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Rodríguez-González, Fidel E; Soto, Cenit; Palacio, Laura; Montero-Alejo, Ana L; Escalona, Néstor; Schott, Eduardo; Comesaña-Gándara, Bibiana; Terraza, Claudio A; Tundidor-Camba, Alain
Polymer chemistry, 05/2023, Letnik: 14, Številka: 19Journal Article
High-performance polymers for membrane gas separation require the careful design of the structure-porous relationship. In this work, five phthalimide-based polymers of intrinsic microporosity (PIMs) were obtained via the double nucleophilic aromatic substitution with the commercially available 5,5′,6,6′-tetrahydroxy-3,3,3′,3′-tetramethylspirobisindane (TTSBI) monomer. The phthalimide monomers were synthesized considering different sizes and positions of the alkyl-substituents to evaluate their influence on the physical properties of the polymers and their potential use as gas separation membranes. Four polymers were soluble in the low-boiling solvents chloroform and tetrahydrofuran, facilitating the casting of self-standing films to evaluate their gas separation properties. The thermally stable membranes showed 5% weight lost between 537 °C and 549 °C. As powders, these four polymers showed apparent BET surface areas ranging from 434 to 661 m 2 g −1 . The experimental BET surface areas correlated with those obtained by molecular simulation models of the synthesized polymers. A linear function is proposed as a tool to predict, with a known uncertainty, the surface area values of this type of polymer from the corresponding computational models. As a trend, increasing the volume of the ortho -substituent in the aryl-phthalimide group increases the permeability of the membranes, reaching generally better performances than Matrimid® and close to those of PIM-1 , considering their place on the Robeson diagrams of the O 2 /N 2 , CO 2 /CH 4 and CO 2 /N 2 gas pairs. Aging studies between 63 and 122 days showed a decrease in permeability, accompanied by the typical increase in selectivity that tends to move the data parallel to the upper Robeson limits. High-performance polymers for membrane gas separation require the careful design of the structure-porous relationship.
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