E-viri
Recenzirano
-
Nakase, M.; Yamamura, T.; Shirasaki, K.; Nagai, M.; Takeshita, K.
Separation science and technology, 08/2019, Letnik: 54, Številka: 12Journal Article
The thorium (Th) fuel cycle is attracting attention again because of its potential merits over the uranium (U) fuel cycle, but the associated back-end technology remains insufficiently mature compared with that of the U fuel cycle. In the chemical reprocessing of spent Th oxide fuels, effective separation of UO 2 2+ from Th 4+ is required and a quite high dose rate is expected in reprocessing because of the strong radiation by 208 Tl generated from 232 U, an associated product of 233 U. Therefore, gel/liquid extraction was applied to U/Th separation.Introducing ligands chemically into the hydrogels (via the C-C bonds) can minimize ligand leaching, and the ligands are expected to be more resistant to radiation. Some of the N,O-hybrid donor ligands that have polymerizable functional groups - Bis(di-N-allyl-N-tollyl) phenanthlorine diamide (Allyl-Tol-PTDA) and N,N,N',N'-tetraallylpyridine-2,6-dicarboxamine (Tet-Allyl-PDA) for gel adsorbent synthesis and N,N,N',N'-tetrahexylpyridine-2,6-dicarboxamine (Tet-Hex-PDA) - were synthesized for solvent extraction because Allyl-Tol-PTDA has low solubility in n-dodecane. Allyl-Tol-PDA and Tet-Allyl-PDA were then polymerized with N-isopropylacrylamide (NIPA) and N,N'-methylenbisacrylamide (BIS) to give thermosensitive hydrogels, namely PTDA-gel and PDA-gel. The general extraction behaviors of Allyl-Tol-PTDA and Tet-Hex-PDA instead of Allyl-Tol-PDA and the adsorption behaviors of PTDA-gel and PDA-gel were compared with those of UO 2 2+ and Th 4+ in HNO 3 . Consequently, differing extraction/adsorption behavior between solvent extraction and gel adsorption was determined. The PTDA gel showed no strong dependency on acidity and temperature with UO 2 2+ , but Th 4+ showed a local maximum with varying acidity. By contrast, the PDA-gel showed temperature dependency: UO 2 2+ adsorbed more at higher temperature and Th 4+ adsorbed more at lower temperature. Therefore, U/Th separation is possible with (i) PTDA-gel at higher temperature and acidity, and (ii) PDA-gel at higher temperature and lower acidity.
![loading ... loading ...](themes/default/img/ajax-loading.gif)
Vnos na polico
Trajna povezava
- URL:
Faktor vpliva
Dostop do baze podatkov JCR je dovoljen samo uporabnikom iz Slovenije. Vaš trenutni IP-naslov ni na seznamu dovoljenih za dostop, zato je potrebna avtentikacija z ustreznim računom AAI.
Leto | Faktor vpliva | Izdaja | Kategorija | Razvrstitev | ||||
---|---|---|---|---|---|---|---|---|
JCR | SNIP | JCR | SNIP | JCR | SNIP | JCR | SNIP |
Baze podatkov, v katerih je revija indeksirana
Ime baze podatkov | Področje | Leto |
---|
Povezave do osebnih bibliografij avtorjev | Povezave do podatkov o raziskovalcih v sistemu SICRIS |
---|
Vir: Osebne bibliografije
in: SICRIS
To gradivo vam je dostopno v celotnem besedilu. Če kljub temu želite naročiti gradivo, kliknite gumb Nadaljuj.