High‐spatial resolution textural and geochemical data from thin slip surfaces in exhumed fault zones archive thermal and rheological signatures of past fault slip. A network of minor, glossy, iridescent silica fault mirrors (FMs) cut Paleoproterozoic gneiss in the Wasatch fault zone (WFZ), Utah. We report field to nanoscale observations from scanning electron microscopy, electron backscattered diffraction, and transmission electron microscopy with energy‐dispersive X‐ray spectroscopy of a silica FM to infer deformation mechanisms during FM development. The FM volume comprises a ∼40–90 μm‐thick basal layer of sintered, µm‐ to nm‐diameter silica particles with polygonal to anhedral morphologies, pervasive crystalline Ti‐bearing phases containing measurable N, and µm‐ to nm‐scale void spaces. Silica particles lack shape and crystallographic preferred orientation and some are predominantly amorphous with internal crystalline domains. The basal layer is overlain by a ∼10–130 nm‐thick, chemically heterogeneous, amorphous film at the FM interface. Mass balance calculations of Ti in the basal layer and host rock indicate the FM volume can be sourced from the underlying gneiss. Multiple textural and geochemical lines of evidence, including N substitution in Ti‐bearing phases, support temperature rise during deformation, associated amorphization of host gneiss, and creation of the FM volume. During thermal decay, interstitial anatase and titanite fully crystallized, silica textures capture their incipient crystallization, and some residual elements are solidified in the nanofilm. Our results support a mechanism of weakening and re‐strengthening of silica FM during fault slip and, together with data from adjacent hematite FMs, record shallow, ancient microseismicity in the WFZ. Key Points Silica fault mirrors comprise a basal layer of variable silica crystallinity and interstitial anatase, with an overlying amorphous nanofilm Textures and geochemistry support coseismic temperature rise, host gneiss amorphization, and incipient crystallization of fault mirror Silica fault mirrors likely accommodated shallow, ancient microseismicity in the Wasatch fault damage zone