The desire to offer clothes protective properties against the harmful UV rays continues to attract the interest of researchers. Several works have been elaborated in this topic and have proved that the clothes do not protect sufficiently against the solar ultraviolet radiation. Their protectiveness depends on the fiber type, the fabric composition, the fabric construction and the dyeing method. This research presents a novel approach which target the improvement of the textile protective properties against UV rays by their dyeing with grape pomace aqueous extract. These properties were tested in combination with several fabrics (natural and synthetic) and mordants (potassium alum and ferrous sulphate). Through this study, it has been shown that the UV-protective properties of the several dyed fibers were upgraded after dyeing with the grape pomace extract, and is intensely relying on the types of fibers and mordants.