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Orchanian, Nicholas M; Guizzo, Sophia; Steigerwald, Michael L; Nuckolls, Colin; Venkataraman, Latha
Chemical communications (Cambridge, England), 11/2022, Letnik: 58, Številka: 9Journal Article
The formation of carbon-carbon bonds with transition metal reagents serves as a cornerstone of organic synthesis. Here, we show that the reactivity of an otherwise kinetically inert transition metal complex can be induced by an external electric field to affect a coupling reaction. These results highlight the importance of electric field effects in reaction chemistry and offers a new strategy to modulate organometallic reactivity. External electric fields can influence the reactivity of organometallic complexes in solution. This effect is demonstrated to induce carbon-carbon bond forming chemistry with a kinetically inert nickel complex at room temperature.
