Quantum simulation has emerged as a valuable arena for demonstrating and understanding the capabilities of near-term quantum computers1–3. Quantum annealing4,5 has been successfully used in ...simulating a range of open quantum systems, both at equilibrium6–8 and out of equilibrium9–11. However, in all previous experiments, annealing has been too slow to coherently simulate a closed quantum system, due to the onset of thermal effects from the environment. Here we demonstrate coherent evolution through a quantum phase transition in the paradigmatic setting of a one-dimensional transverse-field Ising chain, using up to 2,000 superconducting flux qubits in a programmable quantum annealer. In large systems, we observe the quantum Kibble–Zurek mechanism with theoretically predicted kink statistics, as well as characteristic positive kink–kink correlations, independent of temperature. In small chains, excitation statistics validate the picture of a Landau–Zener transition at a minimum gap. In both cases, the results are in quantitative agreement with analytical solutions to the closed-system quantum model. For slower anneals, we observe anti-Kibble–Zurek scaling in a crossover to the open quantum regime. The coherent dynamics of large-scale quantum annealers demonstrated here can be exploited to perform approximate quantum optimization, machine learning and simulation tasks.The coherent dynamics of the transverse-field Ising model driven through a quantum phase transition can be accurately simulated using a large-scale quantum annealer.
Temperature is one of the most fundamental physical properties to characterize various physical, chemical, and biological processes. Even a slight change in temperature could have an impact on the ...status or dynamics of a system. Thus, there is a great need for high-precision and large-dynamic-range temperature measurements. Conventional temperature sensors encounter difficulties in high-precision thermal sensing on the submicron scale. Recently, optical whispering-gallery mode (WGM) sensors have shown promise for many sensing applications, such as thermal sensing, magnetic detection, and biosensing. However, despite their superior sensitivity, the conventional sensing method for WGM resonators relies on tracking the changes in a single mode, which limits the dynamic range constrained by the laser source that has to be fine-tuned in a timely manner to follow the selected mode during the measurement. Moreover, we cannot derive the actual temperature from the spectrum directly but rather derive a relative temperature change. Here, we demonstrate an optical WGM barcode technique involving simultaneous monitoring of the patterns of multiple modes that can provide a direct temperature readout from the spectrum. The measurement relies on the patterns of multiple modes in the WGM spectrum instead of the changes of a particular mode. It can provide us with more information than the single-mode spectrum, such as the precise measurement of actual temperatures. Leveraging the high sensitivity of WGMs and eliminating the need to monitor particular modes, this work lays the foundation for developing a high-performance temperature sensor with not only superior sensitivity but also a broad dynamic range.
When exposed to fire, the integrity of cement-based materials is governed by thermally-induced changes in the mechanical properties of their binding phase, i.e., the calcium–silicate–hydrate (C–S–H) ...gel. However, the effect of temperature on the structure, density, and mechanical properties of C–S–H remains only partially known. Here, based on reactive molecular dynamics simulations, we reveal the nature of thermally-induced damage in C–S–H gels. In general, we show that, at the atomic scale, exposure to high temperature results in partial dehydration, volumetric shrinkage, disordering, and stiffening in the C–S–H grains. However, we show that the thermal response of C–S–H strongly depends on its chemical composition, wherein C–S–H systems associated with lower Ca/Si molar ratios are able to undergo higher temperatures before amorphization. Based on these results, we demonstrate that the stiffness of C–S–H gels (i.e., including porosity—as probed by nanoindentation) is governed by a competition between the stiffening of the grains and the decrease in packing density—wherein the latter eventually become predominant.
The surface phase junction of nanocrystalline TiO2 plays an essential role in governing its photocatalytic activity. Thus, facile and simple methods for preparing phase-junction TiO2 photocatalysts ...are highly desired. In this work, we show that phase-junction TiO2 is directly synthesized from Ti foil by using a simple calcination method with hydrothermal solution as the precursor below the phase transition temperature. Moreover, the ratio of rutile to anatase in the TiO2 samples could be readily tuned by changing the ratio of weight of Ti foil to HCl, which is used as the hydrothermal precursor, as confirmed by the X-ray diffraction analysis. In the photocatalytic reaction by the TiO2 nanocomposite, a synergistic effect between the two phases within a certain range of the ratio is clearly observed. The results suggest that an appropriate ratio of anatase to rutile in the TiO2 nanocomposite can create more efficient solid-solid interfaces upon calcination, thereby facilitating interparticle charge transfer in the photocatalysis.
The lack of a precisely-dated, unequivocal climate proxy from northern China, where precipitation variability is traditionally considered as an East Asian summer monsoon (EASM) indicator, impedes our ...understanding of the behaviour and dynamics of the EASM. Here we present a well-dated, pollen-based, ~20-yr-resolution quantitative precipitation reconstruction (derived using a transfer function) from an alpine lake in North China, which provides for the first time a direct record of EASM evolution since 14.7 ka (ka = thousands of years before present, where the "present" is defined as the year AD 1950). Our record reveals a gradually intensifying monsoon from 14.7-7.0 ka, a maximum monsoon (30% higher precipitation than present) from ~7.8-5.3 ka, and a rapid decline since ~3.3 ka. These insolation-driven EASM trends were punctuated by two millennial-scale weakening events which occurred synchronously to the cold Younger Dryas and at ~9.5-8.5 ka, and by two centennial-scale intervals of enhanced (weakened) monsoon during the Medieval Warm Period (Little Ice Age). Our precipitation reconstruction, consistent with temperature changes but quite different from the prevailing view of EASM evolution, points to strong internal feedback processes driving the EASM, and may aid our understanding of future monsoon behaviour under ongoing anthropogenic climate change.
High-entropy alloys (HEAs) can have either high strength or high ductility, and a simultaneous achievement of both still constitutes a tough challenge. The inferior castability and compositional ...segregation of HEAs are also obstacles for their technological applications. To tackle these problems, here we proposed a novel strategy to design HEAs using the eutectic alloy concept, i.e. to achieve a microstructure composed of alternating soft fcc and hard bcc phases. As a manifestation of this concept, an AlCoCrFeNi2.1 (atomic portion) eutectic high-entropy alloy (EHEA) was designed. The as-cast EHEA possessed a fine lamellar fcc/B2 microstructure, and showed an unprecedented combination of high tensile ductility and high fracture strength at room temperature. The excellent mechanical properties could be kept up to 700°C. This new alloy design strategy can be readily adapted to large-scale industrial production of HEAs with simultaneous high fracture strength and high ductility.
We present TerraClimate, a dataset of high-spatial resolution (1/24°, ~4-km) monthly climate and climatic water balance for global terrestrial surfaces from 1958-2015. TerraClimate uses climatically ...aided interpolation, combining high-spatial resolution climatological normals from the WorldClim dataset, with coarser resolution time varying (i.e., monthly) data from other sources to produce a monthly dataset of precipitation, maximum and minimum temperature, wind speed, vapor pressure, and solar radiation. TerraClimate additionally produces monthly surface water balance datasets using a water balance model that incorporates reference evapotranspiration, precipitation, temperature, and interpolated plant extractable soil water capacity. These data provide important inputs for ecological and hydrological studies at global scales that require high spatial resolution and time varying climate and climatic water balance data. We validated spatiotemporal aspects of TerraClimate using annual temperature, precipitation, and calculated reference evapotranspiration from station data, as well as annual runoff from streamflow gauges. TerraClimate datasets showed noted improvement in overall mean absolute error and increased spatial realism relative to coarser resolution gridded datasets.
In this study, pot experiments were performed to investigate the effects of high temperature stress (44 °C) in maize plants colonized with and without arbuscular mycorrhizal fungi (AMF). Various ...parameters characterizing photosynthetic activity were measured in order to estimate the photosynthetic efficiency in maize plants. It was observed that density of active reaction centers of PSII, quantum efficiency of photosystem II (PSII), linear electron transport, excitation energy trapping, performance index, net photosynthesis rate increased in AMF (+) plants at 44 °C ± 0.2 °C. Efficiency of primary photochemical reaction (represented as Fv/Fo) increased in AMF (+) plants as compared to AMF (−) plants. AMF seems to have protected water splitting complex followed by enhanced primary photochemistry of PSII under high temperature. Basic morphological parameters like leaf width, plant height and cob number increased in AMF (+) plants as compared to AMF (−) plants. AMF (+) plants grew faster than AMF (−) plants due to larger root systems. Chl content increased in AMF (+) plants as compared to AMF (−) maize plants. AMF hyphae likely increased Mg uptake which in turn increased the total chlorophyll content in AMF (+) maize plants. This subsequently led to a higher production in photosynthate and biomass. Thus AMF (+) plants have shown better photosynthesis performance as compared to AMF (−) maize plants under high temperature stress.
•High temperature stress is considered as one of the major destructive stress among various abiotic stresses.•Arbuscular mycorrhizal fungi (AMF) makes symbiotic association with ~ 80% terrestrial plants.•AMF increased quantum efficiency of PSII and protected oxygen evolving complex under high temperature stress.•AMF improved net photosynthetic rate leading to higher production of plant photosynthates and biomass.•AMF improved morphological and photosynthetic efficiency of maize plants under high temperature stress.
The development of single molecule white light emitters is extremely challenging for pure phosphorescent metal-free system at room temperature. Here we report a single pure organic phosphor, namely ...4-chlorobenzoyldibenzothiophene, emitting white room temperature phosphorescence with Commission Internationale de l'Éclair-age coordinates of (0.33, 0.35). Experimental and theoretical investigations reveal that the white light emission is emerged from dual phosphorescence, which emit from the first and second excited triplet states. We also demonstrate the validity of the strategy to achieve metal-free pure phosphorescent single molecule white light emitters by intrasystem mixing dual room temperature phosphorescence arising from the low- and high-lying triplet states.The development of single molecule white light-emitters is extremely challenging for pure phosphorescent metal-free systems at room temperature. Here the authors show a single pure organic room temperature phosphor, 4-chlorobenzoyldibenzothiophene, utilizing the emission from both T
and T
states.
Drop shapes derived from a previously conducted artificial rain experiment using a two-dimensional video disdrometer (2DVD) are presented. The experiment involved drops falling over a distance of 80 ...m to achieve their terminal velocities as well as steady-state oscillations. The previous study analyzed the measured axis ratios (i.e., ratio of maximum vertical to maximum horizontal chord) as a function of equivolumetric spherical drop diameter (Dsub eq) for over 115 000 drops ranging from 1.5 to 9 mm. In this paper, the actual contoured shapes of the drops are reported, taking into account the finite quantization limits of the instrument. The shapes were derived from the fast line-scanning cameras of the 2DVD. The drops were categorized into Dsub eq intervals of 0.25-mm width and the smoothed contours for each drop category were superimposed on each other to obtain their most probable shapes and their variations due to drop oscillations. The most probable shapes show deviation from oblate spheroids for Dsub eq 4 mm, the larger drops having a more flattened base, in good agreement with the equilibrium (nonoblate) shape model of Beard and Chuang. Deviations were noted from the Beard and Chuang model shapes for diameters larger than 6 mm. However, the 2DVD measurements of the most probable contour shapes are the first to validate the Beard and Chuang model shapes for large drops, and further to demonstrate the differences from the equivalent oblate shapes. The purpose of this paper is to document the differences in radar polarization parameters and the range of error incurred when using the equivalent oblate shapes versus the most probable contoured shapes measured with the 2DVD especially for drop size distributions (DSDs) with large median volume diameters (2 mm). The measured contours for Dsub eq 1.5 mm were fitted to a modified conical equation, and scattering calculations were performed to derive the complex scattering amplitudes for forward and backscatter for H and V polarizations primarily at 5.34 GHz (C band) but also at 3 GHz (S band) and 9 GHz (X band). Calculations were also made to derive the relevant dual-polarization radar parameters for measured as well as model-based drop size distributions. When comparing calculations using the contoured shapes against the equivalent oblate spheroid shapes, good agreement was obtained for cases with median volume diameter (Dsub 0) less than around 2 mm. Small systematic differences in the differential reflectivity (Zsub dr) values of up to 0.3 dB were seen for the larger Dsub 0 values when using the oblate shapes, which can be primarily attributed to the shape differences in the resonance region, which occurs in the 5.5-7-mm-diameter range at C band. Lesser systematic differences were present in the resonance region at X band (3-4 mm). At S band, the impact of shape differences in the polarimetric parameters were relatively minor for Dsub 0 up to 2.5 mm. Unusual DSDs with very large Dsub 0 values (3 mm) (e.g., as can occur along the leading edge of severe convective storms or aloft due localized "big drop" zones) can accentuate the Zsub dr difference between the contoured shape and the oblate spheroid equivalent, especially at C band. For attenuation-correction schemes based on differential propagation phase, it appears that the equivalent oblate shape approximation is sufficient using a fit to the axis ratios from the 80-m fall experiment given in this paper. For high accuracy in developing algorithms for predicting Dsub 0 from Zsub dr, it is recommended that the fit to the most probable contoured shapes as given in this paper be used especially at C band. PUBLICATION ABSTRACT
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DOBA, IZUM, KILJ, NUK, PILJ, PNG, SAZU, UILJ, UKNU, UL, UM, UPUK