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Murtazoev, Alisher F; Berdonosov, Peter S; Lyssenko, Konstantin A; Dolgikh, Valery A; Pchelkina, Zlata V; Zakharov, Konstantin V; Geidorf, Michael Y; Vasilchikova, Tatyana M; Volkova, Olga S; Vasiliev, Alexander N
Dalton transactions : an international journal of inorganic chemistry, 07/2023, Letnik: 52, Številka: 27Journal Article
Anhydrous copper tellurite sulfate, Cu3TeO3(SO4)2, has been synthesized via vapor transport reactions in sealed silica glass ampoules. In measurements of magnetization M, magnetic susceptibility χ, specific heat Cp and X-band electron spin resonance, a long-range antiferromagnetic order at TN = 13 K and an H–T magnetic phase diagram have been established. One-third of Cu2+ ions were found to form magnetically silent dimers. A peak in dielectric permittivity ϵ, which accompanies the Néel order, allows considering Cu3TeO3(SO4)2 as a magnetoelectric multiferroic material of the second type. Density functional theory calculations provided estimations of leading exchange interaction parameters.
