Fiber-based electronics enabling lightweight and mechanically flexible/stretchable functions are desirable for numerous e-textile/e-skin optoelectronic applications. These wearable devices require ...low-cost manufacturing, high reliability, multifunctionality and long-term stability. Here, we report the preparation of representative classes of 3D-inorganic nanofiber network (FN) films by a blow-spinning technique, including semiconducting indium-gallium-zinc oxide (IGZO) and copper oxide, as well as conducting indium-tin oxide and copper metal. Specifically, thin-film transistors based on IGZO FN exhibit negligible performance degradation after one thousand bending cycles and exceptional room-temperature gas sensing performance. Owing to their great stretchability, these metal oxide FNs can be laminated/embedded on/into elastomers, yielding multifunctional single-sensing resistors as well as fully monolithically integrated e-skin devices. These can detect and differentiate multiple stimuli including analytes, light, strain, pressure, temperature, humidity, body movement, and respiratory functions. All of these FN-based devices exhibit excellent sensitivity, response time, and detection limits, making them promising candidates for versatile wearable electronics.
The papers in this special section focus on materials and devices for flexible sensors. Presents recent advances in skin electronics, touch sensors for flexible display, near-infrared spectroscopy ...(NIRS) and organic electrochemical transistors (OECT), respectively. Three research article introduces new methods in flexible pressure sensing array, ammonia sensors and charge plasma junctionless tunnel field effect transistor (CP JLTFET), respectively.
Realizing fully stretchable electronic materials is central to advancing new types of mechanically agile and skin-integrable optoelectronic device technologies. Here we demonstrate a materials design ...concept combining an organic semiconductor film with a honeycomb porous structure with biaxially prestretched platform that enables high-performance organic electrochemical transistors with a charge transport stability over 30-140% tensional strain, limited only by metal contact fatigue. The prestretched honeycomb semiconductor channel of donor-acceptor polymer poly(2,5-bis(2-octyldodecyl)-3,6-di(thiophen-2-yl)-2,5-diketo-pyrrolopyrrole-alt-2,5-bis(3-triethyleneglycoloxy-thiophen-2-yl) exhibits high ion uptake and completely stable electrochemical and mechanical properties over 1,500 redox cycles with 10
stretching cycles under 30% strain. Invariant electrocardiogram recording cycles and synapse responses under varying strains, along with mechanical finite element analysis, underscore that the present stretchable organic electrochemical transistor design strategy is suitable for diverse applications requiring stable signal output under deformation with low power dissipation and mechanical robustness.
Traditional technologies for virtual reality (VR) and augmented reality (AR) create human experiences through visual and auditory stimuli that replicate sensations associated with the physical world. ...The most widespread VR and AR systems use head-mounted displays, accelerometers and loudspeakers as the basis for three-dimensional, computer-generated environments that can exist in isolation or as overlays on actual scenery. In comparison to the eyes and the ears, the skin is a relatively underexplored sensory interface for VR and AR technology that could, nevertheless, greatly enhance experiences at a qualitative level, with direct relevance in areas such as communications, entertainment and medicine
. Here we present a wireless, battery-free platform of electronic systems and haptic (that is, touch-based) interfaces capable of softly laminating onto the curved surfaces of the skin to communicate information via spatio-temporally programmable patterns of localized mechanical vibrations. We describe the materials, device structures, power delivery strategies and communication schemes that serve as the foundations for such platforms. The resulting technology creates many opportunities for use where the skin provides an electronically programmable communication and sensory input channel to the body, as demonstrated through applications in social media and personal engagement, prosthetic control and feedback, and gaming and entertainment.
We report a micellar system to prepare Pt-TMDs composites with tunable Pt nanoparticles (NPs, 2-6 nm in size) on single-layer TMDs (MoS
2
, TiS
2
, TaS
2
) nanosheets. The Pt-MoS
2
composites have ...shown excellent performance for the hydrogen evolution reaction (HER) with the Pt NPs exhibiting a volcano-type size effect toward HER activity due to the synergistic effects between the Pt NPs and MoS
2
.
Pt-MoS2 composites are fabricated via growing tunable Pt nanoparticles size (NPs, 2-6 nm) on single-layer MoS2 nanosheets. Which have shown excellent performance for hydrogen evolution reaction (HER) with the Pt NPs exhibiting a volcano-type size effect toward mass activity due to the synergistic effects between the Pt NPs and MoS2.
Lead halide perovskite and organic solar cells (PSCs and OSCs) are considered as the prime candidates currently for clean energy applications due to their solution and low‐temperature processibility. ...Nevertheless, the substantial photon loss in near‐infrared (NIR) region and relatively large photovoltage deficit need to be improved to enable their uses in high‐performance solar cells. To mitigate these disadvantages, low‐bandgap organic bulk‐heterojunction (BHJ) layer into inverted PSCs to construct facile hybrid solar cells (HSCs) is integrated. By optimizing the BHJ components, an excellent power conversion efficiency (PCE) of 23.80%, with a decent open‐circuit voltage (Voc) of 1.146 V and extended photoresponse over 950 nm for rigid HSCs is achieved. The resultant devices also exhibit superior long‐term (over 1000 h) ambient‐ and photostability compared to those from single‐component PSCs and OSCs. More importantly, a champion PCE of 21.73% and excellent mechanical durability can also be achieved in flexible HSCs, which is the highest efficiency reported for flexible solar cells to date. Taking advantage of these impressive device performances, flexible HSCs into a power source for wearable sensors to demonstrate real‐time temperature monitoring are successfully integrated.
A flexible hybrid solar cell with extended photoresponse, high power conversion efficiency of 21.73%, and excellent mechanical durability is realized by incorporating a low‐bandgap organic bulk heterojunction layer into perovskite solar cells. Taking advantage of these impressive device performance, the flexible solar cell–sensor integrated system is demonstrated for real‐time temperature monitoring via on‐body evaluation.
The advances in wearable/flexible electronics have triggered tremendous demands for flexible power sources, where flexible nanogenerators, capable of converting mechanical energy into electricity, ...demonstrate its great potential. Here, recent progress on flexible nanogenerators for mechanical energy harvesting toward self‐powered systems, including flexible piezoelectric and triboelectric nanogenerator, is reviewed. The emphasis is mainly on the basic working principle, the newly developed materials and structural design as well as associated typical applications for energy harvesting, sensing, and self‐powered systems. In addition, the progress of flexible hybrid nanogenerator in terms of its applications is also highlighted. Finally, the challenges and future perspectives toward flexible self‐powered systems are reviewed.
The advances in epidermal electronics have triggered tremendous demands for flexible power sources, where flexible nanogenerator demonstrates its great potential. Here, recent progress on flexible nanogenerators, including flexible piezoelectric, triboelectric, and hybrid nanogenerator, is reviewed, emphasizing the working principle, the advanced materials, fancy structure design and associated applications for energy harvesting.
Continuous monitoring of blood pressure, an essential measure of health status, typically requires complex, costly, and invasive techniques that can expose patients to risks of complications. ...Continuous, cuffless, and noninvasive blood pressure monitoring methods that correlate measured pulse wave velocity (PWV) to the blood pressure via the Moens–Korteweg (MK) and Hughes Equations, offer promising alternatives. The MK Equation, however, involves two assumptions that do not hold for human arteries, and the Hughes Equation is empirical, without any theoretical basis. The results presented here establish a relation between the blood pressure P and PWV that does not rely on the Hughes Equation nor on the assumptions used in the MK Equation. This relation degenerates to the MK Equation under extremely low blood pressures, and it accurately captures the results of in vitro experiments using artificial blood vessels at comparatively high pressures. For human arteries, which are well characterized by the Fung hyperelastic model, a simple formula between P and PWV is established within the range of human blood pressures. This formula is validated by literature data as well as by experiments on human subjects, with applicability in the determination of blood pressure from PWV in continuous, cuffless, and noninvasive blood pressure monitoring systems.
Metal-oxide (MO) semiconductors have emerged as enabling materials for next generation thin-film electronics owing to their high carrier mobilities, even in the amorphous state, large-area ...uniformity, low cost, and optical transparency, which are applicable to flat-panel displays, flexible circuitry, and photovoltaic cells. Impressive progress in solution-processed MO electronics has been achieved using methodologies such as sol gel, deep-UV irradiation, preformed nanostructures, and combustion synthesis. Nevertheless, because of incomplete lattice condensation and film densification, high-quality solution-processed MO films having technologically relevant thicknesses achievable in a single step have yet to be shown. Here, we report a low-temperature, thickness-controlled coating process to create high-performance, solution-processed MO electronics: spray-combustion synthesis (SCS). We also report for the first time, to our knowledge, indium-gallium-zinc-oxide (IGZO) transistors having densification, nanoporosity, electron mobility, trap densities, bias stability, and film transport approaching those of sputtered films and compatible with conventional fabrication (FAB) operations.
Significance Although impressive progress in solution-processed metal-oxide (MO) electronics has been achieved, fundamental science challenges remain concerning whether solution-processed MO materials and particularly technologically relevant, indium-gallium-tin-oxide (IGZO), can achieve efficient and stable charge transport characteristics when processed at low temperatures for short times and how IGZO film density, porosity, carrier mobility, and charge trapping can be manipulated. Here, we report a coating technique, spray-combustion synthesis, and demonstrate IGZO semiconductor thickness, densification, nanoporosity, electron mobility, trap densities, and bias stress stability approaching the quality of sputtered films.
Abstract
The dramatic advances in flexible/wearable electronics have garnered great attention for touch sensors for practical applications in human health monitoring and human–machine interfaces. ...Self-powered triboelectric tactile sensors with high sensitivity, reduced crosstalk, and simple processing routes are highly desirable. Herein, we introduce a facile and low-cost fabrication approach for a metal-electrode free, fully integrated, flexible, and self-powered triboelectric tactile sensor array with 8-by-8 sensor units. Through the height difference between the sensor units and interconnect electrodes, the crosstalk derived from the electrodes has been successfully suppressed with no additional shielding layers. The tactile sensor array shows a remarkable sensitivity of 0.063 V kPa
–1
with a linear range from 5 to 50 kPa, which covers a broad range of testing objects. Furthermore, due to the advanced mechanical design, the flexible sensor array exhibits great capability of pressure sensing even under a curved state. The voltage responses from the pattern mapping by finger touching demonstrate the uniformity of the sensor array. Finally, real-time tactile sensing associated with light-emitting diode (LED) array lighting demonstrates the potential application of the sensor array in position tracking, self-powered touch screens, human–machine interfaces and many others.
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