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  • Ln() amido complexes coordi...
    Lapshin, Ivan V; Cherkasov, Anton V; Asachenko, Andrey F; Trifonov, Alexander A

    Chemical communications (Cambridge, England), 10/2020, Letnik: 56, Številka: 85
    Journal Article

    First Ln( ii ) ring-expanded NHC complexes (er-NHC)LnN(SiMe 3 ) 2 2 (Ln = Sm, Yb) are synthesized and proved to be highly efficient pre-catalysts for the intermolecular hydrophosphination of such indolent substrates as 1-alkenes, cyclohexene and norbornene. First Ln( ii ) ring-expanded NHC complexes (er-NHC)LnN(SiMe 3 ) 2 2 (Ln = Sm, Yb) are synthesized and proved to be highly efficient pre-catalysts for the intermolecular hydrophosphination of such indolent substrates as 1-alkenes, cyclohexene and norbornene.