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Campbell, A. N; Kouwe, E. T. van der
Canadian journal of chemistry, 04/1968, Letnik: 46, Številka: 8Journal Article
The following properties have been determined by direct experiment for pure sodium chlorate and its mixtures with sodium nitrate: heat capacity (both solid and liquid) and heat of fusion. From these experimental quantities, the following properties have been derived: entropy of fusion, heat of mixing, and free energy and entropy of mixing. The results have been compared with our previous results for the corresponding lithium chlorate - lithium nitrate system. On the whole, the conclusion is justified that the structure of melts containing lithium chlorate is more complex than that of melts involving sodium chlorate.
