Fabricating nanocavities in which optically active single quantum emitters are precisely positioned is crucial for building nanophotonic devices. Here we show that self-assembly based on robust ...DNA-origami constructs can precisely position single molecules laterally within sub-5 nm gaps between plasmonic substrates that support intense optical confinement. By placing single-molecules at the center of a nanocavity, we show modification of the plasmon cavity resonance before and after bleaching the chromophore and obtain enhancements of ≥4 × 103 with high quantum yield (≥50%). By varying the lateral position of the molecule in the gap, we directly map the spatial profile of the local density of optical states with a resolution of ±1.5 nm. Our approach introduces a straightforward noninvasive way to measure and quantify confined optical modes on the nanoscale.
Acceleration of high energy ions was observed in z-pinches and dense plasma foci as early as the 1950s. Even though many theories have been suggested, the ion acceleration mechanism remains a source ...of controversy. Recently, the experiments on the GIT-12 generator demonstrated acceleration of ions up to 30 MeV from a deuterium gas-puff z-pinch. High deuteron energies enable us to obtain unique information about spatial, spectral and temporal properties of accelerated ions. In particular, the off-axis ion emission from concentric circles of a ∼1 cm diameter and the radial lines in an ion beam profile are germane for the discussion of acceleration mechanisms. The acceleration of 30 MeV deuterons can be explained by the fast increase of an impedance with a sub-nanosecond e-folding time. The high (>10 ) impedance is attributed to a space-charge limited flow after the effective ejection of plasmas from m = 0 constrictions. Detailed knowledge of the ion acceleration mechanism is used with a neutron-producing catcher to increase neutron yields above 1013 at a current of 2.7 MA.
We study in real time the optical response of individual plasmonic nanoparticles on a mirror, utilized as electrodes in an electrochemical cell when a voltage is applied. In this geometry, Au ...nanoparticles are separated from a bulk Au film by an ultrathin molecular spacer. The nanoscale plasmonic hotspot underneath the nanoparticles locally reveals the modified charge on the Au surface and changes in the polarizability of the molecular spacer. Dark-field and Raman spectroscopy performed on the same nanoparticle show our ability to exploit isolated plasmonic junctions to track the dynamics of nanoelectrochemistry. Enhancements in Raman emission and blue-shifts at a negative potential show the ability to shift electrons within the gap molecules.
Acceleration of ions to multi-MeV energies is investigated in various plasma devices to better understand processes in astrophysical plasmas and to develop efficient accelerators for a variety of ...applications. This paper reports the production of proton, deuteron, and electron beams in a z-pinch-a cylindrically symmetric plasma column that is compressed by its own magnetic field. For this work, the GIT-12 pulsed-power generator was used to drive a novel configuration of z-pinch that dramatically enhanced ion acceleration associated with disruption of the current by instabilities in the compressed plasma. During the disruption of 3 MA current, hydrogen ions were accelerated up to at least 50 MeV, which is almost a hundred-times the ion energy provided by the generator driving voltage of 0.6 MV. Under optimal conditions, the total numbers of hydrogen ions with energies above 20 and 50 MeV were 4 × 1013 and 1011, respectively. Accelerated deuterons produced one 20 ns (full width at half maximum) pulse of fast neutrons via D(d, n)3He and other nuclear reactions. A maximum neutron output of (1.0 ± 0.2) × 1012 neutrons/sr was observed downstream, i.e., in the anode to cathode direction. In this direction, the maximum neutron energy reached 58 ± 7 MeV. Both ion and neutron beams in our experiment reached an end-point energy of about 60 MeV, which is the highest value observed in pulsed-power devices. A localized peak voltage of ≳60 MV was driven by the inductive energy that was stored around the plasma column and that was extracted during a sub-nanosecond current drop. Considering the natural occurrence of current-carrying columns in laboratory and space plasmas, the current interruption observed in z-pinches could represent a more general physical process that contributes to the efficient conversion of magnetic energy into the energy of particle beams in various plasmas.
We study the optical response of individual nm-wide plasmonic nanocavities using a nanoparticle-on-mirror design utilised as an electrode in an electrochemical cell. In this geometry Au nanoparticles ...are separated from a bulk Au film by an ultrathin molecular spacer, giving intense and stable Raman amplification of 100 molecules. Modulation of the plasmonic spectra and the SERS response is observed with an applied voltage under a variety of electrolytes. Different scenarios are discussed to untangle the various mechanisms that can be involved in the electronic interaction between NPs and electrode surfaces.
Mega-ampere dense plasma foci and deuterium gas-puff z-pinches can accelerate deuterons to multi-MeV energies. Diagnostic measurements of the properties of these ions provide information about ion ...acceleration in z-pinch plasmas. In particular, the results from ion pinhole cameras seem to be useful for the discussion of ion acceleration mechanisms. Recently, we have used various configurations of ion pinhole cameras in deuterium gas-puff experiments on the GIT-12 generator at the Institute of High Current Electronics in Tomsk and on the HAWK generator at the US Naval Research Laboratory in Washington. The stack of radiochromic films and CR-39 solid-state nuclear track detectors recorded deuterons with energies up to 30 MeV. From our ion diagnostics, we obtained the spatial distribution of the ion source and the ion-beam divergence during the ion emission. This ion-beam divergence was found to decrease with increasing deuteron energy. At 20 MeV, the divergence of each of the individual micro-beams that composed the ion source was on the order of 10 mrad. The deflection of each micro-beam due to the azimuthal magnetic and/or radial electric fields resulted in radial stripes observed by the beam-profile detectors. By analyzing the ion pinhole images, we found that the deuterons were emitted both from a central spot and from a ring-shaped region with a rather large diameter, on the order of 1 cm. The origin and particular diameter of this ring is attributed to the geometry of the electrodes and to the distribution of the current density before the disruption.
Objectives
To determine the optimal imaging time point for transcatheter aortic valve implantation (TAVI) therapy planning by comprehensive evaluation of the aortic root.
Methods
Multidetector-row CT ...(MDCT) examination with retrospective ECG gating was retrospectively performed in 64 consecutive patients referred for pre-TAVI assessment. Eighteen different parameters of the aortic root were evaluated at 11 different time points in the cardiac cycle. Time points at which maximal (or minimal) sizes were determined, and dimension differences to other time points were evaluated. Theoretical prosthesis sizing based on different measurements was compared.
Results
Largest dimensions were found between 10 and 20 % of the cardiac cycle for annular short diameter (10 %); mean diameter (10 %); effective diameter and circumference-derived diameter (20 %); distance from the annulus to right coronary artery ostium (10 %); aortic root at the left coronary artery level (20 %); aortic root at the widest portion of coronary sinuses (20 %); and right leaflet length (20 %). Prosthesis size selection differed depending on the chosen measurements in 25–75 % of cases.
Conclusion
Significant changes in anatomical structures of the aortic root during the cardiac cycle are crucial for TAVI planning. Imaging in systole is mandatory to obtain maximal dimensions.
Key Points
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Most aortic root structures undergo significant dimensional changes throughout the cardiac cycle.
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The largest dimensions of aortic parameters should be determined to optimize TAVI.
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Circumference-derived diameter showed maximum dimension at 20 % of the cardiac cycle.
A novel configuration of a deuterium z pinch has been used to generate fusion neutrons. Injecting an outer hollow cylindrical plasma shell around an inner deuterium gas puff, neutron yields from DD ...reactions reached Y(n)=(2.9 ± 0.3) × 10(12) at 700 ns implosion time and 2.7 MA current. Such a neutron yield means a tenfold increase in comparison with previous deuterium gas puff experiments at the same current generator. The increase of beam-target yields was obtained by a larger amount of current assembled on the z-pinch axis, and subsequently by higher induced voltage and higher energies of deuterons. A stack of CR-39 track detectors on the z-pinch axis showed hydrogen ions up to 38 MeV. Maximum neutron energies of 15 and 22 MeV were observed by radial and axial time-of-flight detectors, respectively. The number of DD neutrons per one joule of stored plasma energy approached 5 × 10(7). This implies that deuterium gas puff z pinches belong to the most efficient plasma-based sources of DD neutrons.
A set of neutron diagnostics including scintillation time-of-flight detectors, bubble detectors, and several kinds of threshold nuclear activation samples is used to obtain information about the ...yield and spectrum of the neutrons produced by a deuterium gas-puff z-pinch. The experiments are performed at a current of about 3 MA on the GIT-12 generator at the Institute of High Current Electronics of the Siberian Branch of Russian Academy of Sciences in Tomsk. The average neutron yield in the experiments in 2016 was 2.3 × 10 12 neutrons per single shot. Using the data obtained with the help of neutron activation diagnostics, the time-of-flight detectors have been absolutely calibrated and the broad energy spectrum of the produced neutrons was evaluated. By the calculations presented in this paper, due to the multi-MeV energies of deuterons generated in the pinch, up to 15% of the total neutron yield could be produced by nuclear reactions of deuterons with a stainless steel vacuum chamber and aluminum
Z-pinch experiments with deuterium gas puffs have been carried out on the GIT-12 generator at 3 MA currents. Recently, a novel configuration of a deuterium gas-puff z-pinch was used to accelerate ...deuterons and to generate fast neutrons. In order to form a homogeneous, uniformly conducting layer at a large initial radius, an inner deuterium gas puff was surrounded by an outer hollow cylindrical plasma shell. The plasma shell consisting of hydrogen and carbon ions was formed at the diameter of 350 mm by 48 plasma guns. A linear mass of the plasma shell was about 5 µg cm−1 whereas a total linear mass of deuterium gas in single or double shell gas puffs was about 100 µg cm−1. The implosion lasted 700 ns and seemed to be stable up to a 5 mm radius. During stagnation, m = 0 instabilities became more pronounced. When a disruption of necks occurred, the plasma impedance reached 0.4 Ω and high energy (>2 MeV) bremsstrahlung radiation together with high energy deuterons were produced. Maximum neutron energies of 33 MeV were observed by axial time-of-flight detectors. The observed neutron spectra could be explained by a suprathermal distribution of deuterons with a high energy tail . Neutron yields reached 3.6 × 1012 at a 2.7 MA current. A high neutron production efficiency of 6 × 107 neutrons per one joule of plasma energy resulted from the generation of high energy deuterons and from their magnetization inside plasmas.
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