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  • Electrochemical transformat...
    Smolyaninov, I. V.; Kuzmin, V. V.; Arsenyev, M. V.; Smolyaninova, S. A.; Poddel´sky, A. I.; Berberova, N. T.

    Russian chemical bulletin, 07/2017, Letnik: 66, Številka: 7
    Journal Article

    The electrochemical properties of a series of sterically hindered o -benzoquinones in aprotic solvents were examined. The reaction of O 2 and KO 2 with o -benzoquinones and electrogenerated o -semiquinone radical anions was studied. The formation of o -semiquinone radical anions in the reactions of KO 2 with the studied o -quinones was detected using UV-visible and ESR spectroscopy. The influence of the test compounds on lipid peroxidation was considered at the molecular and tissue levels in vitro . In the most cases, o -quinones exhibit antioxidant activity, which varies depending on the type of lipid substrate.