Since the first attempt that was made to obtain direct circularly polarized (CP) light from OLEDs by Meijer
et al.
in 1997, considerable efforts have been devoted to the development of circularly ...polarized organic light-emitting diodes (CP-OLEDs), particularly in the recent years. Circularly polarized electroluminescence (CPEL) based on OLEDs has attracted increasing interest for its efficient ability to generate CP light directly and wide potential applications in 3D displays, optical data storage, and optical spintronics. In this review, we systematically summarize the recent progress in chiral emitter based OLEDs with CPEL properties including CPEL based on chiral conjugated polymers, CPEL based on chiral metal complexes, and CPEL based on chiral simple organic molecules, especially chiral thermally activated delayed fluorescence (TADF) molecules. We believe that this review will provide a promising perspective of chiral emitter based OLEDs with CPEL properties for a broad range of scientists in different disciplinary areas and attract a growing number of researchers to this fast-growing research field.
This review summarizes the recent advances in CP-OLEDs based on chiral conjugated polymers, chiral metal complexes, and chiral simple organic molecules.
Dendrobiumofficinale (Orchidaceae) is one of the world's most endangered plants with great medicinal value. In nature, D. officinale seeds must establish symbiotic relationships with fungi to ...germinate. However, the molecular events involved in the interaction between fungus and plant during this process are poorly understood. To isolate the genes involved in symbiotic germination, a suppression subtractive hybridization (SSH) cDNA library of symbiotically germinated D. officinale seeds was constructed. From this library, 1437 expressed sequence tags (ESTs) were clustered to 1074 Unigenes (including 902 singletons and 172 contigs), which were searched against the NCBI non-redundant (NR) protein database (E-value cutoff, e(-5)). Based on sequence similarity with known proteins, 579 differentially expressed genes in D. officinale were identified and classified into different functional categories by Gene Ontology (GO), Clusters of orthologous Groups of proteins (COGs) and Kyoto Encyclopedia of Genes and Genomes (KEGG) pathways. The expression levels of 15 selected genes emblematic of symbiotic germination were confirmed via real-time quantitative PCR. These genes were classified into various categories, including defense and stress response, metabolism, transcriptional regulation, transport process and signal transduction pathways. All transcripts were upregulated in the symbiotically germinated seeds (SGS). The functions of these genes in symbiotic germination were predicted. Furthermore, two fungus-induced calcium-dependent protein kinases (CDPKs), which were upregulated 6.76- and 26.69-fold in SGS compared with un-germinated seeds (UGS), were cloned from D. officinale and characterized for the first time. This study provides the first global overview of genes putatively involved in D. officinale symbiotic seed germination and provides a foundation for further functional research regarding symbiotic relationships in orchids.
Celotno besedilo
Dostopno za:
DOBA, IZUM, KILJ, NUK, PILJ, PNG, SAZU, SIK, UILJ, UKNU, UL, UM, UPUK
Organic donor–acceptor systems have attracted much attention due to their various potential applications. However, the rational construction and modulation of highly ordered donor–acceptor systems ...could be a challenge due to the complicated self‐assembly process of donor and acceptor species. Considering the well‐defined arrangement of species at the molecule level, a crystalline host–guest system could be an ideal platform for the rational construction of donor–acceptor systems. Herein, it is shown how the rational construction of highly tunable donor–acceptor materials can be achieved based on a crystalline host–guest platform. Within the well‐established metal–organic framework NKU‐111 as the crystalline host enabled by the relatively stable coordination‐directed assembly, the introduction and arrangement of guest molecules in the crystals allow the rational construction of the NKU‐111⊃guest donor–acceptor system. The donor–acceptor interaction in the systems can be readily modulated with different guest molecules, which can be justified by the well‐demonstrated guest‐dependent characteristics. Accordingly, the NKU‐111⊃guest reveals highly tunable donor–acceptor properties such as charge‐transfer‐based emissions and electrical conductivity. This work indicates the potential of crystalline host–guest systems as an ideal platform for systematic investigations of donor–acceptor materials.
A donor–acceptor material based on a host–guest crystalline material platform is raised. As a proof of concept, a metal–organic framework (NKU‐111) is utilized as a host acceptor for the accommodation of aromatic donor guests. The resulting donor–acceptor system features highly tunable charge‐transfer‐based emissions and conductivity, indicating the rationality and efficiency of this strategy.
Abstract
Previous studies have focused mostly on the roles of environmental factors in the rapid intensification (RI) of tropical cyclones (TCs) because of the lack of high-resolution data in ...inner-core regions. In this study, the RI of TCs is examined by analyzing the relationship between an upper-level warm core, convective bursts (CBs), sea surface temperature (SST), and surface pressure falls from 72-h cloud-permitting predictions of Hurricane Wilma (2005) with the finest grid size of 1 km. Results show that both the upper-level inertial stability increases and static stability decreases sharply 2–3 h prior to RI, and that the formation of an upper-level warm core, from the subsidence of stratospheric air associated with the detrainment of CBs, coincides with the onset of RI. It is found that the development of CBs precedes RI, but most subsidence warming radiates away by gravity waves and storm-relative flows. In contrast, many fewer CBs occur during RI, but more subsidence warming contributes to the balanced upper-level cyclonic circulation in the warm-core (as intense as 20°C) region. Furthermore, considerable CB activity can still take place in the outer eyewall as the storm weakens during its eyewall replacement. A sensitivity simulation, in which SSTs are reduced by 1°C, shows pronounced reductions in the upper-level warm-core intensity and CB activity. It is concluded that significant CB activity in the inner-core regions is an important ingredient in generating the upper-level warm core that is hydrostatically more efficient for the RI of TCs, given all of the other favorable environmental conditions.
Celotno besedilo
Dostopno za:
DOBA, IZUM, KILJ, NUK, PILJ, PNG, SAZU, SIK, UILJ, UKNU, UL, UM, UPUK
Abstract
In this study, a nocturnal extreme rainfall event induced by the urban heat island (UHI) effects of the coastal city of Guangzhou in South China on 7 May 2017 is examined using observational ...analyses and 18-h cloud-permitting simulations with the finest grid size of 1.33 km and the bottom boundary conditions nudged. Results show that the model reproduces convective initiation on Guangzhou’s downstream side (i.e., Huashan), where a shallow thermal mesolow is located, the subsequent back-building of convective cells as a larger-scale warm-moist southerly flow interacts with convectively generated cold outflows, and their eastward drifting and reorganization into a localized extreme-rain-producing storm near Jiulong under the influences of local orography. In particular, the model produces the maximum hourly, 3- and 12-hourly rainfall amounts of 146, 315, and 551 mm, respectively, at nearly the right location compared to their corresponding observed extreme amounts of 184, 382, and 542 mm. In addition, the model reproduces an intense meso-γ-scale vortex associated with the extreme-rain-producing Jiulong storm, as also captured by Doppler radar, with organized updrafts along cold outflow boundaries over a semicircle. A comparison of sensitivity and control simulations indicates that despite the occurrence of heavier rainfall amounts without the UHI effects than those without orography, the UHI effects appear to account directly for the convective initiation and heavy rainfall near Huashan, and indirectly for the subsequent formation of the Jiulong storm, while orography plays an important role in blocking cold outflows and enhancing cool pool strength for the sustained back-building of convective cells over the semicircle, thereby magnifying rainfall production near Jiulong.
Celotno besedilo
Dostopno za:
DOBA, IZUM, KILJ, NUK, PILJ, PNG, SAZU, UILJ, UKNU, UL, UM, UPUK
COVID-19 is associated with 5.1% mortality. Although the virological, epidemiological, clinical, and management outcome features of COVID-19 patients have been defined rapidly, the inflammatory and ...immune profiles require definition as they influence pathogenesis and clinical expression of COVID-19. Here we show lymphopenia, selective loss of CD4+ T cells, CD8+ T cells and NK cells, excessive T-cell activation and high expression of T-cell inhibitory molecules are more prominent in severe cases than in those with mild disease. CD8+ T cells in patients with severe disease express high levels of cytotoxic molecules. Histochemical studies of lung tissue from one fatality show sub-anatomical distributions of SARS-CoV-2 RNA and massive infiltration of T cells and macrophages. Thus, aberrant activation and dysregulation of CD8+ T cells occur in patients with severe COVID-19 disease, an effect that might be for pathogenesis of SARS-CoV-2 infection and indicate that immune-based targets for therapeutic interventions constitute a promising treatment for severe COVID-19 patients.
The catalyst in the oxygen electrode is the core component of the aqueous metal-air battery, which plays a vital role in the determination of the open circuit potential, energy density, and cycle ...life of the battery. For rechargeable aqueous metal-air batteries, the catalyst should have both good oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) catalytic performance. Compared with precious metal catalysts, non-precious metal materials have more advantages in terms of abundant resource reserves and low prices. Over the past few years, great efforts have been made in the development of non-precious metal bifunctional catalysts. This review selectively evaluates the advantages, disadvantages and development status of recent advanced materials including pure carbon materials, carbon-based metal materials and carbon-free materials as bifunctional oxygen catalysts. Preliminary improvement strategies are formulated to make up for the deficiency of each material. The development prospects and challenges facing bifunctional catalysts in the future are also discussed.
Different types of advanced non-noble materials in bifunctional catalysts for ORR and OER.
Herein, we propose a solvent-assisted approach for preparing Ni-MOF microflowers with high specific capacitance and excellent rate capability as an electrode material for supercapacitors. The high ...electrochemical performance of this Ni-MOF is attributed to the fast ion transport and low electrical resistance resulting from its hierarchical flower-like structure, and the capacitance contribution from nickel hydroxide species.
Herein, we propose a solvent-assisted approach for preparing Ni-MOF microflowers with high specific capacitance and excellent rate capability as electrode materials for supercapacitors.
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