond to future risks are complicated by the long time horizons and the uncertainty associated with the distribution of impacts. Existing coastal zone management approaches in the UK either do not adequately incorporate changing stakeholder preferences, or effectively ensure that stakeholders are aware of the trade-offs inherent in any coastal management decision.
Using a novel method, scenario-based stakeholder engagement, which brings together stakeholder analysis, climate change management scenarios and deliberative techniques, the necessary trade-offs associated with long term coastal planning are explored. The method is applied to two case studies of coastal planning in Christchurch Bay on the south coast of England and the Orkney Islands off the north coast of Scotland. A range of conflicting preferences exist on the ideal governance structure to manage the coast under different climate change scenarios. In addition, the results show that public understanding of the trade-offs that have to be made is critical in gaining some degree of public support for long term coastal decision-making. We conclude that scenario-based stakeholder engagement is a useful tool to facilitate coastal management planning that takes into account the complexities and challenges of climate change, and could be used in conjunction with existing approaches such as the Shoreline Management Planning process.
Abstract
Brown algae blooms and invasions have affected 29% of the Earth’s coast, yet there is sparse evidence of the impacts and adaptations of these events. Through a systematic review of empirical ...literature on these blooms and invasions, we explore the prevalence of conventional analyses of environmental, economic, and social impacts, as well as opportunities for adaptation and valorisation. The study reveals crucial inconsistencies in the current evidence base on algae impacts: fragmented metrics for quantifying blooms and their effects; inconsistent application and testing of prevention measures (e.g. forecasting, early warning systems); reliance on removal as a management approach with limited evidence of associated costs; and scant evidence of the effectiveness of impact mitigation or adaptation strategies. With a focus on economic and societal dimensions of algae events, we introduce emerging opportunities within the blue economy for bloom utilization. The findings highlight the crucial need for harmonized monitoring protocols, robust cost-benefit analysis of management and adaptation options, and evidence of pathways to valorisation of algae biomass.
Trichomonas vaginalis (TV) infection is common, curable, and associated with significant reproductive morbidity and risk for HIV infection. This analysis updates estimates of the prevalence of ...asymptomatic TV infection, and its associated risk factors, in the non-institutionalized U.S. population.
We analyzed data from 4057 individuals who participated in the National Health and Nutrition Examination Survey (NHANES) 2013-2014 data collection cycle. Participant interviews ascertained demographic characteristics, self-reported tobacco use, and sexual history. Self-collected urine specimens from participants aged 18 to 59 years were tested for TV infection using the Gen-Probe Aptima TV assay. Cotinine was assayed from serum to provide a biomarker of recent tobacco exposure. Weighted percentages are provided to account for unequal selection probabilities among participants and adjustments for non-response.
Our sample included 1942 men (49.2%, 95% Confidence Interval CI 48.0-50.5) and 2115 women (50.8%, 95%CI 49.5-52.0). The infection prevalence among men was 0.5% (n = 16; 95%CI 0.2-1.0) and 1.8% (n = 55; 95%CI 1.1-3.1) in women. After controlling for participant characteristics associated with TV infection, females had a 5.2-fold increased odds of being infected compared to men (adjusted odds ratio (aOR) 5.2, 95% CI 2.4-11.4). Non-Hispanic blacks were more likely to be infected compared to non-Hispanic whites (aOR 11.2, 95% CI 4.6-27.2). Individuals below the federal poverty level were more likely to be infected compared to those earning >3 times the federal poverty level (aOR 6.7, 95% CI 1.7-26.6), and active smokers were more likely to be infected compared to participants with no nicotine exposure (aOR 8.7, 95% CI 4.1-18.2).
Trichomonas vaginalis infection continues to be relatively common, especially in women, smokers, non-Hispanic blacks, and in groups of lower socioeconomic status. Identifying the demographic characteristics of populations in the United States disproportionately affected by TV could impact screening and treatment of this infection in clinical practice. Further research on whether screening and treating for asymptomatic TV infection in high-risk populations improves risk for reproductive morbidity and HIV infection is warranted.
Celotno besedilo
Dostopno za:
DOBA, IZUM, KILJ, NUK, PILJ, PNG, SAZU, SIK, UILJ, UKNU, UL, UM, UPUK
We investigate linkages between stakeholders in resource management that occur at different spatial and institutional levels and identify the winners and losers in such interactions. So-called ...cross-scale interactions emerge because of the benefits to individual stakeholder groups in undertaking them or the high costs of not undertaking them. Hence there are uneven gains from cross-scale interactions that are themselves an integral part of social-ecological system governance. The political economy framework outlined here suggests that the determinants of the emergence of cross-scale interactions are the exercise of relative power between stakeholders and their costs of accessing and creating linkages. Cross-scale interactions by powerful stakeholders have the potential to undermine trust in resource management arrangements. If government regulators, for example, mobilize information and resources from cross-level interactions to reinforce their authority, this often disempowers other stakeholders such as resource users. Offsetting such impacts, some cross-scale interactions can be empowering for local level user groups in creating social and political capital. These issues are illustrated with observations on resource management in a marine protected area in Tobago in the Caribbean. The case study demonstrates that the structure of the cross-scale interplay, in terms of relative winners and losers, determines its contribution to the resilience of social-ecological systems.
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