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Doyle, Laurence R; Hill, Peter J; Wildgoose, Gregory G; Ashley, Andrew E
Dalton transactions, 05/2016, Letnik: 45, Številka: 18Journal Article
The Fe(0) species Fe(N2)(dmpe)2 exists in equilibrium with the previously unreported dimer, Fe(dmpe2)2(μ-N2). For the first time these complexes, alongside Fe(N2)(depe)2, are shown unambiguously to produce N2H4 and/or NH3 upon addition of triflic acid; for Fe(N2)(depe)2 this represents one of the highest electron conversion efficiencies for Fe complexes to date.
