E-viri
Recenzirano
Odprti dostop
-
Sánchez‐González, Rodrigo; Imbarack, Elizabeth; Suazo, Constanza; Soto, Juan Pablo; Leyton, Patricio; Sánchez‐Cortés, Santiago; Campos‐Vallette, Marcelo
Journal of Raman spectroscopy, 20/May , Letnik: 52, Številka: 5Journal Article
In this work, the adsorption and orientation on gold nanoparticles (AuNps) of a new family of cruciform systems consisting of thiophene rings and imino groups were studied. The structural modification and its influence on the adsorbate‐substrate interaction were evaluated by UV–Vis spectroscopy and Surface Enhanced Raman Spectroscopy (SERS). The absence of SERS spectrum for (N,N′‐bis(4‐(trifluoromethyl)benzylidene)‐2,5‐di (thiophene‐2‐yl)‐1,4‐diaminobenzene) CFF shows that the inclusion of a trifluoromethyl group (‐CF3) on the benzylidene fragment limits the interaction of the CFF system with the gold substrate, in contrast, to that obtained for (N, N′‐dibenzylidene‐2,5‐di (thiophene‐2‐yl) ‐1,4‐diaminobenzene) 2‐CF and (N, N′‐bis (4‐methoxybenzylidene) ‐2,5‐di (thiophene‐2yl) ‐1,4‐diaminobenzene) CMF, where the adsorption took place preferentially through the thiophene rings, resulting in partial quinoidization. On the other hand, the interaction for compound (N, N′‐bis (4‐methylenepyridinyl) ‐2,5‐di (thiophene‐2‐yl) ‐1,4‐diaminobenzene) CPy with the surface was conducted by means of the pyridinic fragments. The systematic modification of the bifunctional cruciform systems, with groups of different nature, makes it possible to rationalize the structural aspects that directly influence the adsorbate‐substrate interaction and molecular orientation on gold substrates. These structural parameters are the basis to the development of stable molecular assemblies, which can act as basic building blocks in the manufacture of molecular switches. The adsorption and orientation of a new family of cruciform systems were evaluated by Surface Amplified Raman Spectroscopy (SERS). In this sense, the structural modifications allowed modulating the substrate‐adsorbate interaction center, affinity, and preferential orientation of the adsorbates with respect to the gold nanoparticles.
Vnos na polico
Trajna povezava
- URL:
Faktor vpliva
Dostop do baze podatkov JCR je dovoljen samo uporabnikom iz Slovenije. Vaš trenutni IP-naslov ni na seznamu dovoljenih za dostop, zato je potrebna avtentikacija z ustreznim računom AAI.
Leto | Faktor vpliva | Izdaja | Kategorija | Razvrstitev | ||||
---|---|---|---|---|---|---|---|---|
JCR | SNIP | JCR | SNIP | JCR | SNIP | JCR | SNIP |
Baze podatkov, v katerih je revija indeksirana
Ime baze podatkov | Področje | Leto |
---|
Povezave do osebnih bibliografij avtorjev | Povezave do podatkov o raziskovalcih v sistemu SICRIS |
---|
Vir: Osebne bibliografije
in: SICRIS
To gradivo vam je dostopno v celotnem besedilu. Če kljub temu želite naročiti gradivo, kliknite gumb Nadaljuj.