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Beckers, Helmut; Garcia, Placido; Willner, Helge; Argüello, Gustavo A.; Cobos, Carlos J.; Francisco, Joseph S.
Angewandte Chemie (International ed.), 2007, Letnik: 46, Številka: 20Journal Article
Quantum‐chemical calculations predict the existence of two almost equal‐energy isomers of the FSO5 radical with either side‐on or end‐on bonding of O2 to FSO3 (see picture). The structure of this polyoxy radical isolated in solid noble‐gas matrices and formed by the reaction of FSO3 with molecular oxygen has now been revealed by IR and UV spectroscopic investigations.
