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  • Prediction of an autocataly...
    Pool, René; Bolhuis, Peter G

    Physical review letters, 07/2006, Letnik: 97, Številka: 1
    Journal Article

    We report molecular simulations suggesting that the kinetics of surfactant micelle formation can be sped up significantly by a replication mechanism, in which growing micelles become unstable and split into two similar sized micelles. We argue that for certain surfactants types around the critical micelle concentration, such a mechanism becomes more dominant than the commonly accepted nucleation pathway.