Thunderstorm Ground Enhancements (TGEs) refer to correlated enhancements in surface electric field and gamma ray flux that are manifestations of electron runaway in the storm overhead. The electric field enhancements can be of positive or negative polarity. In this study, altitude‐resolved S‐band radar observations of graupel are used to demonstrate distinct differences in storm structure linked with these “positive” and “negative” TGEs. The physical interpretation rests on the well‐established temperature‐dependent tripole structure of thunderstorms, with the main negative charge of the tripole acting as an electron repeller. This interpretation is supported by case studies showing altitude‐stable convection, with shallow (deep) development linked with “positive” (“negative”) TGEs, and by case studies of collapsing storms that show upper dipole dominance early and lower inverted dipole dominance later when graupel particles descend from a colder to warmer temperature domain. In the case of many TGEs on Mt Aragats (3.2 km MSL), the temperature‐dependent altitude of downward electron acceleration and avalanching may be sufficiently distant (>500 m) from surface detectors that the energetic electrons (1–10 MeV) are not likely avalanche/runaway electrons. Instead, they are Compton‐scattered and pair‐produced electrons from bremsstrahlung gamma radiation emanating from the high‐field avalanche region aloft. These inferences are consistent with GEANT4 calculations that identify the physical origins of energetic electrons at the surface. Key Points Thunderstorm Ground Enhancements (TGEs) are indicative of downward electron acceleration within the storm and are manifest with both polarities of the electric field Vertical development disclosed by RADAR is uniquely linked with "positive" and "negative" TGEs These different vertical developments are attributed to a temperature‐dependent tripole structure of thunderclouds