Laser-induced deposition of metals from a solution has been used as a new method for the synthesis of microcomposite materials in the copper-silver system. It was shown that the obtained materials have good sensory properties with respect to the determination of d -glucose in aqueous solutions. It is also shown that it can be used for gas sensors. Control of sensory properties can be done by changing the method of deposition. X-ray diffraction, EDX, and impedance spectroscopy were used to characterize the materials obtained and it was shown that laser sequential deposition and coprecipitation of two metals give different results. An explanation of the results was proposed. It explains them by the eutectic nature of the interaction in the copper-silver system.