Herein, we studied the use of two different Self Assembled Monolayers (SAMs) made of semiconductor hole transport organic molecules to replace the most common p-type contact, PEDOT:PSS, in PiN methyl ...ammonium lead iodide perovskite solar cells (PSCs). The SAM molecule (
MC-43
) leads to a solar to energy conversion efficiency of 17.3, which is among the highest efficiencies reported to date for PiN perovskite solar cells. The present finding highlights the potential of semiconductor based SAMs to fabricate stable and high performing planar PSCs.
We present a compilation and comparison of geochemical data of Aegean Eocene to Recent magmatic rocks: (1) North Anatolian Eocene magmatic rocks (NAEM), (2) Aegean to west Anatolian Oligocene–Miocene ...magmatic rocks (AOMM), (3) Pliocene–Quaternary South Aegean volcanic arc (SAVA), (4) Pliocene–Quaternary Denizli–Isparta volcanics (DIV), and (5) Na-alkaline basalts with intra-plate geochemical affinity (IPV). These rocks are also compared with Miocene Galatean volcanics (GVP) from central Anatolia.
The NAEM, SAVA and GVP show similar geochemical features indicative of a subduction-related origin in which subducted oceanic plate contaminated the overlying mantle wedge. The distinct geochemical features of the AOMM reflect derivation from an intensely metasomatised mantle source, resulting from partial subduction and accretion of both continental and oceanic assemblages in the fore-arc of a southward migrating subduction system. These features provide an insight into the history of the distinct types of mantle metasomatism in the region and into its geodynamic evolution — an evolution that include complex interaction of subduction roll-back, slab break-off, strike-slip faulting along major transfer zones, block rotations and core complex formation.
Thus, the Eocene to recent magmatism in the region was controlled by various tectonic events: (1) the NAEM was most probably related to break-off of the subducted slab in western Anatolia, (2) magmatic activity in the western AOMM was controlled by rotational extension around poles in northern Greece developed in response to rotational roll-back of the Hellenic subduction system, (3) while AOMM magmatism in the east is closely associated with core complex formation and asthenosphere-related thermal input along a ~N–S-trending slab tear. In contrast, the rocks of the DIV and IPV carry asthenospheric mantle geochemical signatures indicative of roll-back induced asthenospheric upwelling in Rhodope to NW Anatolia, and slab tear-induced asthenospheric upwelling beneath the Menderes Core Complex.
•Geochemistry of Aegean Eocene to recent magmatic rocks are compared•Magmatic rocks include orogenic to anorogenic series•Differences of the rock groups can be explained by the geodynamic evolution•Oceanic and/or continental subduction events occurred in the source region•Magmatic activity was controlled by complex geodynamic events
Objective: The aim of this study was to detect the prevalence of soft tissue calcifications in the head and neck using cone beam computed tomography (CBCT) and to determine their clinical importance. ...Subjects and Methods: Soft tissue calcifications in the head and neck region were retrospectively evaluated in 1557 CBCT images obtained between 2013 and 2015. The findings were categorized as follows: tonsillolith (calcified tonsil), carotid artery calcification (CAC), sialolith (salivary stone), calcified triticeous cartilage (CTC), calcified lymph node (CLN), rhinolith, antrolith, calcification of the superior cornu of the thyroid cartilage (CSCTC), calcified stylohyoid ligaments (CSL), myositis ossifican, osteoma cutis, and intracranial calcification. A Chi-square test was performed for categorical variables. In the 1557 CBCT images, 520 (33.4%) contained had at least one soft tissue calcification in the head and neck region. Results: Tonsilloliths (18.8%) were the most prevalent soft tissue calcification, followed by CTC (5.8%), CAC (4.3%), intracranial calcifications (3.9%), CSL (3.7%), CSCTC (2.1%), osteoma cutis (1%), sialoliths (0.7%), antroliths (0.5%), myositis ossificans (0.4%), rhinoliths, and CLN (0.2%). Conclusion: There was a high prevalence of soft tissue calcifications in the head and neck region on CBCT images. Tonsilloliths were the most common type of calcification. CBCT imaging may aid the diagnosis and assessment of these calcifications.
This study discusses the geochemical features of the Early-Middle Miocene and Pliocene basaltic (SiO2 = ~46–52; MgO = ~6–10 wt%) to andesitic (SiO2 = ~59; MgO = ~4 wt%) rocks exposed in the Gürün and ...Kangal basins (Sivas, eastern part of central Anatolia), respectively. The basaltic rocks are characterized by alkaline to tholeiitic affinities, while the more evolved andesitic samples show calc-alkaline affinity. Trace element variations reveal that they can be evaluated in three sub-groups, each represented by different contents of trace elements for given Nb contents. Primary magmas of each groups were likely produced by different degrees of partial melting (~1–2, 2–3, 7–10% respectively) from a common mantle source, subsequently underwent different degrees of fractionation and crustal contamination. Derivation from a common mantle source of the primitive magmas of each group is supported by similar Sr, Nd and Pb isotopic ratios. Increasing degrees of partial melting seem to be responsible for the alkaline to tholeiitic variation among the basaltic samples, while higher degrees of crustal contamination (AFC) resulted in calc-alkaline affinity of the more evolved samples.
Most primitive Pliocene samples show intra-plate (anorogenic) geochemical features, while the more evolved Miocene calc-alkaline samples resemble geochemically subduction-related (orogenic) magmatic rocks. However, on the basis of detailed geochemical models, we propose that the calc-alkaline affinity among the Miocene samples can also be gained by crustal contamination of their primary magmas which were also anorogenic in character. If this is true, overall, the Miocene and Pliocene basaltic to andesitic rocks in the Gürün and Kangal basins appear to may have formed by variable degrees of partial melting of a common anorogenic mantle that had not been subject to subduction-related metasomatism. This is an alternative approach to the general view assuming the Early-Middle Miocene magmatic activity in the region was derived from subduction-modified mantle sources in response to subduction of the Arabian Plate under the Anatolian Plate. This hypothesis further implies that either delamination of the sub-continental lithosphere or slab break-off processes beneath the central to eastern Anatolia might took place well before the Miocene, thus allowing upwelling unaltered mantle to provide the source of the Miocene to Pliocene volcanic rocks.
•Miocene and Pliocene basalts occur in the Gürün and Kangal basins, respectively.•The rocks vary from alkaline to tholeiitic and calc-alkaline in character.•Alkaline to tholeiitic variation is related to different degrees of melting.•Calc-alkaline affinity is related to crustal contamination processes.•All rock groups have a common mantle source without a subduction-signature.
Zircon ages, mineral chemistry, whole-rock major and trace element compositions, as well as Sr–Nd isotopic ratios of basaltic (basanite, basalt, and hawaiite with MgO=3.90–10.06 and SiO2=43.18–48.16) ...to andesitic (SiO2=50.86–61.27) and rhyolitic (SiO2=71.11–71.13) volcanic rocks (E-W emplaced Nallıhan volcanics) in the Lower Eocene terrestrial sedimentary units in the Central Sakarya Zone were studied and compared with those of the northerly located E-W-trending Eocene volcanic rocks (the Kızderbent Volcanics with 52.7–38.1Ma radiometric ages) that are thought to be related to slab break-off process following the continental collision in the NW Anatolia. Zircon U–Pb ages of the Nallıhan volcanics vary from 51.7±4.7 to 47.8±2.4Ma.
Clinopyroxene from the basaltic and andesitic rocks record crystallization conditions from ~7–8kbars (~23km) and ~1210°C, to 4.5–1.5 kbars (~14–1.5km) and 1110–1010°C crystallization conditions, respectively. The olivine-bearing, high-MgO (up to 10wt%) basaltic rocks of the Nallıhan volcanics have nepheline-normative and Na-alkaline compositions, while the andesitic to rhyolitic rocks show calc-alkaline affinity with mainly sodic character. This is the first time this type of volcanic rock has been described in this region. The initial Sr isotopic ratios of both basaltic and andesitic–rhyolitic samples from the Nallıhan volcanics are similar (~0.7040–0.7045), indicating that fractional crystallization processes were not accompanied by crustal contamination and that the magma chambers were likely stored within ophiolitic units. Trace element ratios suggest that the Nallıhan volcanics were derived from E-MORB- or OIB-like enriched mantle sources, while the Kızderbent volcanics had N-MORB-like depleted mantle sources. Both volcanic units were produced by partial melting of spinel-bearing (shallow) mantle sources that had undergone subduction-related enrichment processes, with the degree of enrichment having been greater for the Kızderbent volcanics.
The geochemical features of both the Nallıhan and Kızderbent volcanics are best explained as the result of slab break-off, in which the Nallıhan volcanics (located closer to the original subduction front) were produced mainly by the melting of upwelling asthenospheric mantle. Further back from the subduction front, the upwelling interacted with more highly metasomatized sub-arc mantle that underwent partial melting to produce the Kızderbent volcanics. This geodynamic scenario can be used for understanding other post-collisional slab break-off-related magmatic activities.
•The U–Pb zircon ages and geochemistry of the Nallıhan volcanics were studied.•Geochemical features indicate derivation from an enriched mantle source.•The results are compared with those of the Eocene volcanic rocks in the environs.•It is concluded that slab break-off volcanism began with Na-alkaline basalts.
•Calcium-alginate capsules for self-healing of asphalt mixtures were manufactured.•Physical, thermal and mechanical properties of the capsules were evaluated.•Mixing and ageing effect on the ...mechanical and healing properties of mixtures were studied.•Capsules addition did not improve the mechanical properties of mixtures.•Self-healing levels obtained by the mixtures varied depending on the capsules addition order.
In this paper, polymeric capsules with sunflower oil as the encapsulated rejuvenator were manufactured and added to asphalt mixtures to improve their self-healing properties. A capsule content of 0.5% by total mass of mixture was added to the asphalt samples. Physical, thermal and mechanical properties of the capsules were evaluated. Additionally, the effect of the mixing order and the ageing time on the mechanical stability and self-healing properties of asphalt mixtures with, and without, capsules were evaluated through stiffness modulus and flexural strength tests. Self-healing properties of asphalt mixtures were evaluated through three-point bending tests on cracked asphalt beams with, and without, capsules. In addition, capsules’ distribution and their integrity inside the asphalt mixtures were analysed using X-ray computed tomography. The main results proved that the capsules can resist the mixing and compaction conditions and break inside the mixture releasing the encapsulated oil in small volumes. In addition, it was observed that the addition of capsules did not improve the stiffness modulus of asphalt mixtures compared to mixtures without capsules, and that the mixing order and the ageing time did not have a significant influence on the flexural strength of the mixtures. Moreover, the healing levels obtained by the mixtures varied depending on the order of addition of capsules, and mixtures with capsules showed higher healing levels than mixtures without capsules. Finally, the levels of healing for the mixtures without ageing were greater than those of mixtures after the ageing process.
Background: Odontogenic cysts develop from the epithelium of dental structures and generally grow slowly. In children and adolescents, cysts usually grow faster than adults and require much knowledge ...for diagnoses and treatments. Aims: This study aimed to determine the diagnosis and treatment of odontogenic cysts in different age groups by evaluating the type of lesions, age, gender, and anatomical distribution of odontogenic cysts seen in children and adolescents by cone-beam computed tomography. Materials and Methods: A total of 42 odontogenic cysts (radicular, dentigerous cyst, and odontogenic keratocyst) were determined in children and adolescents aged 7-18 years. Cone-beam computed tomography images of odontogenic cysts were analyzed in terms of types, age, sex, anatomical location, height, width, depth, scalloped borders, lesion shapes, tooth displacement, root resorption, and association with an unerupted tooth. Results: There was a significant correlation between odontogenic cyst types and age groups, scalloped borders, lesion shape, tooth displacement, root resorption, and association with an unerupted tooth. Conclusion: When odontogenic cysts seen in children and adolescents are examined with cone-beam computed tomography, the radicular cyst was the most common form and was predominated in the 13-18 years age group and in boys. Differences in terms of scalloped borders, lesion shape, tooth displacement, root resorption, and association with unerupted teeth were noticed. The knowledge of the distribution and properties of odontogenic cysts in pediatric patients will help diagnose the lesions during clinical and radiological examinations and make appropriate treatment planning.
Bardet-Biedl syndrome (BBS) is a rare autosomal recessive genetic disorder. This syndrome is associated with 19 genes present, and 80% of the cases are determined as a clinical diagnosis result. A ...15-year-old female presented with a complaint of gingival bleeding during brushing. As a result of received detailed history and the intraoral-extraoral examinations; retinal dystrophy, obesity, polydactyly, and renal defects of Caucasian female consistent with BBS were reported. Oral and dental findings were high-arched palate, crowding, and missing tooth. As dentists, we should know the diagnostic criteria of this syndrome. In addition, we should have a high index of suspicion so as to enhance the timely recognition of this condition. Dentists should also be familiar with the management protocol that includes a multidisciplinary approach to alleviate the existing conditions.
The temporal crest canal (TCC) is a rare variant of the mandibular canal, and it is important to locate the presence and site of mandibular canals and their variants before operation. We have ...examined the anatomical features and prevalence of TCC with cone-beam computed tomography (CT) in south-east Anatolia. The cone-beam CT images of 1023 patients (2026 sides) referred to the Department of Dentomaxillofacial Radiology between 2015 and 2017 years were evaluated retrospectively. Sagittal, cross-sectional, and reformatted panoramic images were analysed to see if a TCC was present. The canals were grouped as Type 1 and Type 2 according to their configuration. Seven (0.7%) were found in 1023 patients. Two of them (0.2%) were in female, and five (0.5%) in male, patients. Four (0.4%) were increasingly narrow and noticeably curved (Type 1), and three (0.3%) were uniformly wide and slightly curved (Type 2). All TCC were unilateral: two on the right and five on the left. We conclude that knowledge of the presence of a TCC and its anatomical variants in the mandibular ramus is important to ensure a proper local anaesthetic nerve block for surgical operations. Cone-beam CT is an important diagnostic tool in dentistry, and clearly recognises a TCC.
The aim of this study was to investigate the incidence of juxta-apical radiolucency (JAR) and its relations with surrounding structures using cone-beam computed tomography (CT). A total of 215 ...cone-beam CT images was analysed retrospectively to record the presence, site, and size of the JAR, and the relations between the JAR and the mandibular canal, buccal or lingual cortical plates, tooth position, and condition of root apex. Descriptive analyses were made, and relations between the categorical variables were tested with the chi squared test. JAR was detected in 71 (33%) (5 bilateral and 66 unilateral) of 215 patients (378 mandibular third molars) on cone-beam CT images. It was most commonly seen mesial to the tooth (43%) and above the third molars (55%), and was least common lingual to the tooth (3%) and at the distoangular third molar (3%) (p = 0.005). There was no significant relation between the JAR and the mandibular canal, but JAR was most likely to be detected superiorly to the mandibular canal (59% of cases). JAR can be seen and evaluated with cone-beam CT. It was most commonly seen mesial to the tooth and above the third molar. No significant relation was found between JAR and the mandibular canal, cortical plate, or condition of the apex. Future studies on the assessment of JAR should be done with a larger sample size as prospective cone-beam CT studies.
