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Barloy, L; Heinrich, B; Douce, L; Henry, M; Scarpi-Luttenauer, M; Kyritsakas, N; Mobian, P
Dalton transactions, 01/2019, Letnik: 48, Številka: 6Journal Article
Stable complexes Ti(1a)(2)2 and Ti(1b)(2)2, where 2 is the 6,6′-diphenyl-2,2′-biphenolato ligand and 1a and 1b ligands are 2,2′-bipyrimidine derivatives, are synthesized. The complex Ti(1b)(2)2 containing a diimine ligand substituted with long alkyl chains (C16) exhibits a liquid crystal behaviour. This property and self-assembling in the crystalline state are explained by the particular molecular conformation of the complexes.
