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  • Total Synthesis of ent-Plag...
    Jackson, Richard K; Wood, John L

    Organic letters, 02/2021, Letnik: 23, Številka: 4
    Journal Article

    An enantioselective total synthesis of plagiochianin B is described that employs (+)-3-carene as its point of departure and delivers the enantiomer of the natural product. Key features of the synthesis include a palladium-mediated regioselective oxidative cleavage of an olefin residing on a pyridine derived from a 6π-azatriene electrocyclization.