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Recently, Fe-based metal–organic frameworks (MOFs) have attracted increasing attention and been widely used. To date, however, it is unknown whether they can be employed to degrade ...tetracycline, one of the most widely used antibiotics. This work therefore aims to provide such support by comparing the performance of three Fe-based MOFs (namely, Fe-MIL-101, Fe-MIL-100, and Fe-MIL-53) in removing tetracycline. Experimental results showed that Fe-MIL-101 exhibited the best performance in tetracycline removal, with 96.6% of tetracycline being removed (initial tetracycline concentration at 50 mg/L) while Fe-MIL-100 and Fe-MIL-53 removed 57.4% and 40.6% under the same conditions. Additionally, the effects of adding dosage, adsorption time, and initial concentration of tetracycline on degradation efficiency were examined. It was found that the adsorption and photocatalytic degradation effect was better with the increase of time, the optimum dosage of Fe-MIL-101 was 0.5 g/L and the removal efficiency decreased with the increasing of initial tetracycline concentrations. Moreover, the trapping experiments and ESR tests indicated that O2−, OH and h+ were the main active species in photocatalytic degradation process of tetracycline. Due to its high removal efficiency and simple synthesis, it could be used as a potential catalyst for degradation of tetracycline and other antibiotics.
Free ammonia (FA) can pose inhibitory and/or biocidal effects on a variety of microorganisms involved in different biological wastewater treatment process, which is widely presented in wastewater ...treatment plants (WWTPs) due to the high levels of ammonium in the systems. This review article gives the up-to-date status on several essential roles of FA in biological wastewater treatment processes: the impacts of FA, mechanisms of FA roles, modeling of FA impacts, and implications of FA for wastewater treatment. Specifically, the impacts of FA on both wastewater and sludge treatment lines were firstly summarized, including nitrification, denitrification, anaerobic ammonium oxidation (Anammox), enhanced biological phosphorus removal and anaerobic processes. The involved mechanisms were then analyzed, which indicated FA inhibition can slow specific microbial activities or even reconfigure the microbial community structure, likely due to negative impacts of FA on intracellular pH, specific enzymes and extracellular polymeric substances (EPS), thus causing cell inactivation/lysis. Mathematical models describing the impact of FA on both wastewater and sludge treatment processes were also explored to facilitate process optimization. Finally, the key implications of FA were identified, that is FA can be leveraged to substantially enhance the biodegradability of secondary sludge, which would further improve biological nutrient removal and enhance renewable energy production.
•The impacts of FA on both wastewater and sludge treatment lines were reviewed.•The mechanisms of FA on commonly found microbial communities in WWTPs were analyzed.•Models for predicting FA on biological wastewater treatment were explored.•Key implications of FA in biological wastewater treatment were identified.
•Capsaicin was completely degraded in anaerobic co-digestion of FW and WAS•Methane can be produced during the degradation of capsaicin•Capsaicin inhibited methane production from anaerobic ...co-digestion of FW and WAS•The presence of capsaicin restrained acetotrophic methanogenesis•Capsaicin promoted the population of complex organic degradation microbes
Anaerobic co-digestion is an attractive option to treat food waste and waste activated sludge, which is increasingly applied in real-world situations. As an active component in Capsicum species being substantially present in food waste in many areas, capsaicin has been recently demonstrated to inhibit the anaerobic co-digestion. However, the interaction between capsaicin and anaerobic co-digestion are still poorly understood. This work therefore aims to deeply understand the fate and impact of capsaicin in the anaerobic co-digestion. Experiment results showed that capsaicin was completely degraded in anaerobic co-digestion by hydroxylation, O-demethylation, dehydrogenation and doubly oxidization, respectively. Although methane was proven to be produced from capsaicin degradation, the increase in capsaicin concentration resulted in decrease in methane yield from the anaerobic co-digestion. With an increase of capsaicin from 2 ± 0.7 to 68 ± 4 mg/g volatile solids (VS), the maximal methane yield decreased from 274.6 ± 9.7 to 188.9 ± 8.4 mL/g VS. The mechanic investigations demonstrated that the presence of capsaicin induced apoptosis, probably by either altering key kinases or decreasing the intracellular NAD+/NADH ratio, which led to significant inhibitions to hydrolysis, acidogenesis, and methanogenesis, especially acetotrophic methanogenesis. Illumina Miseq sequencing analysis exhibited that capsaicin promoted the populations of complex organic degradation microbes such as Escherichia-Shigella and Fonticella but decreased the numbers of anaerobes relevant to hydrolysis, acidogenesis, and methanogenesis such as Bacteroide and Methanobacterium.
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•The maximum P adsorption capacity of FeCl3-modified biochar was 111.0mg/g.•The P removal efficiency of Fe3+-attached biochar was better than Fe3O4.•Fe3+-modified biochar showed good ...P removal ability in wider concentration range.•P removal rate by Fe3+-modified biochar kept over 60% after 5 times reuse.
Excessive discharge of phosphate (P) into the surface water is the key factor to cause the eutrophication, so its removal has aroused much attention in recent years. In this study, different iron modification (chemical co-precipitation of Fe3+/Fe2+ or FeCl3 impregnation) was used to improve the phosphate adsorption capacity of waste activated sludge (WAS)-based biochar. Comparative tests demonstrated that the FeCl3-impregnated WAS-based biochar exhibited much superior phosphate adsorption capacity (111.0mg/g) in all as-prepared samples and performed well even under the interferences with pH and coexisting ions. X-ray diffraction (XRD) analyzes indicated that the iron in FeCl3-impregnated WAS-based biochar existed mainly in amorphous phase, as hematite and amorphous hydroxides forms, which was of great benefit to the phosphate adsorption. Besides, ligand exchange plays important role in the adsorption of phosphate. The WAS-based biochar kept over 60% phosphate removal efficiency after five recycles.
On account of high oxidation ability of sulfate radical-based advanced oxidation processes (AOPs), the eco-friendly catalysts for peroxymonosulfate (PMS) activation have received considerable ...attentions. Previous studies mainly focused on Cobalt-based catalyst due to its high activation efficiency, such as Co3O4/MnO2 and FeCo-layered double hydroxide (LDH), whereas Cobalt-based catalyst usually has serious risk to environment. To avoid this risk, MnFe-LDH was primarily synthesized in this research by simple co-precipitation and subsequently utilized as an effective catalyst for peroxymonosulfate (PMS) activation to degrade organic pollutants. The experimental results demonstrated that MnFe-LDH with a lower dosage (0.20 g/L) could efficiently activate PMS to achieve 97.56% removal of target organic pollutants Acid Orange 7 (AO7). The AO7 degradation process followed the pseudo-first-order kinetic well with an activation energy of 21.32 kJ/mol. The intrinsic influencing mechanism was also investigated. The quenching experiment and electron spin resonance (ESR) indicated that sulfate and hydroxyl radicals were produced by the effective activation of PMS by MnFe-LDH, resulting in a high rate of decolorization. The possible AO7 removal pathway in the constructed MnFe-LDH/PMS system was presented on the basis of UV–vis spectrum analysis and GC–MS, which suggested that the AO7 degradation was firstly initiated by breaking azo linkages, then generated phenyl and naphthalene intermediates and finally presented as ring-opening products. This effective MnFe-LDH/PMS system showed great application potential in the purification of wastewater contaminated by refractory organic pollutants.
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•MnFe-LDH was used as heterogeneous catalyst to active peroxymonosulfate.•The MnFe-LDH/PMS system showed high performance for organic pollutant degradation.•Rreaction parameters of MnFe-LDH/PMS system for AO7 degradation were optimized.•Catalyst showed stable catalytic performance in consecutive runs.•The probable degradation pathways were proposed and discussed.
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Phosphate (P) removal is significant for the prevention of eutrophication in natural waters. In this paper, a novel adsorbent for the removal of P from aqueous solution was ...synthesized by loading zirconium oxide and iron oxide onto activated carbon nanofiber (ACF-ZrFe) simultaneously. The adsorbent was characterized by scanning electron microscopy (SEM), Fourier transform infrared (FT-IR) spectroscopy and X-ray photoelectron spectroscopy (XPS). The results showed that P adsorption was highly pH dependent and the optimum pH was found to be 4.0. The isotherm of adsorption could be well described by the Langmuir model and the maximum P adsorption capacity was estimated to be 26.3mgP/g at 25°C. The kinetic data were well fitted to the pseudo-second-order equation, indicating that chemical sorption was the rate-limiting step. Moreover, co-existing ions including sulfate (SO42−), chloride (Cl−), nitrate (NO3−) and fluoride (F−) exhibited a distinct effect on P adsorption with the order of F−>NO3−>Cl−>SO42−. Further investigations by FT-IR spectroscopy and pH variations associated with the adsorption process revealed that ligands exchange and electrostatic interactions were the dominant mechanisms for P adsorption. The findings reported in this work highlight the potential of using ACF-ZrFe as an effective adsorbent for the removal of P in natural waters.
Triclocarban (TCC), one typical antibacterial agent being widely used in various applications, was found to be present in waste activated sludge at significant levels. To date, however, its effect on ...anaerobic fermentation of sludge has not been investigated. This work therefore aims to fill this knowledge gap. Experimental results showed that when TCC content in sludge increased from 26.7 ± 5.3 to 520.5 ± 12.6 mg per kilogram total suspended solids, the maximum concentration of short-chain fatty acids (SCFA) increased from 32.6 ± 2.5 to 228.2 ± 3.6 (without pH control) and from 211.7 ± 2.4 to 378.3 ± 3.2 mg COD/g VSS (initial pH 10), respectively. The large promotion of acetic acid was found to be the major reason for the enhancement of total SCFA production. Although a significant level of TCC was degraded in the fermentation process, SCFA was neither produced from TCC nor affected by its major intermediates at the relevant levels. It was found that TCC facilitated solubilization, acidogenesis, acetogenesis, and homoacetogenesis processes but inhibited methanogenesis process. Microbial analysis revealed that the increase of TCC increased the microbial community diversity, the abundances of SCFA (especially acetic acid) producers, and the activities of key enzymes relevant to acetic acid production.
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•Triclocarban affected SCFA production from anaerobic fermentation of sludge.•A significant level of triclocarban was degraded in the fermentation process.•Triclocarban facilitated solubilization, acidogenesis, acetogenesis, and homoacetogenesis processes.•Triclocarban inhibited methanogenesis process.
Denitrifying anaerobic methane oxidation (DAMO) can concurrently reduce methane emissions and nitrogen levels in aquatic environments, but how useful is this process? We propose the use of DAMO-based ...technology as a tool for sustainably operating wastewater treatment plants (WWTPs).
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•The photochemical technologies for removing PFOX from water were summarized.•Characteristics of PFOX photo-oxidation and photo-reduction processes were explored.•Factors affecting ...the PFOX degradation and defluorination procedure were discussed.•The PFOX photochemical degradation mechanisms were elucidated in details.•The application prospects for PFOX photodegradation were suggested.
Perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) are persistent organic pollutants in the environment and have serious health risks, including endocrine disrupting properties, immunotoxicity and developmental effects etc. The photochemical degradation has been proven to be a low-cost, efficient and sustainable technology for the removal of PFOX (X=A or S) in water. At present, most of the investigations have been conducted in ultrapure water and at concentrations much higher comparing to those detected in the real wastewaters. Furthermore, there are few studies about the toxicity of treated water. In this paper, the state of knowledge on the photocatalytic degradation of PFOX, including photo-oxidative and photo-reductive degradation, is reviewed comprehensively. Compared with photo-oxidation, photo-reduction appears to be more suitable for the PFOX removal since it is more favorable for the defluorination of PFOX and further complete mineralization. The effects of key parameters on the photocatalytic degradation and defluorination process of PFOX are commendably accessed, such as light wavelength, photocatalyst concentration, initial PFOX concentration, pH, reaction atmosphere, temperature, and coexisting organic or inorganic matters. The mechanisms of PFOX photodegradation process are also elucidated in detail. This paper will help to deeply understand PFOX decomposition process and put forward better perspectives in the future for researchers who work in this field.
•Details of how NaCl affects methane production from food waste were clarified.•An efficient approach to mitigate the impact of NaCl on the production of methane was reported.•The mechanisms for ...co-digestion of food waste and WAS exhibiting higher methane production were investigated.
Previous studies have demonstrated that the presence of sodium chloride (NaCl) inhibited the production of methane from food waste anaerobic digestion. However, the details of how NaCl affects methane production from food waste remain unknown by now and the efficient approach to mitigate the impact of NaCl on methane production was seldom reported. In this paper, the details of how NaCl affects methane production was first investigated via a series of batch experiments. Experimental results showed the effect of NaCl on methane production was dosage dependent. Low level of NaCl improved the hydrolysis and acidification but inhibited the process of methanogenesis whereas high level of NaCl inhibit both steps of acidification and methanogenesis. Then an efficient approach, i.e. co-digestion of food waste and waste activated sludge, to mitigate the impact of NaCl on methane production was reported. Finally, the mechanisms of how co-digestion mitigates the effect on methane production caused by NaCl in co-digestion system were revealed. These findings obtained in this work might be of great importance for the operation of methane recovery from food waste in the presence of NaCl.