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  • Au(i)-mediated N2-eliminati...
    Yue, Erlin; Dettling, Lea; Sklorz, Julian A W; Kaiser, Selina; Weber, Manuela; Müller, Christian

    Chemical communications, 01/2022, Letnik: 58, Številka: 2
    Journal Article

    Novel tosyl- and mesitylsulfonyl-substituted triazaphospholes were synthesized and structurally characterized. In an attempt to prepare the corresponding Au(i)-complexes with stoichiometric amounts of AuCl·S(CH3)2, cyclo-1,3-diphospha(iii)-2,4-diazane-AuCl-complexes were obtained instead. Our here presented results offer a new strategy for preparing such coordination compounds selectively in a one-pot approach.