In this book we have collected a series of state-of-the art papers written by specialists in the field of ionic liquid crystals (ILCs) to address key questions concerning the synthesis, properties, ...and applications of ILCs. New compounds exhibiting ionic liquid crystalline phases are presented, both of calamitic as well as discotic type. Their dynamic and structural properties have been investigated with a series of experimental techniques including differential scanning calorimetry, polarized optical spectroscopy, X-ray scattering, and nuclear magnetic resonance, impedance spectroscopy to mention but a few. Moreover, computer simulations using both fully atomistic and highly coarse-grained force fields have been presented, offering an invaluable microscopic view of the structure and dynamics of these fascinating materials.
Azobenzene‐containing cross‐linked liquid crystal polymer films without hydrophilic groups exhibit dual‐responsivity to humidity and UV light. The films realize not only a series of large and ...sophisticated contactless motions by utilizing moisture, including an inchworm walk, and tumbling locomotion, but also dual‐mode actuation that can be applied in flexible electronics.
The cholesteric‐liquid‐crystalline structure, which concerns the organization of chromatin, collagen, chitin, or cellulose, is omnipresent in living matter. In technology, it is found in temperature ...and pressure sensors, supertwisted nematic liquid crystal displays, optical filters, reflective devices, or cosmetics. A cholesteric liquid crystal reflects light because of its helical structure. The reflection is selective – the bandwidth is limited to a few tens of nanometers and the reflectance is equal to at most 50% for unpolarized incident light, which is a consequence of the polarization‐selectivity rule. These limits must be exceeded for innovative applications like polarizer‐free reflective displays, broadband polarizers, optical data storage media, polarization‐independent devices, stealth technologies, or smart switchable reflective windows to control solar light and heat. Novel cholesteric‐liquid‐crystalline architectures with the related fabrication procedures must therefore be developed. This article reviews solutions found in living matter and laboratories to broaden the bandwidth around a central reflection wavelength, do without the polarization‐selectivity rule and go beyond the reflectance limit.
A review on cholesteric‐liquid‐crystalline helical structures found in living matter and in laboratory and which reflect and polarize light over a broad wavelength band and beyond the classical reflectance limit of 50% of unpolarized incident light.
Skeletal muscles are natural motors executing sophisticated work through precise control of linear contraction. Although various liquid crystal polymers based artificial muscles have been designed, ...the mechanism based on mainly the order–disorder transition usually leads to discrete shape morphing, leaving arbitrary and precise deformation a huge challenge. Here, one novel photoresponsive hemiphasmidic side‐chain liquid crystal polymer with a unique “breathing” columnar phase that enables continuous morphing is presented. Due to confinement inside the supramolecular columnar assembly, the cooperative movements of side‐chains and backbones generate a significant negative thermal expansion and lead to temperature‐controllable muscle‐like elongation/contraction in the oriented polymer strip. The irreversible isomerization of the photoresponsive mesogens results in the synergistic phototunable bending and high‐contrast fluorescence change. Based on the orthogonal responses to heat and light, controllable arm‐like bending motions of this material, which is applicable in constructing advanced artificial muscles or intelligent soft robotics, are further demonstrated.
A hemiphasmidic side‐chain liquid crystal polymer forms multichain supramolecular columnar assemblies. Through the cooperative movements of main‐chains and side‐chains, the uniaxially aligned polymer strip executes muscle‐like continuous and reversible elongation/contraction. The irreversible photoisomerization of mesogens further endows the polymer strip with arm‐like phototunable bending which can lift heavy load. Both deformations are under precise control of temperature.
Hydrogen-bonded liquid crystalline polymers have emerged as promising “smart” supramolecular functional materials with stimuli-responsive, self-healing, and recyclable properties. The hydrogen bonds ...can either be used as chemically responsive (i.e., pH-responsive) or as dynamic structural (i.e., temperature-responsive) moieties. Responsiveness can be manifested as changes in shape, color, or porosity and as selective binding. The liquid crystalline self-organization gives the materials their unique responsive nanostructures. Typically, the materials used for actuators or optical materials are constructed using linear calamitic (rod-shaped) hydrogen-bonded complexes, while nanoporous materials are constructed from either calamitic or discotic (disk-shaped) complexes. The dynamic structural character of the hydrogen bond moieties can be used to construct self-healing and recyclable supramolecular materials. In this review, recent findings are summarized, and potential future applications are discussed.
Polymer-stabilized liquid crystals (PSLCs) are multi-functional materials consisting of polymer networks in a continuous phase of liquid crystals (LCs), of which polymer networks provide anchoring ...energy to align the LCs. A number of improvements are detailed, including polymer-stabilized nematic liquid crystals (PSNLCs), polymer-stabilized cholesteric liquid crystals (PSCLCs), polymer-stabilized blue phase liquid crystals (PSBPLCs), polymer-stabilized smectic liquid crystals (PSSLCs), polymer-stabilized ferroelectric liquid crystals (PSFLCs), and polymer-stabilized antiferroelectric liquid crystals (PSAFLCs) in this review. Polymer stabilization has achieved multiple functionalities for LCs; in smart windows, a sufficiently strong electric field allows the LCs to reorient and enables switching from a scattering (transparent) state to a transparent (scattering) state. For broadband reflectors, the reflection bandwidth of LCs is manually tuned by electric fields, light, magnetic fields, or temperature. PSBPLCs open a new way for next-generation displays, spatial light modulators, sensors, lasers, lenses, and photonics applications. Polymer networks in PSFLCs or PSAFLCs enhance their grayscale memories utilized in flexible displays and energy-saving smart cards. At the end, the remaining challenges and research opportunities of PSLCs are discussed.
This book by Lev M. Blinov is ideal to guide researchers from their very first encounter with liquid crystals to the level where they can perform independent experiments on liquid crystals with a ...thorough understanding of their behaviour also in relation to the theoretical framework. Liquid crystals can be found everywhere around us. They are used in virtually every display device, whether it is for domestic appliances of for specialized technological instruments. Their finely tunable optical properties make them suitable also for thermo-sensing and laser technologies. There are many monographs written by prominent scholars on the subject of liquid crystals. The majority of them presents the subject in great depth, sometimes focussing on a particular research aspect, and in general they require a significant level of prior knowledge. In contrast, this books aims at an audience of advanced undergraduate and graduate students in physics, chemistry and materials science. The book consists of three parts: the first part, on structure, starts from the fundamental principles underlying the structure of liquid crystals, their rich phase behaviour and the methods used to study them, the second part, on physical properties, emphasizes the influence of anisotropy on all the aspects of liquid crystals behaviour, the third, focuses on electro-optics, the most important properties from the applications standpoint. This part covers only the main effects and illustrates the underlying principles is greater detail. Professor Lev M. Blinov has had a long carrier as an experimentalist. He made major contributions in the field of ferroelectric mesophases. In 1985 he received the USSR state prize for investigations of electro-optical effects in liquid crystals for spatial light modulators. In 1999 he was awarded the Frederiks medal of soviet Liquid Crystal Society and in 2000 he was honoured with the G. Gray silver medal of British Liquid Crystal Society. He has held many visiting academic positions in universities and laboratories across Europe and in Japan.
Tying knots and linking microscopic loops of polymers, macromolecules, or defect lines in complex materials is a challenging task for material scientists. We demonstrate the knotting of microscopic ...topological defect lines in chiral nematic liquid-crystal colloids into knots and links of arbitrary complexity by using laser tweezers as a micromanipulation tool. All knots and links with up to six crossings, including the Hopf link, the Star of David, and the Borromean rings, are demonstrated, stabilizing colloidal particles into an unusual soft matter. The knots in chiral nematic colloids are classified by the quantized self-linking number, a direct measure of the geometric, or Berry's, phase. Forming arbitrary microscopic knots and links in chiral nematic colloids is a demonstration of how relevant the topology can be for the material engineering of soft matter.
Currently, the global liquid crystal (LC) industry is worth approximately USD 115 billion, most of which is used for display applications using nematic LCs (including chiral nematic LCs). The purpose ...of this Special Issue is to provide new knowledge and research tools as the application of LC devices expands from flat displays to new fields such as 3D displays and sensors. This issue will provide LC researchers with ways to solve their problems.
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