Asia has been a major testing ground for various competing models of continental deformation due to its relatively well-understood plate boundary conditions in the Cenozoic, exceptional exposure of ...active structures, and strain distribution, and widespread syn-collisional igneous activity as a proxy for the thermal state of the mantle and crust. Two Cenozoic orogens dominate the continent: the Himalayan–Tibetan orogen in the east induced by the India–Asia collision and the Turkish–Iranian–Caucasus orogen in the west induced by the Arabia–Asia collision. The development of the two orogens was accomplished by shortening in the early stage followed by strike-slip faulting and extension in the late stage. In the Himalayan–Tibetan orogen, shortening across two discrete thrust belts at 55–30 Ma in southern and northern Tibet created a large intracontinental basin (the Paleo-Qaidam basin) in between. Subsequent crustal thickening and a possible thermal event in the mantle (e.g., convective removal of central Tibetan mantle lithosphere) may have raised the elevation of this early intra-plateau basin up to ~ 2–3 km to its current height. Collision between India and Asia also caused lateral extrusion of southeast Asia between 32 Ma and 17 Ma. The latest stage of the India–Asia collision was expressed by north-trending rifting and the development of trench-facing V-shaped conjugate strike-slip faults in central Mongolia, central Tibet, eastern Afghanistan and southeast Asia. In the Turkish–Iranian–Caucasus orogen, early crustal thickening in the orogenic interior began at or prior to 30–20 Ma. This style of deformation was replaced by strike-slip faulting at ~
15–5 Ma associated with further northward penetration of Arabia into Asia, westward extrusion of the Anatolia/Turkey block, and rapid extension across the Sea of Crete and Sea of Aegean. The late stage extension in both orogens was locally related to extensional core-complex development. The continental-margin extension of east Asia was developed in two stages: initially in a widely distributed zone that has an east-west width of 500–800 km during 65–35 Ma, which was followed by localized extension and opening of back-arc basins associated with the development of spreading centers at 32–17 Ma (e.g., Japan Sea or East Korea Sea, Bohai Bay, and South China Sea). Opening of the back-arc basins could be induced by (1) rapid eastward migration of the western Pacific trench system or (2) oblique subduction of Pacific plate beneath Asia that had produced a series of en echelon right-slip primary shear zones linking with back-arc spreading centers oriented obliquely to the strike of the nearby trench. Since ~
15 Ma, the eastern margin of Asia became contractional in the east–west direction, as indicated by the collapse of back-arc basins in the western Pacific and the development of fold-thrust belts along the eastern continental margin. Coeval with the contraction is widespread east–west extension in Siberia, North China, and the Tibetan plateau. The above observations can be explained by a change in boundary condition along the eastern margin of Asia that allowed the thickened Asian continent to spread eastward, causing east-west extension in its trailing edge and east-west compression in its leading edge. In west Asia, continental-margin extension started at about 25–20 Ma in the Aegean and Cretan regions, which was associated with a rapid southward retreat of the Hellenic arc. The complex evolution of Cenozoic deformation in Asia may be explained by a combined effect of temporal changes in plate boundary conditions, thermal evolution of the upper mantle perturbed by collisional tectonics, and the built-up of gravitational energy through crustal thickening and thermal heating. Although the past research in Asia has treated the India–Asia and Arabia–Asia convergence as separate collisional processes, their interaction may have controlled the far-field Cenozoic deformation in Asia. The most pronounced result of this interaction is the creation of a northeast-trending 300–400-km wide and >
1500-km long zone of northwest-striking right-slip faults, which extends from the Zagros thrust belt in the south to western Mongolia in the north and links with the active Tian Shan and Altai Shan intracontinental orogens. Cenozoic deformation and coeval igneous activity spatially overlap with one another in the Himalayan–Tibetan and Turkish–Iranian–Caucasus orogens. A large Cenozoic magmatic gap exists between Tibet in the south and Mongolia in the north where Cenozoic deformation has not been associated with any coeval igneous activity. Finally, Cenozoic igneous activity is always associated with Jurassic–Cretaceous magmatic arcs, suggesting a causal relationship between the early arc magmatism and later syn-collisional magmatism.
Despite a long research history over the past 150 years, the geometry, kinematics, and dynamic evolution of the Himalayan orogen remain poorly understood. This is mainly due to continued emphasis on ...the two-dimensionality of the Himalayan orogenic architecture and extrapolation of geologic relationships from a few well-studied but small areas to the rest of the orogen. Confusion and misconception are also widespread in the Himalayan literature in terms of the geographic, stratigraphic, and structural divisions. To clarify these issues and to provide a new platform for those who are interested in studying the geologic development of this spectacular mountain belt, I systematically review the essential observations relevant to the along-strike variation of the Himalayan geologic framework and its role in Cenozoic Himalayan exhumation, metamorphism and foreland sedimentation. A main focus of my synthesis is to elucidate the emplacement history of the high-grade Greater Himalayan Crystalline Complex (GHC) that occupies the core of the orogen. Because the north-dipping Main Central Thrust (MCT) above and South Tibet Detachment (STD) below bound the GHC in most parts of the Himalaya, it is critical to determine the relationship between them in map and cross-section views. The exposed map pattern in the central Himalaya (i.e., Nepal) indicates that the MCT has a flat-ramp geometry. The thrust flat in the south carries a 2–15-km-thick slab of the GHC over the Lesser Himalayan Sequence (LHS) and creates a large hanging-wall fault-bend fold continuing >
100 km south of the MCT ramp zone. In the western Himalayan orogen at the longitude ∼
77°E, the MCT exhibits a major lateral ramp (the Mandi ramp). West of this ramp, the MCT places the low-grade Tethyan Himalayan Sequence (THS) over the low-grade LHS, whereas east of the ramp, the MCT places the high-grade GHC over the low-grade LHS. This along-strike change in stratigraphic juxtaposition and metamorphic grade across the MCT indicates a westward decrease in its slip magnitude, possibly a result of a westward decrease in total crustal shortening along the Himalayan orogen. Everywhere exposed, the STD follows roughly the same stratigraphic horizon at the base of the THS, exhibiting a long (>
100 km) hanging-wall flat. This relationship suggests that the STD may have initiated along a preexisting lithologic contact or the subhorizontal brittle–ductile transition zone in the middle crust. Although the STD has the THS in its hanging wall everywhere in the Himalayan orogen, no THS footwall cutoffs have been identified. This has made slip estimates of the STD exceedingly difficult. The southernmost trace of the STD either merges with the MCT (e.g., in Zanskar) or lies within 1–2 km of the MCT frontal trace (e.g., in Bhutan), suggesting that the MCT may join the STD in their up-dip directions to the south. This geometry, largely neglected by the existing models, has important implications for the deformation, exhumation, and sedimentation history of the entire Himalayan orogen.
Actualizing full singlet exciton yield via a reverse intersystem crossing from the high‐lying triplet state to singlet state, namely, “hot exciton” mechanism, holds great potential for ...high‐performance fluorescent organic light‐emitting diodes (OLEDs). However, incorporating comprehensive insights into the mechanism and effective molecular design strategies still remains challenging. Herein, three blue emitters (CNNPI, 2TriPE‐CNNPI, and 2CzPh‐CNNPI) with a distinct local excited (LE) state and charge‐transfer (CT) state distributions in excited states are designed and synthesized. They show prominent hybridized local and charge‐transfer (HLCT) states and aggregation‐induced emission enhancement properties. The “hot exciton” mechanism based on these emitters reveals that a balanced LE/CT distribution can simultaneously boost photoluminescence efficiency and exciton utilization. In particular, a nearly 100% exciton utilization is achieved in the electroluminescence (EL) process of 2CzPh‐CNNPI. Moreover, employing 2CzPh‐CNNPI as the emitter, emissive dopant, and sensitizing host, respectively, the EL performances of the corresponding nondoped pure‐blue, doped deep‐blue, and HLCT‐sensitized fluorescent OLEDs are among the most efficient OLEDs with a “hot exciton” mechanism to date. These results could shed light on the design principles for “hot exciton” materials and inspire the development of next‐generation high‐performance OLEDs.
Full exciton utilization is achieved in the electroluminescence process of 2CzPh‐CNNPI, owing to the balanced distribution of locally excited and charge‐transfer states. Further, this molecule is the first “hot exciton” material that can be employed as the emitter, emissive dopant, and sensitizing host, respectively, and simultaneously achieve high performance in the corresponding blue and host‐sensitized fluorescent organic light‐emitting diodes.
WRKY transcription factors play a key role in the tolerance of biotic and abiotic stresses across various crop species, but the function of some WRKY genes, particularly in tomato, remains ...unexplored. Here, we characterize the roles of a previously unstudied WRKY gene, SlWRKY8, in the resistance to pathogen infection and the tolerance to drought and salt stresses. Expression of SlWRKY8 was up‐regulated upon Pseudomonas syringae pv. tomato DC3000 (Pst. DC3000), abiotic stresses such as drought, salt and cold, as well as ABA and SA treatments. The SlWRKY8 protein was localized to the nucleus with no transcription activation in yeast, but it could activate W‐box‐dependent transcription in plants. The overexpression of SlWRKY8 in tomato conferred a greater resistance to the pathogen Pst. DC3000 and resulted in the increased transcription levels of two pathogen‐related genes SlPR1a1 and SlPR7. Moreover, transgenic plants displayed the alleviated wilting or chlorosis phenotype under drought and salt stresses, with higher levels of stress‐induced osmotic substances like proline and higher transcript levels of the stress‐responsive genes SlAREB, SlDREB2A and SlRD29. Stomatal aperature was smaller under drought stress in transgenic plants, maintaining higher water content in leaves compared with wild‐type plants. The oxidative pressure, indicated by the concentration of hydrogen peroxide (H2O2) and malondialdehyde (MDA), was also reduced in transgenic plants, where we also observed higher levels of antioxidant enzyme activities under stress. Overall, our results suggest that SlWRKY8 functions as a positive regulator in plant immunity against pathogen infection as well as in plant responses to drought and salt stresses.
In order to better constrain the evolution of the Tethyan orogenic system, we conducted an integrated investigation involving U-Pb dating of igneous and detrital zircon, geochemical analysis of ...igneous rocks, compositional analysis of sedimentary strata, and a synthesis of existing work across the Qilian Shan, Qaidam Basin, and the Eastern Kunlun Range of central and northern Tibet. This effort reveals five stages of arc magmatism at 1005-910 Ma, 790-720 Ma, 580-500 Ma, 490-375 Ma, and 290-195 Ma, respectively. Arc activities were interrupted by repeated continent-continent collision followed by ocean opening along the older suture zones first created in the Neoproterozoic. This suggests that Wilson cycles have played a controlling role in constructing the southern Asian continent. The magmatic history and regional geologic constraints allow us to construct a coherent tectonic model that has the following key features. (1) The linked South Qilian suture in the west and North Qinling suture in the east formed the northern boundary of the coherent Kunlun-Qaidam-North Qinling Terrane in the early Paleozoic. (2) The Songpan-Ganzi Terrane has been the western part of the Yangtze craton since the Neoproterozoic. (3) Development of the wide (>700 km) Permian-Triassic arc across the Kunlun-Qaidam Terrane was induced by flat subduction and rapid slab rollback, which also caused extreme extension of the Songpan-Ganzi Terrane. (4) The formation of the Anymaqen-Kunlun-Muztagh Ocean (= the Neo-Kunlun Ocean in this study) was created within Laurasia rather than being a preexisting ocean between Gondwana and Laurasia as postulated by most early studies.
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•Magnetic OMICs were successfully fabricated via a facile inverse micelle method.•Calcination temperature affected the structure property and surface chemistry of OMICs.•OMIC-3 ...exhibited excellent performance for As(III) and As(V) removal from water.•HA significantly influenced on the arsenic removal even at a lower concentration.•Surface hydroxyl groups played a key role in the arsenic adsorption mechanism.
In this study, magnetic ordered mesoporous Fe/Ce bimetal oxides (OMICs) were successfully synthesized via the modified sol-gel-based inverse micelle method. The textural/structure properties, surface chemistry and adsorption behavior of OMICs could be easily adjusted by using the calcination temperature. The sintering of samples would decrease the surface area, while expand the pore and crystallite size, which resulted in the formation of highly ordered inner-connected structure. Compared with pure mesoporous iron oxides (MI) and mesoporous cerium oxides (MC), this ordered mesoporous iron-cerium bimetal oxides (OMIC-3, 450 °C) exhibited remarkable arsenic adsorption performance. The maximum adsorption capacities of As(III) and As(V) for OMIC-3 were 281.34 and 216.72 mg/g, respectively, and both As(III)/As(V) adsorption kinetics were well described by the pseudo-second order. The ionic strength and coexisting ions (except SiO32− and PO43-) did not affect arsenic removal, while humic acid (HA) significantly influenced on the arsenic removal even at a lower concentration. The adsorption mechanism study revealed that both the surface charge and surface M-OH groups of OMIC-3 were played the key roles in arsenic removal. The reusable property suggested that this magnetic OMIC-3 was a promising excellent adsorbent for decontamination of arsenic-polluted (especially As(III)-polluted) wastewater.
Collision-induced continental deformation commonly involves complex interactions between strike-slip faulting and off-fault deformation, yet this relationship has rarely been quantified. In northern ...Tibet, Cenozoic deformation is expressed by the development of the >1000-km-long east-striking left-slip Kunlun, Qinling, and Haiyuan faults. Each have a maximum slip in the central fault segment exceeding 10s to ~100km but a much smaller slip magnitude (~<10% of the maximum slip) at their terminations. The along-strike variation of fault offsets and pervasive off-fault deformation create a strain pattern that departs from the expectations of the classic plate-like rigid-body motion and flow-like distributed deformation end-member models for continental tectonics. Here we propose a non-rigid bookshelf-fault model for the Cenozoic tectonic development of northern Tibet. Our model, quantitatively relating discrete left-slip faulting to distributed off-fault deformation during regional clockwise rotation, explains several puzzling features, including the: (1) clockwise rotation of east-striking left-slip faults against the northeast-striking left-slip Altyn Tagh fault along the northwestern margin of the Tibetan Plateau, (2) alternating fault-parallel extension and shortening in the off-fault regions, and (3) eastward-tapering map-view geometries of the Qimen Tagh, Qaidam, and Qilian Shan thrust belts that link with the three major left-slip faults in northern Tibet. We refer to this specific non-rigid bookshelf-fault system as a passive bookshelf-fault system because the rotating bookshelf panels are detached from the rigid bounding domains. As a consequence, the wallrock of the strike-slip faults deforms to accommodate both the clockwise rotation of the left-slip faults and off-fault strain that arises at the fault ends. An important implication of our model is that the style and magnitude of Cenozoic deformation in northern Tibet vary considerably in the east–west direction. Thus, any single north–south cross section and its kinematic reconstruction through the region do not properly quantify the complex deformational processes of plateau formation.
•We propose a non-rigid passive bookshelf-fault model for deformation in north Tibet.•Right-lateral shear drives clockwise rotation and left-slip faulting on W–E faults.•Clockwise rotation of faults occurs against left-slip Altyn Tagh bounding fault.•Model explains bidirectional decrease in slip and four-quadrant strain pattern.•Protracted deformation in northern Tibet since Eocene
Organic emitters with persistent phosphorescence have shown potential application in optoelectronic devices. However, rational design and phosphorescence tuning are still challenging. Here, a series ...of metal-free luminophores without heavy atoms and carbonyl groups from commercial/lab-synthesized carbazole and benzene were synthesized to realize tunable molecular emission from fluorescence to phosphorescence by simply substituent variation. All the molecules emit blue fluorescence in both solution and solid state. Upon removal of excitation source, the fluorinated luminophores show obvious phosphorescence. The lab-synthesized carbazole based molecules exhibit a huge lifetime difference to the commercially purchased ones due to the existence of isomer in the latter samples. The small energy gap between singlet and triplet state and low reorganization energy help enhance intersystem crossing to contribute to a more competitive radiative process from triplet to ground state. Blue and white organic light-emitting devices are fabricated by using fluorinated luminophore as emitting layer.
Abstract
The demand for sustainable energy has motivated the development of artificial photosynthesis. Yet the catalyst and reaction interface designs for directly fixing permanent gases (e.g. CO
2
, ...O
2
, N
2
) into liquid fuels are still challenged by slow mass transfer and sluggish catalytic kinetics at the gas-liquid-solid boundary. Here, we report that gas-permeable metal-organic framework (MOF) membranes can modify the electronic structures and catalytic properties of metal single-atoms (SAs) to promote the diffusion, activation, and reduction of gas molecules (e.g. CO
2,
O
2
) and produce liquid fuels under visible light and mild conditions. With Ir SAs as active centers, the defect-engineered MOF (e.g. activated NH
2
-UiO-66) particles can reduce CO
2
to HCOOH with an apparent quantum efficiency (AQE) of 2.51% at 420 nm on the gas-liquid-solid reaction interface. With promoted gas diffusion at the porous gas-solid interfaces, the gas-permeable SA/MOF membranes can directly convert humid CO
2
gas into HCOOH with a near-unity selectivity and a significantly increased AQE of 15.76% at 420 nm. A similar strategy can be applied to the photocatalytic O
2
-to-H
2
O
2
conversions, suggesting the wide applicability of our catalyst and reaction interface designs.
This study aims at examining the correlation of intraosseous temperature change with drilling impulse data during osteotomy and establishing real-time temperature prediction models.
A combination of ...in vitro bovine rib model and Autonomous Dental Implant Robotic System (ADIR) was set up, in which intraosseous temperature and drilling impulse data were measured using an infrared camera and a six-axis force/torque sensor respectively. A total of 800 drills with different parameters (e.g., drill diameter, drill wear, drilling speed, and thickness of cortical bone) were experimented, along with an independent test set of 200 drills. Pearson correlation analysis was done for linear relationship. Four machining learning (ML) algorithms (e.g., support vector regression SVR, ridge regression RR, extreme gradient boosting XGboost, and artificial neural network ANN) were run for building prediction models.
By incorporating different parameters, it was found that lower drilling speed, smaller drill diameter, more severe wear, and thicker cortical bone were associated with higher intraosseous temperature changes and longer time exposure and were accompanied with alterations in drilling impulse data. Pearson correlation analysis further identified highly linear correlation between drilling impulse data and thermal changes. Finally, four ML prediction models were established, among which XGboost model showed the best performance with the minimum error measurements in test set.
The proof-of-concept study highlighted close correlation of drilling impulse data with intraosseous temperature change during osteotomy. The ML prediction models may inspire future improvement on prevention of thermal bone injury and intelligent design of robot-assisted implant surgery.
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