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  • Preparation and Properties ...
    Nalbandyan, Vladimir B.; Vasilchikova, Tatyana M.; Zakharov, Konstantin V.; Vasiliev, Alexander N.; Evstigneeva, Maria A.; Guda, Alexander A.

    Inorganic chemistry, 06/2024, Letnik: 63, Številka: 22
    Journal Article

    The homogeneous high-entropy wolframite-type solid solution (Mn1/5Co1/5Ni1/5Cu1/5Cd1/5)­WO4 was prepared by solid-state reaction at 1000 °C. Elongated “crystals” were grown from the Na2WO4 flux, but their strongly broadened powder X-ray diffraction patterns indicated partial dissolution. Nevertheless, successive annealing of the homogeneous solid solution for 3–4 h at 800, 700, and 600 °C did not bring any sign of dissolution. Thus, the material is kinetically stable at low temperatures although thermodynamically unstable. The long-range antiferromagnetic order was established at T N ∼ 24.8 K. Based on magnetization and specific heat measurements, a magnetic phase diagram was built, demonstrating the presence of an additional field-induced phase. In contrast to the parent MnWO4, no dielectric anomaly has been found down to 2 K.