E-viri
Recenzirano
-
Ostrowska, Sylwia; Arnaut, Pierre; Liptrot, David J; Cazin, Catherine S. J; Nolan, Steven P
Chemical communications (Cambridge, England), 07/2023, Letnik: 59, Številka: 59Journal Article
The synthesis, isolation and full characterisation of a Cu(IPr)(OC(H)(CF 3 ) 2 ) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) complex are reported. This new Cu( i ) complex is a versatile synthon and can activate numerous X-H bonds including C-H, N-H and S-H bonds. Cu(IPr)(OC(H)(CF 3 ) 2 ) was investigated as a pre-catalyst in several catalytic reactions. A simple synthetic route gives access to well-defined Cu( i )-alkoxide complexes that prove stable to air and can be used as pre-catalysts.
![An air-stable [Cu(NHC)(OR)]...](http://api.summon.serialssolutions.com/2.0.0/image/issn/XR4PS5YY4K/1359-7345/medium "An air-stable [Cu(NHC)(OR)] (R = C(H)(CF)) complex for C-H, N-H and S-H bond activation")
