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•Eoarchean zircon grains are preserved in the sediments of the Carajás Basin.•The Carajás Domain contains relicts of a Paleo- to early Mesoarchean basin.•The Carajás Domain hosts the ...Neoarchean Parauapebas Large Igneous Province.•The LIP immediately preceded a period of continental extension that formed a rift.•The Carajás Basin evolved to a Transamazonian back-bulge basin.
Despite representing one of the largest cratons on Earth, the early geological evolution of the Amazonia Craton remains poorly known due to relatively poor exposure and because younger metamorphic and tectonic events have obscured initial information. In this study, we investigated the sedimentary archives of the Carajás Basin to unravel the early geological evolution of the southeastern Amazonia Craton. The Carajás Basin contains sedimentary rocks that were deposited throughout a long period spanning more than one billion years from the Mesoarchean to the Paleoproterozoic. The oldest archives preserved in this basin consist of a few ca. 3.6 Ga detrital zircon grains showing that the geological roots of the Amazonia Craton were already formed by the Eoarchean. During the Paleoarchean or the early Mesoarchean (<3.1 Ga), the Carajás Basin was large and rigid enough to sustain the formation and preservation of the Rio Novo Group greenstone belt. Later, during the Neoarchean, at ca. 2.7 Ga, the southeastern Amazonia Craton witnessed the emplacement of the Parauapebas Large Igneous Province (LIP) that probably covered a large part of the craton and was associated with the deposition of some of the world largest iron formations. The emplacement of this LIP immediately preceded a period of continental extension that formed a rift infilled first by iron formations followed by terrigenous sediments. This major change of sedimentary regime might have been controlled by the regional tectonic evolution of the Amazonia Craton and its emergence above sea-level. During the Paleoproterozoic, at ca. 2.1 Ga, the Rio Fresco Group, consisting of terrigenous sediments from the interior of the Amazonia Craton, was deposited in the Carajás Basin. At that time, the Amazonian lithosphere could have either underwent thermal subsidence forming a large intracratonic basin or could have been deformed by long wavelength flexures that induced the formation of basins and swells throughout the craton under the influence of the growing Transamazonian mountain belt.
Spinel is a ubiquitous mineral in mafic/ultramafic rocks. Spinel cores chemistry is extensively used as a petrogenetic proxy while their alteration phases, ferritchromite, and Cr‐magnetite, are used ...as metamorphic grade indicators. However, the magnetic properties and composition of these phases are still ill‐defined and no consensus exists concerning the metamorphic conditions involved in their formation. Here, we use the magnetic properties of these Cr‐spinel alteration phases, via field‐dependent parameters and observations with a magnetic microscope coupled with mineral chemistry and Mössbauer spectroscopy, to better constrain their composition. We identify Cr‐magnetite by a Curie point of ca. 520°C. We show that it is characterized by an n between 0.1 and 0.2 in the Fe‐Cr spinel formula Fe2+(Fe1−nCrn)2O4, which corresponds to 6–13 wt.% of Cr2O3. The abundance of Cr‐magnetite indicates a strong alteration of Cr‐spinels that could reflect a significant hydrothermal activity rather than a high metamorphism grade. Normalized variation curves of the magnetic susceptibility during heating allow a relative quantification of the contributions of different magnetic phases to the magnetic susceptibility. This highlights a link between ferritchromite destabilization into maghemite at ca. 130°C followed by the destabilization of this maghemite starting at 300°C. We identify specific covariation trends between these two magnetic species characterizing different alteration processes. This study opens the door to magnetic monitoring of the Cr‐spinel alteration state in mafic and ultramafic rocks. It constitutes a new, fast, and weakly destructive way to study the petrological history of both terrestrial and extraterrestrial rocks.
Plain Language Summary
Spinels are a common accessory mineral in Earth's mantle rocks, basaltic lavas and more generally, in mafic/ultramafic rocks from other telluric bodies. Because they are often (partially) preserved even in the case of highly altered rocks like serpentinites, and their chemistry is dependent on magmatic and metamorphic processes, they have been used for decades to investigate the history of their host rock. In this study, we focus on the magnetic and chemical characterization of the phases that compose spinel alteration rims, namely the ferritchromite and the Cr‐magnetite (Chromium‐rich magnetite). Coupling the magnetism and mineral chemistry methods allowed us to better constrain the magnetic behavior of these mineral phases, hence defining clear magnetic signatures for them and precise their chemical composition fields. We show that magnetic measurements can be used to finely monitor the spinels alteration state by quantifying the relative contributions of their different alteration products to the magnetization of a given rock sample. This constitutes a new way to study the metamorphic and/or hydrothermal history of both terrestrial and extraterrestrial rocks.
Key Points
Main spinel alteration products can be easily identified via thermomagnetic measurements
We redefine Cr‐magnetite as a Fe‐Cr spinel Fe2+(Fe1−nCrn)2O4, with 0.1 < n < 0.2 (6–13 wt.% of Cr2O3) and with a Tc at ca. 500–530°C
This study opens the door to magnetic monitoring of the Cr‐spinel alteration state in mafic and ultramafic rocks
South America contributes only a small fraction of the global archeomagnetic data. Recent work in the region has expanded significantly the previous database with new data being generated from Chile, ...Argentina, Northeast and Southeast Brazil. We report here new results from Jesuit Missions in South Brazil, at the triple border with Argentina and Paraguay. Our archeological collection comprises a total of 24 fragments of baked clay construction materials from three Jesuit Missions, São Luiz Gonzaga 1657–1687 AD (3 fragments), São João Batista 1667–1697 AD (4 fragments) and Santo Ângelo 1676–1706 AD (17 fragments). Archeointensity determinations were performed with the double-heating technique in its modified form, with pTRM checks and pTRM tail checks. Measurements were complemented by anisotropy and cooling-rate corrections. A total of 24 specimens (11 fragments) passed strict quality selection, corresponding to a success rate of 45%. We also performed an experimental test for the 6-specimen average anisotropy correction technique and we show that it does not correct for the effects of TRM anisotropy. Results were similar within error for the three missions: São Luiz Gonzaga (40.2±2.4 μT), São João Batista (39.1±1.6 μT) and Santo Ângelo (41.1±2.0 μT). These data were then compared with the most reliable data from South America, after a critical assessment of the current database. According to our analysis, only 39 intensity data for the continent can be considered as high-quality, most within the last 700 years; only three data were retained for older periods (800–1100 AD). The filtered data match reasonably well the available models for the past five centuries. A combined curve for South and Southeast Brazil plus Argentina plot systematically below relocated data from NE Brazil and Chile. These differences are likely due to complexities in the geometry of the field in South America not appropriately accounted for by a simple axial dipole. Our analysis highlights the need for high-quality data for the continent.
•Three high-quality archeointensity data are presented for South America.•The South American database is reassessed to retain only high-quality entries.•The filtered results are coherent and define a well-behaved evolution of the field.•We prove the 6-specimen average technique does not correct for anisotropy effects.
The end of the Neoproterozoic is punctuated by glacial deposition, but the chronology of these deposits is hindered presently by the paucity of geochronological data. Here, we present new radiometric ...dating for the basal Sete Lagoas cap carbonate deposits that overlie glacial units in the São Francisco craton. Six samples from aragonite‐pseudomorph crystal‐rich facies, showing pristine textures and constant 87Sr/86Sr ratios around 0.7075, yielded a Pb–Pb isochron age of 740 ± 22 Ma, which is interpreted as the depositional age for these remarkably preserved rocks. This age can be used to infer a low‐to‐moderate palaeolatitude of 20–30° for carbonate (and glacial) deposition. In addition, as it overlaps the ages obtained for the oldest Neoproterozoic glacial successions, our result reinforces the idea of a long‐standing ‘Sturtian’ interval, suggesting that this event represents either different discrete glaciations or a protracted event encompassing almost 80 Ma.
SUMMARY
Palaeosecular variation (PSV) determinations and studies of the geometry of the Earth’s main magnetic field provide important information about the field evolution, and to constrain numerical ...geodynamo models. Palaeomagnetic directional data from lava flows over the last few million years is of particular interest because the regional and global tectonic effects are minimal. However, the distribution of this type of palaeomagnetic data is uneven where the Southern Hemisphere is the destitute side. Therefore, the better knowledge of the geomagnetic field behaviour depends on the increased availability of high-quality data, especially in the Southern Hemisphere. A PSV and the time-averaged field (TAF) study was then performed in 0–5 Ma lava flows from the Caviahue–Copahue Volcanic Complex located in Northern Patagonia, Argentina (37°0′S, 71°10′W). The magnetic mineralogy of lava flows was investigated through thermomagnetic susceptibility curves, isothermal remanent magnetization (IRM) acquisition curves, hysteresis loops and first-order reversal curves (FORCs). Samples are essentially comprised of titanomagnetite with different Ti contents and magnetic domain structures typical of vortex state particles. A total of 50 volcanic sites were sampled, which provided 42 reliable palaeomagnetic site-mean directions after alternating field and thermal demagnetization. From these 42 sites, 36 are of normal and 6 are of reversed polarity. The mean direction from normal (reversed) sites is D = 356.2°, I = −50.1°, α95 = 4.0° and N = 36 (D = 176.5°, I = 59.5°, α95 = 14.1° and N = 6). Using only site-level data with the precision parameter k ≥ 100, we obtain 26 palaeomagnetic sites for PSV and TAF investigations in the study region. The filtered data set has a mean direction (D = 354.4°, I = −53.2° and α95 = 5.1°) close to the expected direction for a geocentric axial dipole (GAD) field (IGAD = −57.3°). The palaeopole (Plat = 84.4°, Plon = 229.1° and A95 = 5.7°) coincides with the Earth’s spin axis within the 95 per cent confidence interval. Virtual geomagnetic pole scatter ($S_{B} = {15.8^{18.9}_{11.8}}^{\circ }$) and the inclination anomaly ($\Delta I = 4.1_{-1.0}^{{9.2}^{\circ }}$) are both consistent at the 95 per cent confidence level with recent PSV and TAF models, respectively. Our results support the presence of small non-dipole field contributions (<3 per cent) superimposed on the GAD term, as reported by South American studies at mid southern latitudes.
The terminal Neoproterozoic Era (850-542 Ma) is characterized by the most pronounced positive sulfur isotope ((34)S/(32)S) excursions in Earth's history, with strong variability and maximum values ...averaging δ(34)S∼+38‰. These excursions have been mostly interpreted in the framework of steady-state models, in which ocean sulfate concentrations do not fluctuate (that is, sulfate input equals sulfate output). Such models imply a large pyrite burial increase together with a dramatic fluctuation in the isotope composition of marine sulfate inputs, and/or a change in microbial sulfur metabolisms. Here, using multiple sulfur isotopes ((33)S/(32)S, (34)S/(32)S and (36)S/(32)S ratios) of carbonate-associated sulfate, we demonstrate that the steady-state assumption does not hold in the aftermath of the Marinoan Snowball Earth glaciation. The data attest instead to the most impressive event of oceanic sulfate drawdown in Earth's history, driven by an increased pyrite burial, which may have contributed to the Neoproterozoic oxygenation of the oceans and atmosphere.
Extensive phosphorite deposition is observed in the Neoproterozoic after a prolonged hiatus during most of the Mesoproterozoic era. This event is thought to represent an important record of major ...palaeoenvironmental, palaeoceanographic and biotic changes that shaped Neoproterozoic ecosystems, suggesting close relationships between phosphogenesis and the preservation of key Ediacaran biotas. However, high‐grade Ediacaran phosphorite deposits are relatively uncommon, diminishing the opportunity to test current phosphate mineralization–deposition models and their implications for Neoproterozoic research. In this scenario, widespread Ediacaran phosphorite–dolomite–shale successions of the Bocaina Formation (Corumbá Group – Central Brazil) are poorly explored in international literature. Nevertheless, recent advances in phosphate exploration gave access to continuous drill core sections and freshly opened mine pits, revealing an unprecedented record of complex phosphatic successions featuring the occurrence of Ediacaran microfossils assigned to the Doushantuo–Pertatataka assemblages. This work seeks to constrain main lithofacies, sequence stratigraphy and depositional settings from these phosphatic successions in order to analyse the sedimentary evolution of the unit under the current Neoproterozoic phosphorite research framework. These results indicate that the Bocaina Formation records secular sustained phosphate deposition. These deposits are related to unprecedented, microbialite reef rim phosphorites deposited during a lower accretionary rimmed platform stage, followed by the deposition of Doushantuo‐like, whole platform phosphorites associated with a later, drowned platform stage, therefore, reinforcing the evidence for the operation of strong allogeneic controls on phosphate mineralization–concentration. In addition, this study concludes that fossiliferous Ediacaran phosphatic deposits such as the Bocaina Formation are important to understanding Neoproterozoic phosphogenic events, because they may record the transition from a Precambrian to Phanerozoic‐like phosphogenesis associated with the instauration of the Ediacaran–Cambrian phosphatic taphonomic window. This evidence hints that the growing dataset from the Bocaina Formation may bring new, exciting perspectives for Neoproterozoic research as a whole.
Earth's climate experienced a warming event known as the Middle Eocene Climatic Optimum (MECO) at ~40Ma, which was an abrupt reversal of a long-term Eocene cooling trend. This event is characterized ...in the deep Southern, Atlantic, Pacific and Indian Oceans by a distinct negative δ18O excursion over 500kyr. We report results of high-resolution paleontological, geochemical, and rock magnetic investigations of the Neo-Tethyan Monte Cagnero (MCA) section (northeastern Apennines, Italy), which can be correlated on the basis of magneto- and biostratigraphic results to the MECO event recorded in deep-sea sections. In the MCA section, an interval with a relative increase in eutrophic nannofossil taxa (and decreased abundances of oligotrophic taxa) spans the culmination of the MECO warming and its aftermath and coincides with a positive carbon isotope excursion, and a peak in magnetite and hematite/goethite concentration. The magnetite peak reflects the appearance of putative magnetofossils, while the hematite/goethite apex is attributed to an enhanced detrital mineral contribution, likely as aeolian dust transported from the continent adjacent to the Neo-Tethys Ocean during a drier, more seasonal climate during the peak MECO warming. Based on our new geochemical, paleontological and magnetic records, the MECO warming peak and its immediate aftermath are interpreted as a period of high primary productivity. Sea-surface iron fertilization is inferred to have stimulated high phytoplankton productivity, increasing organic carbon export to the seafloor and promoting enhanced biomineralization of magnetotactic bacteria, which are preserved as putative magnetofossils during the warmest periods of the MECO event in the MCA section. Together with previous studies, our work reinforces the connection between hyperthermal climatic events and the occurrence (or increased abundance) of putative magnetofossils in the sedimentary record.
•The studied record spans the Middle Eocene Climatic Optimum at Monte Cagnero, Italy.•Paleontological, geochemical, and rock magnetic investigations were conduced.•Fine magnetite content reflects enhanced magnetofossil contents during MECO warming.•Iron fertilization stimulated high phytoplankton productivity during the MECO.
The Paraná-Etendeka Magmatic Province is associated with the distensive tectonics that caused the rupture of the Gondwana continent during the Lower Cretaceous and generated an intense volcanism that ...covers South America and the NW portion of Namibia in Africa. In Brazil, this volcanic sequence is named Serra Geral Group and predominantly consists of basalts and subordinated silicic rocks. The goal of this study is to characterize the geomorphological features observed in the Aparados da Serra region, southern Brazil, and to evaluate the relationship between these structures and the primary silicic volcanic structures. The geomorphological features were first identified using remote sensing and then correlated with flow structures observed in the field, as well as petrographic and geochemical data. AMS data were used to determine magnetic patterns and the direction of magmatic flow of the rocks. Despite the low degree of anisotropy, clear patterns of lineation and foliation were identified in the studied rocks. Our data shows that Units I and II correspond to silicic lava flows linked to effusive fissure eruptions, presenting a dome morphology caused by differential erosion. Unit III rocks may correspond to true volcanic domes, whereas the Unit IV corresponds to the effusive feeder structures.
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