This tutorial review provides a brief summary of recent research progress on carbon-based electrode materials for supercapacitors, as well as the importance of electrolytes in the development of ...supercapacitor technology. The basic principles of supercapacitors, the characteristics and performances of various nanostructured carbon-based electrode materials are discussed. Aqueous and non-aqueous electrolyte solutions used in supercapacitors are compared. The trend on future development of high-power and high-energy supercapacitors is analyzed.
A second-order topological insulator (SOTI) in d spatial dimensions features topologically protected gapless states at its (d-2)-dimensional boundary at the intersection of two crystal faces, but is ...gapped otherwise. As a novel topological state, it has been attracting great interest, but it remains a challenge to identify a realistic SOTI material in two dimensions (2D). Here, based on combined first-principles calculations and theoretical analysis, we reveal the already experimentally synthesized 2D material graphdiyne as the first realistic example of a 2D SOTI, with topologically protected 0D corner states. The role of crystalline symmetry, the robustness against symmetry breaking, and the possible experimental characterization are discussed. Our results uncover a hidden topological character of graphdiyne and promote it as a concrete material platform for exploring the intriguing physics of higher-order topological phases.
Electric double-layer capacitors are a family of electrochemical energy storage devices that offer a number of advantages, such as high power density and long cyclability. In recent years, research ...and development of electric double-layer capacitor technology has been growing rapidly, in response to the increasing demand for energy storage devices from emerging industries, such as hybrid and electric vehicles, renewable energy, and smart grid management. The past few years have witnessed a number of significant research breakthroughs in terms of novel electrodes, new electrolytes, and fabrication of devices, thanks to the discovery of innovative materials (
e.g.
graphene, carbide-derived carbon, and templated carbon) and the availability of advanced experimental and computational tools. However, some experimental observations could not be clearly understood and interpreted due to limitations of traditional theories, some of which were developed more than one hundred years ago. This has led to significant research efforts in computational simulation and modelling, aimed at developing new theories, or improving the existing ones to help interpret experimental results. This review article provides a summary of research progress in molecular modelling of the physical phenomena taking place in electric double-layer capacitors. An introduction to electric double-layer capacitors and their applications, alongside a brief description of electric double layer theories, is presented first. Second, molecular modelling of ion behaviours of various electrolytes interacting with electrodes under different conditions is reviewed. Finally, key conclusions and outlooks are given. Simulations on comparing electric double-layer structure at planar and porous electrode surfaces under equilibrium conditions have revealed significant structural differences between the two electrode types, and porous electrodes have been shown to store charge more efficiently. Accurate electrolyte and electrode models which account for polarisation effects are critical for future simulations which will consider more complex electrode geometries, particularly for the study of dynamics of electrolyte transport, where the exclusion of electrode polarisation leads to significant artefacts.
A comprehensive review of molecular simulations of electric double-layer capacitors using various electrolyte types at porous and non-porous electrodes.
The oxygen reduction reaction (ORR) is one of the most important electrochemical reactions in energy conversion and storage technologies, such as fuel cells and metal-air batteries. However, the ...sluggish kinetics of the ORR is a key factor limiting the performance of these energy storage and conversion devices. Perovskite oxides are a promising family of electrocatalysts for the ORR because of their unique physical and chemical properties, such as variable crystal structure and non-stoichiometric chemistry. Studies have shown that the catalytic properties of perovskite oxides in the ORR are largely related to oxygen vacancies, which alter their electronic and crystal structures and surface chemistry. This review summarizes recent research advances on understanding the role of oxygen vacancies of the ABO
3
perovskite oxides in catalyzing the ORR. With a brief introduction of perovskite oxides, approaches to creating oxygen vacancies in the ABO
3
perovskite oxides and the role of oxygen vacancies in improving their catalytic performance for the ORR are discussed. Research perspectives in this important area are highlighted.
The oxygen reduction reaction (ORR) is one of the most important electrochemical reactions in energy conversion and storage technologies, such as fuel cells and metal-air batteries.
In this work, conducting polymers poly(3,4-ethylenedioxythiophene) (PEDOT), polyaniline (PANi), and polypyrrole (PPy) were directly coated on the surface of reduced graphene oxide (RGO) sheets via ...an in situ polymerization process to prepare conducting-polymer-RGO nanocomposites with different loadings of the conducting polymers. Experiment results showed that ethanol played an important role in achieving a uniform coating of the polymers on RGO sheets. The electrochemical capacitive properties of the composite materials were investigated by using cycle voltammetry and charge/discharge techniques. The composite consisting of RGO and PANi (RGO-PANi) exhibited a specific capacitance of 361 F/g at a current density of 0.3 A/g. The composites consisting of RGO and PPy (RGO-PPy) and PEDOT (RGO-PEDOT) displayed specific capacitances of 248 and 108 F/g, respectively, at the same current density. More than 80% of initial capacitance retained after 1000 charge/discharge cycles, suggesting a good cycling stability of the composite electrodes. The good capacitive performance of the conducting–polymer-RGO composites is contributed to the synergic effect of the two components.
The impact of central Asian aridification on the low latitude North Pacific Ocean since the late Miocene remains unclear. To address this question, we systematically studied an abyssal manganese ...nodule from the northwestern Pacific Ocean, which is expected to be sensitive to eolian dust sourced from central Asia. Geochemical variations and the fossilized remains of magnetotactic bacteria within the studied nodule manifest two prominent Asian aridification events at ∼8–7 Ma and 3.6–0 Ma. These results suggest that central Asian aridification impacted both primary productivity and abyssal microbial activity in the NW Pacific Ocean via eolian dust inputs. In contrast to the Pliocene aridification event, the late Miocene event was associated with a primary productivity bloom that is not evident in coeval global primary productivity records, which indicates that the ∼8–7 Asian aridification event was likely due to NE Tibetan Plateau uplift rather than to global cooling.
Plain Language Summary
Central Asian aridification since the late Miocene has had a significant influence on climate, temperature, and North Pacific Ocean productivity through eolian dust inputs transported by westerlies. However, it is unclear whether the low latitude of NW Pacific Ocean responded to this aridification. We systematically analyzed the geochemistry and magnetism of a NW Pacific manganese nodule, and find that Asian aridification since, the late Miocene impacted biogeochemical cycling and abyssal microbial activity in the NW Pacific Ocean via eolian dust input. Our results imply that these two prominent Asian aridification events at around 8–7 Ma and ca. 3.6 Ma can be attributed to the NE Tibetan Plateau uplift and global cooling, respectively.
Key Points
A manganese nodule from the NW Pacific carries a paleoclimatic record of Asian aridification since the Late Miocene
Asian aridification impacted biogeochemical cycling and abyssal microbial activity in the NW Pacific Ocean
Major Asian aridification events at ∼8–7 Ma and ∼3.6–0 Ma may be attributed to NE Tibetan Plateau uplift and global cooling, respectively
Supercapacitors, which are attracting rapidly growing interest from both academia and industry, are important energy‐storage devices for acquiring sustainable energy. Recent years have seen a number ...of significant breakthroughs in the research and development of supercapacitors. The emergence of innovative electrode materials (e.g., graphene) has clearly provided great opportunities for advancing the science in the field of electrochemical energy storage. Conversely, smart configurations of electrode materials and new designs of supercapacitor devices have, in many cases, boosted the electrochemical performance of the materials. We attempt to summarize recent research progress towards the design and configuration of electrode materials to maximize supercapacitor performance in terms of energy density, power density, and cycle stability. With a brief description of the structure, energy‐storage mechanism, and electrode configuration of supercapacitor devices, the design and configuration of symmetric supercapacitors are discussed, followed by that of asymmetric and hybrid supercapacitors. Emphasis is placed on the rational design and configuration of supercapacitor electrodes to maximize the electrochemical performance of the device.
Charged and ready to go: In the past few years, significant breakthroughs in the development of supercapacitors as energy‐storage devices is promoted by the emergence of innovative electrode materials (e.g., graphene) and driven by rapidly increasing demands for high‐performance energy‐storage devices (see picture; ASC/SSC=asymmetric/symmetric supercapacitor.
Chemically derived graphene holds great promise as an electrode material for electrochemical energy storage owing to its unique physical and chemical properties. Recent years have witnessed ...tremendous research breakthroughs in the field of graphene-based materials for electrochemical capacitors. This article presents a review of the latest developments in the functionalization of chemically derived graphene for improving its electrocapacitive properties. Beginning with a brief description of supercapacitors, graphene, and chemically derived graphene, we discuss the preparation, electrocapacitive properties, and drawbacks of chemically derived graphene and its derivatives, followed by a discussion on how to functionalize chemically derived graphene for improving its double-layer capacitance and pseudocapacitance. Emphasis is made on comparing and highlighting demonstrated approaches to functionalizing chemically derived graphene. Future research towards developing advanced electrochemical capacitors, perspectives and challenges are outlined.
This review summarizes the latest developments in the functionalization of chemically derived graphene for improving its electrocapacitive performance.
Abyssal manganese nodules have been explored widely for their economic potential and paleoenvironmental significance. Debate about whether biogenic or physical‐chemical processes are responsible for ...their formation remains because of difficulties in quantifying ancient microbiological contributions. To address this question, we investigated microbial fossils in manganese nodules from the western Pacific Ocean by integrating scanning electron microscope, transmission electron microscope, and synchrotron transmission X‐ray microscope observations. Our results suggest that the nodules host abundant fossil biogenic magnetite and manganese‐oxidizing bacteria. These organisms engage in redox reactions or live in environments with redox gradients. By combining magnetic properties and observations of fossil biogenic magnetite morphology, we estimate magnetofossil abundances and further assess fossil biogenic manganese oxide in nodules. Our results imply that manganese nodule formation appears to be dominated by biomineralization with an additional terrestrial contribution. Extensive biomineralization in ultralow‐productivity oceanic environments suggests that manganese nodule formation is an important aspect of biogeochemical cycling in abyssal seafloor environments.
Key Points
Abyssal ferromanganese nodules host abundant fossil biogenic magnetite and manganese oxide produced in environments with redox gradients
Redox reactions fueled abyssal microbial activity and contributed to biomass production in microecosystems within nodules
Manganese nodule formation appears to be dominated by biomineralization
•The article models ridership impacts of integrating ridesourcing with public transit.•Ridesourcing can help promote transit ridership and reduce operation costs.•Ridesourcing complements public ...transit by enhancing last-mile transit access.•Ridesourcing significantly reduces the wait time and travel time of a transit trip.•Transfers and additional pickups deter the integration of ridesourcing and transit.
Inspired by the success of private ridesourcing companies such as Uber and Lyft, transit agencies have started to consider integrating ridesourcing services (i.e. on-demand, app-driven ridesharing services) with public transit. Ridesourcing services may enhance the transit system in two major ways: replacing underutilized routes to improve operational efficiency, and providing last-mile connectivity to extend transit’s catchment area. While an integrated system of ridesourcing services and public transit is conceptually appealing, little is known regarding whether and how consumers might use a system like this and what key service attributes matter the most to them. This article investigates traveler responses to a proposed integrated transit system, named MTransit, at the University of Michigan Ann Arbor campus. We conducted a large-sample survey to collect both revealed preference (RP) and stated preference (SP) data and fit a RP-SP mixed logit model to examine the main determinants of commuting mode choice. The model results show that transfers and additional pickups are major deterrents for MTransit use. We further applied the model outputs to forecast the demand for MTransit under different deployment scenarios. We find that replacing low-ridership bus lines with ridesourcing services could slightly increase transit ridership while reducing operations costs. The service improvements offered by ridesourcing mainly come from reductions in wait time. Though relatively small in our study, another source of improvement is the decrease of in-vehicle travel time. Moreover, we find that when used to provide convenient last-mile connections, ridesourcing could provide a significant boost to transit. This finding verifies a popular notion among transit professionals that ridesourcing services can serve as a complement to public transit by enhancing last-mile transit access.
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