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  • Dong, B X; Zhang, S Y; Liu, W L; Wu, Y C; Ge, J; Song, L; Teng, Y L

    Chemical communications (Cambridge, England), 04/2015, Letnik: 51, Številka: 26
    Journal Article

    A novel water-stable open poly-nuclear Cu(I)-based metal-organic framework, NC2H84Cu5(BTT)3·xG (G = guest of DMA and H2O) (1), featuring a giant multi-prismatic nanoscale cage and high CO2/N2 and CO2/H2 sorption selectivities, was successfully assembled by using the nitrogen-rich ligand of 1,3,5-tris(2H-tetrazol-5-yl)benzene (H3BTT) to bridge two types of Cu3 and Cu2 clusters.