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Khariushin, Ivan V; Ovsyannikov, Alexander S; Baudron, Stéphane A; Ward, Jas S; Kiesilä, Anniina; Rissanen, Kari; Kalenius, Elina; Kovalenko, Konstantin A; Fedin, Vladimir P; Solovieva, Svetlana E; Antipin, Igor S; Bulach, Véronique; Ferlay, Sylvie
Chemical communications (Cambridge, England), 12/2022, Letnik: 58, Številka: 98Journal Article
Giant octahedral M32 coordination cages were prepared via self-assembly of sulfonylcalix4arene-supported tetranuclear M(ii) clusters (M = Co, Ni) with hybrid linker based on tris(dipyrrinato)cobalt(iii) complexes appended with peripherical carboxylic groups. Due to intrinsic and extrinsic porosity, the obtained solid-state supramolecular architectures demonstrated good performance as adsorbents for the separation of industrially important gases mixtures.
