In order to improve energy density of a capacitor, an operative potential limit extension is a simple way. Based on this concept, we have studied 2-electrode symmetric electrical double layer ...capacitor (EDLC) of PICACIFF-activated carbon electrodes in 4 mol dm super(-3)of sodium nitrate using ethylene glycol (EG)-aqueous solution as an electrolyte media. Infrared spectroscopy was used to characterize the interactions of the electrolyte components. The electrochemical performance of the capacitor was experimented using cyclic voltammetry, galvanostatic charge-discharge cycling and impedance spectroscopy techniques at 0 degreesC, 25 degreesC and 60 degreesC through the aqueous and EG-aqueous electrolytes. The electrochemical performances of the aqueous cells were significantly enhanced by the EG addition. In such cases, a 1.5-2.0 V potential window and a range of 12-16 Wh kg super(-1) energy density were obtainable. This energy density value is two times higher than a usual aqueous cell. Moreover, a little percentile of aqueous to EG electrolyte changes the conductivity and its power density drastically. We conclude that this kind of electrolyte might be a suitable solution in between the aqueous and organic electrolytes. Also, it can achieve much higher energy density than the aqueous just a partial substitution of an organic medium.
Assist gas plays a central role in laser fusion cutting. In this work, the aerodynamic interactions between the assist gas and the workpiece are reviewed. An insight into those phenomena that hinder ...the cutting quality and performance is provided. These phenomena include shock waves, choking, boundary layer separation, etc. The most relevant and promising attempts to overcome these common problems related to the gas dynamics are surveyed. The review of the current scientific literature has revealed some gaps in the current knowledge of the role of the assist gas dynamics in laser cutting. The assist gas interactions have been investigated only under static conditions; and the dynamic interaction with the molten material on the cutting front has not been addressed. New nozzle designs with improved efficiency of molten material removal are required to improve cut quality; and cutting speed in current industrial laser cutting machines; especially in those assisted by new high-brightness laser sources.
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•Few studies have examined the effects of Ca nano-fertilizers on pomegranate fruit yield and quality.•Fruit yield and quality of pomegranate trees have been assessed after two sprays ...with different Ca formulations, including a nano-fertilizer and CaCl2.•Ca foliar fertilization had no effects on pomegranate yield and only small effects on fruit quality.•A positive effect of Ca fertilizers in decrease pomegranate fruit cracking was found.•Low doses of a Ca nano-fertilizer were better than high doses of CaCl2 in reducing pomegranate fruit cracking.
An experiment was conducted to assess the effects of foliar sprays of a calcium fertilizer containing nanoparticles (nano-Ca) and calcium chloride (CaCl2.2H2O) on the yield and quality of pomegranate fruits cv. Ardestani, during two consecutive years, 2014 and 2015. The nano-Ca fertilizer was sprayed at concentrations of 0.25 and 0.50g Ca L−1, and CaCl2.2H2O was used at concentrations of 1 and 2% (2.73 and 5.45g Ca L−1), with treatments being applied twice, first at full blooming and then one month later. Calcium foliar fertilization did not have significant effects on yield, number of fruits per tree and average fruit weight, whereas it increased fruit length only in the case of the CaCl2 1% treatment in the first season. The untreated trees in the orchard were moderately affected by fruit cracking, with 6–7% of the fruits being affected. Calcium foliar treatment with the nano-Ca fertilizer at 0.50g Ca L−1 and 1% CaCl2 (in the both seasons) and also 2% CaCl2 (only in the second season) decreased significantly fruit cracking when compared with the control treatment, resulting in increases in marketable fruit yield. Foliar sprays with CaCl2 1% increased TSS by 7.6% only in the second season. Moreover, foliar nano-Ca fertilization at 0.50g Ca L−1 led to minor decreases (approximately 1%) in total phenolics only in the first season. Other chemical properties, including titratable acidity, fruit maturity, total sugar, antioxidant activity and total anthocyanin contents were not affected by Ca foliar fertilization. Leaf analyses show that Ca foliar treatments increased leaf Ca concentrations in the first season, with the exception of the low dose of nano-fertilizer, whereas the leaf concentrations of N, P, K, Fe, Zn and Mn were unaffected. In summary, fertilization with a low (0.50g Ca L−1) Ca concentration in the form of a nano-Ca formulation resulted in similar decreases in pomegranate fruit cracking than those obtained with higher doses of CaCl2 (2.73 and 5.45g Ca L−1).
Peaches and nectarines have a short shelf life even when harvested at appropriate physiological maturity. Market life is increased by storage at low temperatures. However, chilling injury symptoms ...can appear, causing physiological disorders and limiting shipping potential. The rootstock effect on the post-harvest quality has hardly been explored. Thus, the principal aim of this work was to study the influence of seven different
rootstocks on the "Big Top" nectarine cv, considering harvest and post-harvest quality parameters and their correlation with chilling injury disorders. Basic fruit quality traits, individual sugars and organic acids analyzed by HPLC and other biochemical compounds such as relative antioxidant capacity, total phenolics content, flavonoids, anthocyanins, vitamin C and related enzyme activities (PAL, POD, PPO) were considered. In addition, correlations with possible candidate genes for chilling injury (CI) tolerance were searched by qPCR. Although a low susceptibility to CI symptoms has been found in "Big Top", rootstocks "PADAC 9902-01", "PADAC 99-05" and "ReplantPAC" exhibited lower CI symptoms. A statistically significant influence of the evaluated rootstocks was found concerning the parameters of this study. Phenols and anthocyanins seem to be important parameters to be considered in the prevention of chilling injury disorders. Moreover,
,
,
and
genes relative expressions were positively associated with chilling injury susceptibility. This study opens new perspectives for understanding peach fruit adaptation and response to cold storage temperatures during the post-harvest period.
In article number 2100924, Antonio Riveiro, Juan Pou, and co‐workers introduce a novel concept of controlling and guiding the corrosion process of a material through a laser treatment. After the ...treatment, the degradation is no longer random and unpredictable, but progresses towards the designed regions and directions. Applications like batteries, biodegradable implants or cathodic protection systems may benefit from such a controlled and tailored corrosion.
The objective of this study was to compare four manufacturing processes of Co-Cr dental alloys: casting (CAST), computer aided design/computer aided manufacturing (CAD/CAM) milling (MILL), selective ...laser melting (SLM), and laser directed energy deposition (LDED). Comparison included microstructural, mechanical, and electrochemical analyses. Half of the samples obtained were heat treated to simulate the porcelain fused to metal (PFM) firing process, and the metal real state in an oral environment. Co-Cr dental alloys manufactured via casting, LDED, milling, and SLM techniques presented evident differences in their mechanical properties. However, their electrochemical performances were similar, with high resistance to corrosion in artificial saliva, in both aerated and deaerated media (corrosion rate under 4 microns per year). LDED and milling materials showed the highest modulus of toughness, and gave improved results in comparison with CAST and SLM techniques (p < 0.05). The LDED process could be implemented in the manufacturing of the restorative dental industry, with a high overall performance, competing directly with the best quality techniques, and reducing their disadvantages.
Laser-directed energy deposition (LDED) is an additive manufacturing (AM) technology which can be an alternative to the traditional subtractive milling process for the obtention of ...porcelain-fused-to-metal (PFM) prosthesis. Still, the adhesion performance of the veneering ceramics for this material has been not studied yet. The main objective of this study is to perform a systematic comparison of the adhesion performance of Co-Cr-W metal frameworks obtained through LDED and conventional milling techniques. Comparison includes microstructural, superficial, and adhesion analysis. Co-Cr manufactured via LDED technique presents similar behavior (p < 0.05) in comparison to the material obtained via milling techniques, and its performance was validated with the veneering ceramics and veneering composites currently employed in the dental industry.
•‘Translocated’ incompatibility was only found on the Japanese plum cv. ‘Golden Japan’ budded on AP-45.•Plum cvs. exhibited good graft compatibility with all hexaploid plum rootstocks.•‘Reine Claude ...Verte’ showed ‘localized’ incompatibility budded on Myrobalan B and Myrobalan GF 3-1.•‘Stanley’ cv. showed ‘localized’ incompatibility with the six evaluated peach × almond hybrid rootstocks.•Peach-almond and P. cerasifera based rootstocks showed prune brownline disease symptoms with ‘Golden Japan’.
The introduction of some new rootstocks requires knowledge of the potential ‘translocated’ and ‘localized’ graft incompatibilities before releasing these rootstocks into the market. Trials were established at the Aula Dei Experimental Station (Zaragoza, Spain) to assess graft compatibility between five European plum (Prunus domestica L.) and six Japanese plum (Prunus salicina L.) cultivars with thirty-eight rootstocks belonging to peach × almond hybrids, as well as slow-growing, fast-growing and interspecific hybrid plum groups. Some of these rootstocks are under process of selection and others are commercial rootstocks already introduced into the European market. External visual diagnosis of the scion-rootstock graft combinations was performed by observing symptoms of the ‘translocated’ incompatibility in the nursery. Visual symptoms of ‘translocated’ incompatibility were only found on the Japanese plum cv. ‘Golden Japan’ budded on the plum-apricot hybrid AP-45. The ‘localized’ graft incompatibility was assessed after internal macroscopically examination of graft unions. In the case of the European plum cvs., ‘President’ and ‘Reine Claude Tardive of Chambourcy’ exhibited good graft compatibility with all the tested rootstocks, with the exception of ‘President’ budded on the pentaploid plum hybrid rootstock Damas GF 1869. ‘Reine Claude Verte’ cv. showed ‘localized’ incompatibility with Myrobalan B and Myrobalan GF 3-1 since the second year after budding. ‘Stanley’ cv. showed ‘localized’ incompatibility with the six evaluated peach × almond hybrid rootstocks, although it was compatible with all plum based rootstocks. In the case of Japanese plums, four cultivars (‘Angeleno’, ‘Black Amber’,’ Delbarazur’ and ‘Songold’) did not show any graft incompatibility, but ‘Friar’ showed ‘localized’ incompatibility on Myrobalan B. In the case of peach-almond and P. cerasifera based rootstocks (Adarcias, GF 677, Damas GF 1869, Myrobalan B, Myrobalan 29 C, Myrobalan GF 3-1 and Marianna GF 8-1), ‘Golden Japan’ trees showed similar symptoms to those caused by TomRV in Myrobalan and peach rootstocks and ‘localized’ incompatibility. Finally, this study confirmed the interest of P. insititia specie as well as several interspecific Prunus hybrids as a good source of rootstocks for the plum industry.
Silver nanostructured thin films have been fabricated on silicon substrate by combining simultaneously pulsed laser ablation in liquid (PLAL) and electrophoretic deposition (ED) techniques. The ...composition, topography, crystalline structure, surface topography, and optical properties of the obtained films have been studied by energy dispersive X-ray spectroscopy (EDS), high-resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), and UV-visible spectrophotometry. The coatings were composed of Ag nanoparticles ranging from a few to hundred nm. The films exhibited homogenous morphology, uniform appearance, and a clear localized surface plasmon resonance (LSPR) around 400 nm.
Sheep farming makes an important socio-economic contribution to Spain’s rural areas by sustaining farming and employment in less favored regions, but it is a low-profit sector because of high ...operating and regulatory costs. One possible solution would be to raise for slaughter lambs from dairy sheep that are not required as replacements. However, the early weaning of these lambs and their artificial rearing generally lead to reduced growth rates and high mortalities. In the work presented herein, three housing systems (slat + heating plate, slat + infrared lamp, and deep-litter + infrared lamp) were tested on 763 lambs over an eight-month period in a farm located in Ejea de los Caballeros (Zaragoza, Spain), with a view to reducing mortality during the period of artificial lactation. The effect of the environmental parameters of the lamb housing on the development of the lambs was evaluated by monitoring environmental (temperature, relative humidity, CO2 and NH3) and productive parameters (weight, average daily gain, and deaths). The results suggested that the combination of deep litter with straw bedding and infrared lamp heating would be the most favorable option, as it led to the highest average daily gain and the lowest percentage of deaths. From the study of the relationship of the initial weight with deaths, a prediction curve was obtained, defining the maximum prices to be paid per lamb as a function of their initial weight to guarantee the profitability of the raising process. This may be regarded as a valuable guidance for Spanish sheep farmers, as it can reduce their economic uncertainty.
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