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Long, Yang; Su, Zhishan; Zheng, Yanling; He, Shiyu; Zhong, Jing; Xiang, Haifeng; Zhou, Xiangge
ACS catalysis, 03/2020, Letnik: 10, Številka: 5Journal Article
A rhodium-catalyzed transarylation of benzamides via selective C–C bond activation with arylboronic acids was described, which was distinct from the conventional metal-catalyzed C–N bond activation. This transformation exhibited good functional group compatibility with yields up to 88%, offering a practical approach for the construction and functionalization of benzamides. Preliminary experimental and computational studies revealed the selectivity of metal insertion into the C–C bond or the C–N bond was greatly affected by substituents on the amide’s N atom.
